journal article·2023-08-25

Tridoped Mesoporous Carbon as a Metal-Free Catalyst for Ammoxidation of (Hetero)Aromatic Alcohols to Nitriles

Weitao Wang, Liqiong Ma, Huan Wang, Xulu Jiang, Zhen-Hong He, Kuan Wang, Yang Yang, Lu Li, Zhao-Tie Liu

ACS Applied Nano Materials· Volume 6· Issue 16
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Abstract

Ammoxidation of alcohols is a promising cyanide-free strategy for the synthesis of organic nitriles. It is desirable but challenging to conduct nitrile synthesis over a heterogeneous metal-free catalyst with aqueous ammonia as a nitrogen source and molecular oxygen as an oxidant. In the present work, an Se,P,N-tridoped carbon nanomaterial (Se,P,N/CN-900) was prepared and used as a metal-free catalyst for the direct ammoxidation of alcohols to nitriles with aqueous ammonia and molecular oxygen. The synergistic effect was revealed for the highly efficient catalytic performance of the tridoped carbon catalyst. The present catalyst showed good stability, and various (hetero)aromatic alcohols can be converted to the corresponding nitriles with high yields. To the best of our knowledge, this is the first work to achieve ammoxidation of alcohols to nitriles with a high efficiency over multidoped carbon materials.
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Research context

OpenAlex topics: Chemical Synthesis and Reactions · Oxidative Organic Chemistry Reactions · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry & Chemical Engineering, Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science & Technology, Xi’an, Shaanxi 710021, China

Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science and Technology, Xi’an 710021, China

Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology, Shaanxi University of Science and Technology, Xi’an 710021, China

School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi’an, Shaanxi 710119, China

Funding

Education Department of Shaanxi Province · Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry, Ministry of Education · Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology

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