journal article·2020-06-25Open access

High strength paper from high yield pulps by means of hot-pressing

Tove Joelsson, Gunilla Pettersson, Sven Norgren, Anna Svedberg, Hans Höglund, Per Engstrand

Abstract

Abstract The hypothesis is that it should be possible to modify papermaking conditions in line with the softening properties of high yield pulp fibres and achieve similar strength properties to conventional chemical pulp based paper. We therefore investigated the rheological and physical properties of high yield pulp based papers during hot-pressing. Our results confirm that increased temperature combined with sufficient pressure enables permanent densification by softening of lignin, producing very high tensile strength. This treatment also significantly improved the wet tensile strength in comparison to bleached kraft pulp without using wet strength agents. The high yield pulps used here were spruce based thermomechanical pulp, chemi-thermomechanical pulp, and high temperature chemi-thermomechanical pulp, and birch-aspen based neutral sulphite semi chemical pulp, with spruce-pine based bleached kraft pulp as reference. Rapid Köhten sheets of150\hspace{0.1667em}\text{g}/{\text{m}2}and 50 % dryness were hot-pressed in a cylinder-press at 20–200 °C, 7 MPa, and 1 m/min. The mechanical properties showed great improvements in these high yield pulp papers, with tensile index increased to 75 kNm/kg and compression strength index to 45 kNm/kg; levels close to and better than bleached kraft. Wet strength increased to 16 Nm/g compared to 5 Nm/g for bleached kraft.
Source: crossref · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Cellulose Research Studies · Lignin and Wood Chemistry · Material Properties and Processing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

6311 Mid Sweden University , Sundsvall , Sweden

MoRe Research Örnsköldsvik AB , Box 70 , Örnsköldsvik , Sweden

References (27)

Show source-provided references
1. Atack, D. (1972) On the characterization of pressurized refiner mechanical pulps. Sven. Papp.tidn. 75(3):89–94.10.1016/0014-4827(72)90523-X ↗
2. Back, E.L. (1984) A review of pressdrying. Tech. Report, D-224, STFI, Stockholm.
3. Back, E., Andersson, R. (1979) Multistage press drying of paper. Sven. Papp.tidn. 2:35–39.
4. Back, E., Salmén, L. (1982) Glass transitions of wood components hold implications for molding and pulping processes. Tappi J. 65(7):107–110.
5. Byrd, V.L. (1979) Press drying – Flow and adhesion of hemicellulose and lignin. Tappi J. 62(7):81–84.
6. Dunlop-Jones, N. (1991) Wet-strength chemistry. In: Pap. Chem.. Eds. Roberts, J. C. Chapman & Hall, New York, USA. pp. 76.10.1007/978-94-011-6474-0_6 ↗
7. Goring, D.A.I. (1963) Thermal softening of lignin, hemicellulose and cellulose. Pulp Pap. Mag. Can. 64(12):T517–T527.
8. Gupta, P.R., Rezanowich, A., Goring, D.A.I. (1962) The adhesive properties of lignin. Pulp Pap. Mag. Can. 63:21–30.
9. Irvine, G.M. (1984) The glass transition of lignin and hemicellulose and their measurement by differential thermal analysis. Tappi J. 67(5):118–121.
10. Irvine, G.M. (1985) The significance of the glass transition of lignin in thermomechanical pulping. Wood Sci. Technol. 19(2):139–149.10.1007/BF00353074 ↗
11. Klinga, N., Höglund, H., Sandberg, C. (2007) Paper properties of TMP and CTMP handsheets from spruce, as affected by the solids content from pressing. Nord. Pulp Pap. Res. J. 22(4):475–480.10.3183/npprj-2007-22-04-p475-480 ↗
12. Lehtinen, J. (1998) Condebelt board and paper drying. Dry. Technol. 16(6):1047–1073.10.1080/07373939808917453 ↗
13. Lindström, T., Wågberg, L., Larsson, T. (2005) On the nature of joint strength in paper – a review of dry and wet strength resins used in paper manufacturing. In: 13th Pulp Pap. Fundam. Res. Symp., Cambridge, UK. pp. 457–562.10.15376/frc.2005.1.457 ↗
14. Lucisano, M.F.C. (2002) On Heat and Paper: From Hot Pressing to Impulse Technology. Dr. Thesis, K. Tek. Högskolan, ISSN 1104-7003.
15. Mason, W.H. (1931) Process of making integral insulating board with hard welded surfaces. Patent number: US1812969.
16. Mason, W.H. (1937) Molding composition and process of making same. Patent number: US2080078.
17. Mason, W.H. (1938) Process of making ligno-cellulose fiber products. Patent number: US2120137.
18. Norgren, S., Pettersson, G., Höglund, H. (2018) Strong paper from spruce CTMP – Part II: Effect of pressing at nip press temperatures above the lignin softening temperature. Nord. Pulp Pap. Res. J. 33(1):142–149.10.1515/npprj-2018-3009 ↗
19. Olsson, A.M. (1997) The effect of lignin composition on the viscoelastic properties of wood. Nord. Pulp Pap. Res. J. 12(03):140–144.10.3183/npprj-1997-12-03-p140-144 ↗
20. Page, D.H. (1969) A theory for the tensile strength of paper. Tappi J. 52(4):674–681.
21. Pettersson, G., Norgren, S., Höglund, H. (2017) Strong paper from spruce CTMP – Part I. Nord. Pulp Pap. Res. J. 32(01):054–058.10.3183/NPPRJ-2017-32-01-p055-059 ↗
22. Rundlöf, M., Sjölund, A., Ström, H., Åsell, I., Wågberg, L. (2000) The effect of dissolved and colloidal substances released from TMP on the properties of TMP fines. Nord. Pulp Pap. Res. J. 15(4):256–265.10.3183/npprj-2000-15-04-p256-265 ↗
23. Salmén, L. (1984) Viscoelastic properties of in situ lignin under water-saturated conditions. J. Mater. Sci. 19(9):3090–3096.10.1007/BF01026988 ↗
24. Scott, J.A.N., Procter, A.R., Fergus, B.J., Goring, D.A.I. (1969) The application of ultraviolet microscopy to the distribution of lignin in wood description and validity of the technique. Wood Sci. Technol. 3(1):73–92.10.1007/BF00349985 ↗
25. Shimada, K., Hosoya, S., Ikeda, T. (1997) Condensation reactions of softwood and hardwood lignin model compounds under organic acid cooking conditions. J. Wood Chem. Technol. 17(1–2):57–72.10.1080/02773819708003118 ↗
26. Stone, J.E., Clayton, D.W. (1960) The use of microtome sections for measuring the change in strength of spruce fibers due to pulping. Pulp Pap. Mag. Can. 46:345–355.
27. Wahren, D. (1982) Methods and apparatus for the rapid consolidation of moist porous web. Patent number: US4324613.