journal article·2025-06-26

Hemicellulose as an additive in papermaking

M. Mostafizur Rahman, Taslima Ferdous, Yangcan Jin, M. Sarwar Jahan

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Abstract

Abstract Hemicellulose, a lignocellulosic component derived from wood or non-wood pulping, has garnered emerging research interest due to its unique property profiles, which enable its potential use as a bio-based alternative additive in paper production. Additionally, it holds significant promise for commercialization within the forest biorefinery sector. The paper reviews the articles investigated on hemicellulose and cationic hemicellulose addition in papermaking. Studies have shown that hemicellulose removal from the pulp decreased tensile strength, and hemicellulose addition reduced refining energy and improved strength properties. The effectiveness of hemicellulose addition in pulp is influenced by the molar mass of xylan. The primary challenge in using hemicellulose as a wet-end chemical is its limited ability to significantly improve papermaking properties. Therefore, it needs to be cationized to get desired performance. The cationization agents are 3-chloro-2-hydroxypropyl trimethyl ammonium chloride (CHPTAC) and 2,3-epoxypropyl trimethyl ammonium chloride (EPTAC), which are used in alkaline medium. To reduce the degradation of hemicellulose, the cationization was also carried out in aqueous ethanol and relatively low alkali concentration. The application of cationic xylans to the anionic pulp surface mitigates the electrostatic repulsion, facilitate stronger inter-fiber bonding and improve papermaking properties.
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Research context

OpenAlex topics: Advanced Cellulose Research Studies · Biofuel production and bioconversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Pulp and Paper Research Division , 130051 Bangladesh Council of Scientific and Industrial Research Laboratories , Dhaka , Dr. Qudrat-i-Khuda Road, Dhaka 1205 , Bangladesh

Department of Applied Chemistry and Chemical Engineering , University of Dhaka , Dhaka , 1000 , Bangladesh

Jiangsu Key Lab of Pulp and Paper Science and Technology , Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University , Nanjing , 210037 , China

Funding

Ministry of Science and Technology, Government of the People’s Republic of Bangladesh

References (61)

Show source-provided references
1. Abdullah, R.S.M.H. (2010). Cationic starch as a dry strength agent in magnetic papermaking. Sains Malays. 39: 239–242.
2. Ahrenstedt, L., Oksanen, A., Salminen, K., and Brumer, H. (2008). Paper dry strength improvement by xyloglucan addition: wet-end application, spray coating and synergism with borate. Holzforschung 62: 8–14, https://doi.org/10.1515/hf.2008.002.10.1515/HF.2008.002 ↗
3. Ahsan, L., Jahan, M.S., and Ni, Y. (2014). Recovering/concentrating of hemicellulosic sugars and acetic acid by nanofiltration and reverse osmosis from prehydrolysis liquor of kraft based hardwood dissolving pulp process. Bioresour. Technol. 155: 111–115, https://doi.org/10.1016/j.biortech.2013.12.096.10.1016/j.biortech.2013.12.096 ↗
4. Antal, M., Ebringerová, A., and Micko, M.M. (1991). Cationic hemicelluloses from aspen wood flour and their use in paper production. Pap. Ger. FR 45.
5. Antal, M., Ebringerova, A., and Hromadkova, Z. (1997). Structure and papermaking properties of aminoalkylxylans. Papier, Eduard Roether Verlag Berliner Allee 56, W-6100 Darmstadt, Germany 51: 223–226, .
6. Bai, L., Hu, H., and Xu, J. (2012). Influences of configuration and molecular weight of hemicelluloses on their paper-strengthening effects. Carbohydr. Polym. 88: 1258–1263, https://doi.org/10.1016/j.carbpol.2012.02.002.10.1016/j.carbpol.2012.02.002 ↗
7. Bhaduri, S.K., Ghosh, I.N., and Sarkar, N.D. (1995). Ramie hemicellulose as beater additive in paper making from jute-stick kraft pulp. Ind. Crops Prod. Elsevier 4: 79–84.10.1016/0926-6690(95)00018-8 ↗
8. Christiernin, M., Henriksson, G., Lindström, M.E., Brumer, H., Teeri, T.T., Lindström, T., and Laine, J. (2003). The effects of xyloglucan on the properties of paper made from bleached kraft pulp. Nord. Pulp Pap. Res. J. 18: 182–187, https://doi.org/10.3183/npprj-2003-18-02-p182-187.10.3183/npprj-2003-18-02-p182-187 ↗
9. Chung, N.H. and Hoang, P.H. (2019). Preparation of oat spelt xylan and its application as additive for enhancement of paper properties. Cellul. Chem. Technol. 53: 499–507, https://doi.org/10.35812/cellulosechemtechnol.2019.53.50.10.35812/CelluloseChemTechnol.2019.53.50 ↗
10. Converti, A., Domínguez, J.M., Perego, P., Da Silva, S.S., and Zilli, M. (2000). Wood hydrolysis and hydrolyzate detoxification for subsequent xylitol production. Chem. Eng. Technol. Ind. Chem. Plant Equip. Process Eng. Biotech. 23: 1013–1020.10.1002/1521-4125(200011)23:11<1013::AID-CEAT1013>3.3.CO;2-3 ↗
11. Deutschle, A.L., Römhild, K., Meister, F., Janzon, R., Riegert, C., and Saake, B. (2014). Effects of cationic xylan from annual plants on the mechanical properties of paper. Carbohydr. Polym. Elsevier 102: 627–635, https://doi.org/10.1016/j.carbpol.2013.12.016.10.1016/j.carbpol.2013.12.016 ↗
12. Ebringerová, A., Hromadkova, Z., Kačuráková, M., and Antal, M. (1994). Quaternized xylans: synthesis and structural characterization. Carbohydr. Polym. Elsevier 24: 301–308, https://doi.org/10.1016/0144-8617(94)90075-2.10.1016/0144-8617(94)90075-2 ↗
13. Fatehi, P. (2011). Importance of charge density of cationic additives on increasing paper strength, pulp pap.-can., pulp & paper Canada magazine group-big magazine lp 80 valleybrook. Toronto 112: 28–34.
14. Fineman, M.N. (1952). The role of hemicelluloses in the mechanism of wet strength. Tappi 35: 320–324.
15. Fuhrmann, A. and Krogerus, B. (2009). Xylan from bleached hardwood pulp-new opportunities. TAPPI Eng. Pulping Environ. Conf. Memphis TN U. S.: 11–14.
16. Gallina, G., Cabeza, Á., Grénman, H., Biasi, P., García-Serna, J., and Salmi, T. (2018). Hemicellulose extraction by hot pressurized water pretreatment at 160 ºC for 10 different woods: yield and molecular weight. J. Supercrit. Fluids 133: 716–725, https://doi.org/10.1016/j.supflu.2017.10.001.10.1016/j.supflu.2017.10.001 ↗
17. Haack, V., Heinze, T., Oelmeyer, G., and Kulicke, W.M. (2002). Starch derivatives of high degree of functionalization, 8. Synthesis and flocculation behavior of cationic starch polyelectrolytes. Macromol. Mater. Eng. 287: 495–502, https://doi.org/10.1002/1439-2054(20020801)287:8<495::aid-mame495>3.0.co;2-k.10.1002/1439-2054(20020801)287:8<495::AID-MAME495>3.0.CO;2-K ↗
18. Helmerius, J., von Walter, J.V., Rova, U., Berglund, K.A., and Hodge, D.B. (2010). Impact of hemicellulose pre-extraction for bioconversion on birch Kraft pulp properties. Bioresour. Technol. Elsevier 101: 5996–6005, https://doi.org/10.1016/j.biortech.2010.03.029.10.1016/j.biortech.2010.03.029 ↗
19. Holtzapple, M.T. (2003). Hemicelluloses in: Encyclopedia of food Sciences and nutrition, 2nd ed. Elsevier, Amsterdam, pp. 3060–3071.10.1016/B0-12-227055-X/00589-7 ↗
20. Hu, G., Fu, S., and Liumaki, H. (2013). Hemicellulose in pulp affects paper properties and printability. Appita Technol. Innov. Manuf. Environ. 66: 139–144.
21. Hubbe, M.A. (2019). Nanocellulose, cationic starch and paper strength. Appita J., Appita Inc. Macleod, VIC 72: 82–94.
22. Jahan, M.S., Sultana, N., Rahman, M., and Quaiyyum, A. (2013). An integrated biorefinery initiative in producing dissolving pulp from agricultural wastes. Biomass Convers. Biorefinery 3: 179–185, https://doi.org/10.1007/s13399-012-0067-x.10.1007/s13399-012-0067-x ↗
23. Jenkins, S. (2009) The improvement of dry strength by synthetic polymers. In: Thorn, I., and Au, C.O. (Eds.), Appl. wet-end pap. chem.. Springer, Netherlands, Dordrecht, pp. 137–146.10.1007/978-1-4020-6038-0_7 ↗
24. Kavaliauskaite, R., Klimaviciute, R., and Zemaitaitis, A. (2008). Factors influencing production of cationic starches. Carbohydr. Polym. Elsevier 73: 665–675, https://doi.org/10.1016/j.carbpol.2008.01.019.10.1016/j.carbpol.2008.01.019 ↗
25. Kochumalayil, J.J. and Berglund, L.A. (2014). Water-soluble hemicelluloses for high humidity applications–enzymatic modification of xyloglucan for mechanical and oxygen barrier properties. Green Chem. 16: 1904–1910, https://doi.org/10.1039/c3gc41823e.10.1039/C3GC41823E ↗
26. Köhnke, T. and Gatenholm, P. (2007). The effect of controlled glucuronoxylan adsorption on drying-induced strength loss of bleached softwood pulp. Nord. Pulp Pap. Res. J. 22: 508–515, https://doi.org/10.3183/npprj-2007-22-04-p508-515.10.3183/npprj-2007-22-04-p508-515 ↗
27. Köhnke, T., Pujolras, C., Roubroeks, J.P., and Gatenholm, P. (2008). The effect of barley husk arabinoxylan adsorption on the properties of cellulose fibres. Cellulose 15: 537–546, https://doi.org/10.1007/s10570-008-9209-5.10.1007/s10570-008-9209-5 ↗
28. Köhnke, T., Brelid, H., and Westman, G. (2009). Adsorption of cationized barley husk xylan on kraft pulp fibres: influence of degree of cationization on adsorption characteristics. Cellulose 16: 1109–1121, https://doi.org/10.1007/s10570-009-9341-x.10.1007/s10570-009-9341-x ↗
29. Köhnke, T., Lund, K., Brelid, H., and Westman, G. (2010). Kraft pulp hornification: a closer look at the preventive effect gained by glucuronoxylan adsorption. Carbohydr. Polym. Elsevier 81: 226–233, https://doi.org/10.1016/j.carbpol.2010.02.023.10.1016/j.carbpol.2010.02.023 ↗
30. Kong, F., Guo, Y., Liu, Z., Wang, S., and Lucia, L.A. (2018). Synthesis of cationic xylan derivatives and application as strengthening agents in papermaking. BioResources 13, https://doi.org/10.15376/biores.13.2.2960-2976.10.15376/biores.13.2.2960-2976 ↗
31. Lan, X., Fu, S., and Kong, Y. (2024). A new recognition of the binding of cellulose fibrils in papermaking by probing interaction between nanocellulose and cationic hemicellulose. Cellulose 31: 5823–5842, https://doi.org/10.1007/s10570-024-05926-5.10.1007/s10570-024-05926-5 ↗
32. Lima, D.U., Oliveira, R.C., and Buckeridge, M.S. (2003). Seed storage hemicelluloses as wet-end additives in papermaking. Carbohydr. Polym. Elsevier 52: 367–373, https://doi.org/10.1016/s0144-8617(03)00008-0.10.1016/S0144-8617(03)00008-0 ↗
33. Lindström, T., Wågberg, L., and Larsson, T. (2005) On the nature of joint strength in paper-A review of dry and wet strength resins used in paper manufacturing. 13th fundamental research symposium, Vol. 32. The Pulp and Paper Fundamental Research Society, Cambridge, UK, pp. 457–562.10.15376/frc.2005.1.457 ↗
34. Link, W.F. (1962). Polyacrylamide as a stock additive. Tappi 45: 326–333.
35. Liu, Z., Ni, Y., Fatehi, P., and Saeed, A. (2011). Isolation and cationization of hemicelluloses from pre-hydrolysis liquor of kraft-based dissolving pulp production process. Biomass Bioenergy Elsevier 35: 1789–1796, https://doi.org/10.1016/j.biombioe.2011.01.008.10.1016/j.biombioe.2011.01.008 ↗
36. Liu, H., Hu, H., Jahan, M.S., and Ni, Y. (2013). Furfural formation from the pre-hydrolysis liquor of a hardwood kraft-based dissolving pulp production process. Bioresour. Technol. 131: 315–320, https://doi.org/10.1016/j.biortech.2012.12.158.10.1016/j.biortech.2012.12.158 ↗
37. Lu, C., Rosencrance, S., Swales, D., Covarrubias, R., and Hubbe, M.A. (2020). Dry strength: strategies for stronger paper. Make Paper Prod. Stand Out Strat. Use Wet End Chem Addit.: 155–196.
38. Lyytikainen, K., Saukkonen, E., Vaisanen, M., Timonen, J., and Backfolk, K. (2014). Effect of reduced pulp xylan content on wet end chemistry and paper properties-a pilot scale study. TAPPI J., Tech assoc pulp paper ind inc 15 technology park South, norcross, GA 30092 USA 13: 29–37, https://doi.org/10.32964/tj13.2.29.10.32964/TJ13.2.29 ↗
39. Moss, P.A. and Pere, J. (2006). Microscopical study on the effects of partial removal of xylan on the swelling properties of birch kraft pulp fibres. Nord. Pulp Pap. Res. J. 21: 8–12, https://doi.org/10.3183/npprj-2006-21-01-p008-012.10.3183/npprj-2006-21-01-p008-012 ↗
40. Pere, J., Pääkkönen, E., Ji, Y., and Retulainen, E. (2019). Influence of the hemicellulose content on the fiber properties, strength, and formability of handsheets. BioResources, North Carolina State University 14: 251–263.10.15376/biores.14.1.251-263 ↗
41. Postma, D. (2012). Chemical and physical modification of wood based hemicelluloses for use in the pulp and paper industry, PhD Thesis. Stellenbosch University, Stellenbosch.
42. Potthast, A., Röhrling, J., Rosenau, T., Borgards, A., Sixta, H., and Kosma, P. (2003). A novel method for the determination of carbonyl groups in cellulosics by fluorescence labeling. 3. Monitoring oxidative processes. Biomacromolecules 4: 743–749, https://doi.org/10.1021/bm025759c.10.1021/bm025759c ↗
43. Ramírez, F., Puls, J., Zúñiga, V., and Saake, B. (2008). Sorption of corn cob and oat spelt arabinoxylan onto softwood kraft pulp. hfsg 62: 329–337, https://doi.org/10.1515/hf.2008.059.10.1515/HF.2008.059 ↗
44. Ren, J.L., Sun, R.C., Liu, C.F., Chao, Z.Y., and Luo, W. (2006). Two-step preparation and thermal characterization of cationic 2-hydroxypropyltrimethylammonium chloride hemicellulose polymers from sugarcane bagasse. Polym. Degrad. Stab. Elsevier 91: 2579–2587, https://doi.org/10.1016/j.polymdegradstab.2006.05.008.10.1016/j.polymdegradstab.2006.05.008 ↗
45. Ren, J.L., Sun, R.C., Liu, C.F., Lin, L., and He, B.H. (2007). Synthesis and characterization of novel cationic SCB hemicelluloses with a low degree of substitution. Carbohydr. Polym. Elsevier 67: 347–357, https://doi.org/10.1016/j.carbpol.2006.06.002.10.1016/j.carbpol.2006.06.002 ↗
46. Ren, J.L., Peng, F., Sun, R.C., Liu, C.F., Cao, Z.N., Luo, W., and Tang, J.N. (2008). Synthesis of cationic hemicellulosic derivatives with a low degree of substitution in dimethyl sulfoxide media. J. Appl. Polym. Sci. 109: 2711–2717, https://doi.org/10.1002/app.28256.10.1002/app.28256 ↗
47. Ren, J.L., Peng, X.W., Peng, F., and Sun, R.C. (2011). The preparation and application of the cationic biopolymer based on xylan-rich hemicelluloses from agricultural biomass. Adv. Mater. Res. Trans Tech Publ. 239: 463–467, https://doi.org/10.4028/www.scientific.net/amr.239-242.463.10.4028/www.scientific.net/AMR.239-242.463 ↗
48. Robinson, J.V. (1980). Fiber bonding. In: Casey, J.P. (Ed.). Pulp and paper chemistry and chemical technology, 3rd ed., Vol. 2. John Wiley & Sons, Inc., New York, NY.
49. Roy, S., Rahman, M.M., Ferdous, T., Likhon, M.N.A., and Jahan, M.S. (2024). Preparation of chitosan derivative and its application in papermaking. Int. J. Biol. Macromol. Elsevier 256: 128371, https://doi.org/10.1016/j.ijbiomac.2023.128371.10.1016/j.ijbiomac.2023.128371 ↗
50. Rydholm, S.A. (1965). Pulping processes. Interscience Publ, Inc, New York.
51. Saeed, A., Jahan, M.S., Li, H., Liu, Z., Ni, Y., and van Heiningen, A. (2012). Mass balances of components dissolved in the pre-hydrolysis liquor of kraft-based dissolving pulp production process from Canadian hardwoods. Biomass Bioenergy 39: 14–19, https://doi.org/10.1016/j.biombioe.2010.08.039.10.1016/j.biombioe.2010.08.039 ↗
52. Schönberg, C., Oksanen, T., Suurnäkki, A., Kettunen, H., and Buchert, J. (2001). The importance of xylan for the strength properties of spruce kraft pulp fibres. Holzforschung 55: 639–644, https://doi.org/10.1515/hf.2001.104.10.1515/HF.2001.104 ↗
53. Schwikal, K., Heinze, T., Ebringerová, A., and Petzold, K. (2005). Cationic xylan derivatives with high degree of functionalization. Macromol. Symp. 232: 49–56.10.1002/masy.200551406 ↗
54. Schwikal, K., Heinze, T., Saake, B., Puls, J., Kaya, A., and Esker, A.R. (2011). Properties of spruce sulfite pulp and birch kraft pulp after sorption of cationic birch xylan. Cellulose 18: 727–737, https://doi.org/10.1007/s10570-011-9526-y.10.1007/s10570-011-9526-y ↗
55. Shen, J. and Fatehi, P. (2013). A review on the use of lignocellulose-derived chemicals in wet-end application of papermaking. Curr. Org. Chem. Bentham Sci. Pub. 17: 1647–1654, https://doi.org/10.2174/13852728113179990075.10.2174/13852728113179990075 ↗
56. Sitch, D.A. and Marshall, H.B. (1950). The effect of hemicelluloses on the papermaking properties of white birch, can. J. Res. 28f: 376–389, https://doi.org/10.1139/cjr50f-034.10.1139/cjr50f-034 ↗
57. Unlu, O., Atik, C., and Aytac, A. (2024). Cationic xylan modified precipitated calcium carbonate filler: preparation, its use in papermaking and evaluation of influence on paper properties. Cellulose 32: 1–25, https://doi.org/10.1007/s10570-024-06357-y.10.1007/s10570-024-06357-y ↗
58. van Heiningen, A. (2006). Converting a Kraft pulp mill into an integrated forest biorefinery. Pulp Pap. Can 107: 38–43.
59. Wägberg, L. and Lindstrom, T. (1987). Flocculation of cellulosic fibers by cationic polyacrylamides with different charge densities. Nord. Pulp Pap. Res. J. 2: 152–160, https://doi.org/10.3183/npprj-1987-02-04-p152-160.10.3183/npprj-1987-02-04-p152-160 ↗
60. Yang, H., Qiu, L., Qian, X., and Shen, J. (2013). Filler modification for papermaking with cationic starch and carboxymethyl cellulose: a comparative study. BioResources 8, https://doi.org/10.15376/biores.8.4.5449-5460.10.15376/biores.8.4.5449-5460 ↗
61. Zhao, M., Robertsén, L., Wågberg, L., and Pettersson, T. (2022). Adsorption of paper strength additives to hardwood fibres with different surface charges and their effect on paper strength. Cellulose 29: 2617–2632, https://doi.org/10.1007/s10570-022-04447-3.10.1007/s10570-022-04447-3 ↗