journal article·2018-09-25

Engineered porous calcium silicate as paper filler: effect of filler morphology on paper properties

Shunxi Song, Xiaoli Zhen, Meiyun Zhang, Lin Li, Bin Yang, Peng Lu

Publisher page

Abstract

Abstract Developing engineered filler with special morphology to increase filler content and deliver paper desirable properties has been deserved much concern. In this work, two engineered calcium silicate fillers with different morphology, namely fly ash based calcium silicate (FACS), fibrous calcium silicate (FCS) were adopted to investigate the effect of filler morphology on paper properties, and natural wollastonite was used for comparison. It is found that FACS exhibits a wrinkled, porous surface while FCS reveals spherical agglomerates composed of needle-like particles. Physical tests demonstrated that in comparison with natural wollastonite with discrete shape, the aggregated porous structure of FACS and FCS showed noticeable improvement in bulk and opacity due to their high specific surface area (112 m2/g v.s 29 m2/g). At around 40 % filler content, the bulk of FACS and FCS filled handsheets increased 59.6 % and 43.8 %, respectively. The findings suggested that the engineered porous calcium silicate can be potentially used as paper filler in light weighted paper.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Cellulose Research Studies · Aerogels and thermal insulation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Demonstration Center for Experimental Light Chemistry Engineering Education (Shaanxi University of Science & Technology) , Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development , Key Laboratory of Paper based Functional Materials of China National Light Industry , College of Bioresources Chemical and Materials Engineering , Shaanxi University of Science & Technology , Xi’an 710021 , China

Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control , Nanning 530004 , China

Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education/Shandong Province , Qilu University of Technology , Jinan 250353 , China

Funding

National Natural Science Foundation of China · Ministry of Education of the People's Republic of China · Shaanxi University of Science and Technology

References (33)

Show source-provided references
1. Adel, A.M., Ahmed, N.M., Diab, M.A., Selim, M.M. (2016) The influence of TiO2/CC core/shell pigments on the properties of paper sheets. Powder Technol. 291:437–447.10.1016/j.powtec.2016.01.007 ↗
2. Beazley, K.M., Petereit, H. (1975) Effect of China clay and calcium carbonate on paper properties. Wochenbl. Papierfabr. 103(4):143–147.
3. Bown, R. (1998) Particle size, shape, and structure of paper fillers and their effect on paper properties. Pap. Technol. 39(2):44–48.
4. Chauhan, V.S., Bhardwaj, N.K. (2013) Preflocculated talc using cationic starch for improvement in paper properties. Appita J. 66(3):220–228.
5. Chen, X., Qian, X., An, X. (2011) Using calcium carbonate whiskers as papermaking filler. BioRes. 6(3):2435–2447.10.15376/biores.6.3.2435-2447 ↗
6. El-Sherbiny, S., El-Sheikh, S.M., Barhoum, A. (2015) Preparation and modification of nano calcium carbonate filler from waste marble dust and commercial limestone for papermaking wet end application. Powder Technol. 279:290–300.10.1016/j.powtec.2015.04.006 ↗
7. Fan, J., Li, T., Ren, Y.H., Qian, X.R., Wang, Q.W., Shen, J., Ni, Y.H. (2017a) Interaction between two oppositely charged starches in an aqueous medium containing suspended mineral particles as a basis for the generation of cellulose-compatible composites. Ind. Crop. Prod. 97:417–424.10.1016/j.indcrop.2016.12.048 ↗
8. Fan, H., Qi, Y., Cai, J., Rong, Z., Liu, J. (2017b) Fly ash based composite fillers modified by carbonation and the properties of filled paper. Nord. Pulp Pap. Res. J. 32(4):666–673.10.3183/npprj-2017-32-04_p666-673_liu ↗
9. Gill, R.A. (1989) The behavior of on-site synthesized precipitated calcium carbonates and other calcium carbonate fillers on paper properties. Nord. Pulp Pap. Res. J. 4(2):120–127.10.3183/npprj-1989-04-02-p120-127 ↗
10. Gill, R., Scott, W. (1987) The relative effects of different calcium carbonate filler pigments on optical properties. Tappi J. 1:93–98.
11. Han, Y.R., Seo, Y.B. (1997) Effect of particle shape and size of calcium carbonate on physical properties of paper. J. Korea Tappi 29(1):7–12.
12. He, M., Cho, B.U., Won, J.M. (2016) Effect of precipitated calcium carbonate - Cellulose nanofibrils composite filler on paper properties. Carbohydr. Polym. 136:820–825.10.1016/j.carbpol.2015.09.069 ↗
13. Holik, H. (2013) Handbook of Paper and Board (Volume 1). Wiley-VCH, Singapore. pp. 113–114.10.1002/9783527652495 ↗
14. Hubbe, M.A., Gill, R.A. (2004) Filler particle shape vs. paper properties - A review. In: TAPPI Pap. Summit-Spring Tech. Int. Environ. Conf. TAPPI Press, Atlanta, GA. pp. 141–150.
15. Järnström, L., Wikström, M., Rigdahl, M. (2000) Porous mineral particles as coating pigments. Nord. Pulp Pap. Res. J. 15:88–97.10.3183/npprj-2000-15-02-p088-097 ↗
16. Krogerus, B. (1999) Papermaking Chemistry. Fapet Oy, Finland. pp. 135–137.
17. Li, T., Fan, J., Chen, W., Shu, J., Qian, X., Wei, H., Wang, Q., Shen, J. (2016) Coaggregation of mineral filler particles and starch granules as a basis for improving filler-fiber interaction in paper production. Carbohydr. Polym. 149:20–27.10.1016/j.carbpol.2016.04.082 ↗
18. Liu, H., Chen, Y., Zhang, H., Yuan, Z., Zou, X., Zhou, Y., Ni, Y. (2012) Increasing the use of high-yield pulp in coated high-quality wood-free papers: from laboratory demonstration to mill trials. Ind. Eng. Chem. Res. 51(11):4240–4246.10.1021/ie2029514 ↗
19. Lourenço, A.F., Gamelas, J.A.F., Zscherneck, C., Ferreira, P.J. (2013) Evaluation of silica-coated PCC as new modified filler for papermaking. Ind. Eng. Chem. Res. 52(14):5095–5099.10.1021/ie3035477 ↗
20. Mathur, V.K. (2004) Multi-phase calcium silicate hydrates, methods for their preparation, and improved paper and pigment products produced therewith, WO 01/14274 A1, 1 March 2001.
21. Mathur, V.K. (2009) Fibrous Fillers to Manufacture Ultra High Ash/Performance Paper, Project Report, G.R. International, Washington, America.
22. Mathur, V.K., Joyce, M.K. (2004) Novel silicate fibrous fillers and their application in paper. In: TAPPI 2004 Pap. Summit Spring Tech. Conf.
23. Shen, J., Song, Z.Q., Qian, X.R., Liu, W., Yang, F. (2010) Filler engineering for papermaking: comparision with fiber engineering and some important research topics. BioRes. 5(2):510–513.10.15376/biores.5.2.510-513 ↗
24. Sinha, A.S.K. (2008) Effects of pulverized coal fly-ash addition as a wet-end filler in papermaking. Tappi J. 7(9):3–7.10.32964/TJ7.9.3 ↗
25. Song, S., Zhang, M., He, Z., Li, J.Z., Ni, Y. (2012) Investigation on a novel fly ash based calcium silicate filler: effect of particle size on paper properties. Ind. Eng. Chem. Res. 51:16377–16384.10.1021/ie3028813 ↗
26. Song, S., Zhang, M., Yuan, Z., Wang, J., Sun, J., Ni, Y. (2014) The potential of fly ash-based calcium silicate as paper filler: physical properties and printability. Tappi J. 13(10):49–57.10.32964/TJ13.10.49 ↗
27. Sood, Y.V., Tyagi, R., Tyagi, S., Pande, P.C., Tondon, R. (2010) Surface charge of different paper making raw materials and its influence on paper properties. J. Sci. Ind. Res. 69(4):300–304.
28. Sun, D, Song, B., Wang, C. (2011) Properties of synthetic calcium silicate and its application in wastewater treatment. Pap. Papermak 30(6):52–54.
29. Thorn, I., Au, C.O. (2009) Applications of Wet-End Paper Chemistry. Springer, New York. pp. 126–132.10.1007/978-1-4020-6038-0 ↗
30. Thorp, B. (2005) Engineered fillers: an Agenda 2020 goal. Solutions 88(5):45–48.
31. Velho, J. (2002) How mineral fillers influence paper properties: some guidelines. In: Iberoamerican Congress on Pulp and Paper Research.
32. Willets, W.R., Brooks, A.M., Craig, W.L., Haywood, G., Albert, C.G., Kenney, J.W., Leppla, P.W., Belcher, V.A., Mcclellan, R.S., DenHam, F.H. (1958) Paper Loading Materials, Technical Association of the Pulp and Paper Industry, America, pp. 55–56.
33. Xue, H., Wang, G., Hu, M., Chen, B. (2015) Modification of wollastonite by acid treatment and alkali-induced redeposition for use as papermaking filler. Powder Technol. 276:193–199.10.1016/j.powtec.2015.02.030 ↗