journal article·2019-03-26Open access

Improving fire retardancy of cellulosic thermal insulating materials by coating with bio-based fire retardants

Chao Zheng, Dongfang Li, Monica Ek

Abstract

Abstract Sustainable thermal insulating materials produced from cellulosic fibers provide a viable alternative to plastic insulation foams. Industrially available, abundant, and inexpensive mechanical pulp fiber and recycled textile fiber provide potential raw materials to produce thermal insulating materials. To improve the fire retardancy of low-density thermal insulating materials produced from recycled cotton denim and mechanical pulp fibers, bio-based fire retardants, such as sulfonated kraft lignin, kraft lignin, and nanoclays, were coated onto sustainable insulating material surfaces to enhance their fire retardancy. Microfibrillated cellulose was used as a bio-based binder in the coating formula to disperse and bond the fire-retardant particles to the underlying thermal insulating materials. The flammability of the coated thermal insulating materials was tested using a single-flame source test and cone calorimetry. The results showed that sulfonated kraft lignin-coated cellulosic thermal insulating materials had a better fire retardancy compared with that for kraft lignin with a coating weight of 0.8 kg/m2. Nanoclay-coated samples had the best fire retardancy and did not ignite under a heat flux of 25 kW/m2, as shown by cone calorimetry and single-flame source tests, respectively. These cost-efficient and bio-based fire retardants have broad applications for improving fire retardancy of sustainable thermal insulating materials.
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Research context

OpenAlex topics: Flame retardant materials and properties · Natural Fiber Reinforced Composites · Lignin and Wood Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Fiber and Polymer Technology , KTH Royal Institute of Technology , Teknikringen 56-58 , SE-100 44 Stockholm , Sweden

Funding

Svenska Forskningsrådet Formas

References (43)

Show source-provided references
1. Altun, Y., Doğan, M., et al. (2016) The effect of red phosphorus on the fire properties of intumescent pine wood flour – LDPE composites. Fire Mater. 40(5):697–703.10.1002/fam.2336 ↗
2. Bertini, F., Canetti, M., et al. (2012) Effect of ligno-derivatives on thermal properties and degradation behavior of poly(3-hydroxybutyrate)-based biocomposites. Polym. Degrad. Stab. 97(10):1979–1987.10.1016/j.polymdegradstab.2012.03.009 ↗
3. Brohez, S. (2005) Uncertainty analysis of heat release rate measurement from oxygen consumption calorimetry. Fire Mater. 29(6):383–394.10.1002/fam.895 ↗
4. Camino, G., Duquesne, S., et al. (2001) Mechanism of expandable graphite fire retardant action in polyurethanes. In: Fire and Polymers, Eds. Nelson, G.L., Wilkie, C.A., American Chemical Society, Washington, DC. pp. 90–109.10.1021/bk-2001-0797.ch008 ↗
5. Canetti, M., Bertini, F. (2007) Supermolecular structure and thermal properties of poly(ethylene terephthalate)/lignin composites. Compos. Sci. Technol. 67(15–16):3151–3157.10.1016/j.compscitech.2007.04.013 ↗
6. Canetti, M., Bertini, F., et al. (2006) Thermal degradation behaviour of isotactic polypropylene blended with lignin. Polym. Degrad. Stab. 91(3):494–498.10.1016/j.polymdegradstab.2005.01.052 ↗
7. CEN (2007) Fire classification of construction products and building elements. Classification using test data from reaction to fire tests. Standard 13501-1 European Committee for Standardization, Brussels, Belgium.
8. CEN ISO (2010) Reaction to fire tests. Ignitability of products subjected to direct impingement of flame. Single-flame source test. Standard 11925-2 European Committee for Standardization and International Organization for Standardization, Belgium and Switzerland.
9. Cervantes-Uc, J.M., Cauich-Rodríguez, J.V., et al. (2007) Thermal degradation of commercially available organoclays studied by TGA–FTIR. Thermochim. Acta 457(1–2):92–102.10.1016/j.tca.2007.03.008 ↗
10. Chatterjee, S., Shanmuganathan, K., et al. (2017) Fire-retardant, self-extinguishing inorganic/polymer composite memory foams. ACS Appl. Mater. Interfaces 9(51):44864–44872.10.1021/acsami.7b16808 ↗
11. Dilmac, S., Kesen, N. (2003) A comparison of new Turkish thermal insulation standard (TS 825), ISO 9164, EN 832 and German regulation. Energy Build. 35(2):161–174.10.1016/S0378-7788(02)00020-8 ↗
12. El-Darwish, I., Gomaa, M. (2017) Retrofitting strategy for building envelopes to achieve energy efficiency. Alex. Eng. J. 56(4):579–589.10.1016/j.aej.2017.05.011 ↗
13. Ferry, L., Dorez, G., et al. (2015) Chemical modification of lignin by phosphorus molecules to improve the fire behavior of polybutylene succinate. Polym. Degrad. Stab. 113:135–143.10.1016/j.polymdegradstab.2014.12.015 ↗
14. Gibson, G., Ramsson, T., et al. (2012) Building shell and thermal insulation-technology brief R01. The Energy Technology Systems Analysis Program. https://iea-etsap.org.
15. Han, T., Sophonrat, N., et al. (2018) Evolution of sulfur during fast pyrolysis of sulfonated kraft lignin. J. Anal. Appl. Pyrolysis 133:162–168.10.1016/j.jaap.2018.04.006 ↗
16. Hu, Y., Yu, B., et al. (2017) Novel fire-retardant coatings. In: Novel Fire Retardant Polymers and Composite Materials, Ed. Wang, D.-Y., Woodhead Publishing, Cambridge, UK. pp. 53–91.10.1016/B978-0-08-100136-3.00003-0 ↗
17. ISO (2012) Reaction-to-fire tests heat release, smoke production and mass loss rate part 3: Guidance on measurement. Standard 5660-3 International Organization for Standardization, Switzerland.
18. ISO (2015) Standard 5660-1: Reaction-to-fire tests heat release, smoke production and mass loss rate part 1: Heat release rate (cone calorimeter method) and smoke production rate (dynamic measurement). International Organization for Standardization, Switzerland.
19. Konduri, M.K.R., Fatehi, P. (2015) Production of water-soluble hardwood kraft lignin via sulfomethylation using formaldehyde and sodium sulfite. ACS Sustain. Chem. Eng. 3(6):1172–1182.10.1021/acssuschemeng.5b00098 ↗
20. Kopczyński, M., Plis, A., et al. (2015) Thermogravimetric and kinetic analysis of raw and torrefied biomass combustion. Chem. Eng. Prog. 36(2):209–223.10.1515/cpe-2015-0014 ↗
21. Lacoste, C., El Hage, R., et al. (2018) Sodium alginate adhesives as binders in wood fibers/textile waste fibers biocomposites for building insulation. Carbohydr. Polym. 184:1–8.10.1016/j.carbpol.2017.12.019 ↗
22. Laoutid, F., Bonnaud, L., et al. (2009) New prospects in flame retardant polymer materials: From fundamentals to nanocomposites. Mater. Sci. Eng., R Rep. 63(3):100–125.10.1016/j.mser.2008.09.002 ↗
23. Mandlekar, N., Malucelli, G., et al. (2018) Fire retardant action of zinc phosphinate and polyamide 11 blend containing lignin as a carbon source. Polym. Degrad. Stab. 153:63–74.10.1016/j.polymdegradstab.2018.04.019 ↗
24. Marney, D., Russell, L., et al. (2008) The suitability of halloysite nanotubes as a fire retardant for nylon 6. Polym. Degrad. Stab. 93(10):1971–1978.10.1016/j.polymdegradstab.2008.06.018 ↗
25. Miao, X., Tan, D.M., et al. (2008) Mechanical and biological properties of hydroxyapatite/tricalcium phosphate scaffolds coated with poly(lactic-co-glycolic acid). Acta Biomater. 4(3):638–645.10.1016/j.actbio.2007.10.006 ↗
26. Moriana, R., Vilaplana, F., et al. (2016) Cellulose nanocrystals from forest residues as reinforcing agents for composites: A study from macro- to nano-dimensions. Carbohydr. Polym. 139:139–149.10.1016/j.carbpol.2015.12.020 ↗
27. Mousavioun, P., Doherty, W.O.S., et al. (2010) Thermal stability and miscibility of poly(hydroxybutyrate) and soda lignin blends. Ind. Crop. Prod. 32(3):656–661.10.1016/j.indcrop.2010.08.001 ↗
28. Musbah Redwan, A., Haji Badri, K., et al. (2015) The effect of aluminium hydroxide (ATH) on the mechanical properties and fire resistivity of palm-based fibreboard prepared by pre-polymerization method. Adv. Mater. Res. 1087:287–292.10.4028/www.scientific.net/AMR.1087.287 ↗
29. Ouyang, X., Ke, L., et al. (2009) Sulfonation of alkali lignin and its potential use in dispersant for cement. J. Dispers. Sci. Technol. 30(1):1–6.10.1080/01932690802473560 ↗
30. Pfundstein, M., Gellert, R., et al. Insulating Materials: Principles, Materials, Applications. Walter de Gruyter, Regensburg, Germany, 2008.10.11129/detail.9783034614757 ↗
31. Prieur, B., Meub, M., et al. (2016) Phosphorylation of lignin to flame retard acrylonitrile butadiene styrene (ABS). Polym. Degrad. Stab. 127:32–43.10.1016/j.polymdegradstab.2016.01.015 ↗
32. Pöhler, T., Jetsu, P., et al. (2017) Use of papermaking pulps in foam-formed thermal insulation materials. Nord. Pulp Pap. Res. J. 32(03):367–374.10.3183/npprj-2017-32-03-p367-374 ↗
33. Richmond, F. Cellulose Nanofibers Use in Coated Paper. The University of Maine, Orono, USA, 2014.
34. Scheiding, W. (2000) Thermal conductivity of wood fibers for insulation panels. Holz Roh- Werkst. 58(3):0177–0181.10.1007/s001070050409 ↗
35. Seefeldt, H., Braun, U., et al. (2012) Residue stabilization in the fire retardancy of wood–plastic composites: Combination of ammonium polyphosphate, expandable graphite, and red phosphorus. Macromol. Chem. Phys. 213(22):2370–2377.10.1002/macp.201200119 ↗
36. Shan, G., Jin, W., et al. (2015) Flame-retardant polymer nanocomposites and their heat-release rates. J. Hazard. Toxic Radioact. Waste 19(4):04015006.10.1061/(ASCE)HZ.2153-5515.0000269 ↗
37. Simmler, H., Brunner, S., et al. (2005) Vacuum insulation panels-study on VIP-components and panels for service life prediction of VIP in building applications (subtask a). http://www.iea-ebc.org.
38. Song, P., Cao, Z., et al. (2011) Thermal degradation and flame retardancy properties of ABS/lignin: Effects of lignin content and reactive compatibilization. Thermochim. Acta 518(1–2):59–65.10.1016/j.tca.2011.02.007 ↗
39. Statheropoulos, M., Kyriakou, S. (2000) Quantitative thermogravimetric-mass spectrometric analysis for monitoring the effects of fire retardants on cellulose pyrolysis. Anal. Chim. Acta 409(1):203–214.10.1016/S0003-2670(99)00859-4 ↗
40. Weil, E.D. (2011) Fire-protective and flame-retardant coatings – a state-of-the-art review. J. Fire Sci. 29(3):259–296.10.1177/0734904110395469 ↗
41. Yurddaskal, M., Celik, E. (2018) Effect of halogen-free nanoparticles on the mechanical, structural, thermal and flame retardant properties of polymer matrix composite. Compos. Struct. 183:381–388.10.1016/j.compstruct.2017.03.093 ↗
42. Zheng, C., Li, D., et al. (2017a) Cellulose-fiber-based insulation materials with improved reaction-to-fire properties. Nord. Pulp Pap. Res. J. 32(3):466–472.10.3183/npprj-2017-32-03-p466-472 ↗
43. Zheng, C., Li, D., et al. (2017b) Cellulose fiber based fungal and water resistant insulation materials. Holzforschung 71(7–8):633–639.10.1515/hf-2016-0162 ↗