journal article·2024-09-13

Enhanced Interfacial Charge Transport of Ni Metal–Organic Framework Nanosheets Interconnected by Carbon Nanotubes for Capacitive Deionization

Jianing Hu, Wen Xi, Jiahui Zhang, Youfang Zhang, Rui Wang, Huanwen Wang, Yansheng Gong, Beibei He, Jun Jin

ACS Applied Nano Materials· Volume 7· Issue 17
Publisher page

Abstract

Metal–organic frameworks (MOFs) have shown significant potential in hybrid capacitive deionization owing to their unique structure and adjustable pore size. However, their limited electronic conductivity and electrochemical stability hinder their practical application. In this study, we developed hierarchically structured Ni-MOF nanosheets interconnected by carbon nanotubes (Ni-MOF@CNT) through a one-pot hydrothermal reaction. By combining the porous structure of Ni-MOF with the synergistic effect of Ni 2+ ions and CNTs, the Ni-MOF@CNT electrode with fast interfacial charge transfer demonstrates a high desalination capacity of 47.58 mg g –1 and excellent cycling stability. Additionally, the Ni-MOF@CNT electrode demonstrates a remarkable Li + ion extraction capacity of 30.29 mg g –1 .
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Research context

OpenAlex topics: Membrane-based Ion Separation Techniques · Membrane Separation Technologies · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China

Hubei Key Laboratory of Polymer Materials, Ministry of Education Key Laboratory for Green Preparation and Application of Functional Materials, School of Materials Science and Engineering, Hubei University, Wuhan 430062, China

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Funding

Natural Science Foundation of Hubei Province · National Natural Science Foundation of China · China University of Geosciences

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