Microcrystalline Cellulose Decorated with Fe₃O₄ Nanoparticle Catalysts for the Microwave-Assisted Synthesis of Thioglyoxamides

Dharmesh J. Shah; Anuj S. Sharma; Vinay S. Sharma; Vinod Kumar Vishwakarma; Achalkumar Ammathnadu Sudhakar; Pranav S. Shrivastav; Rajender S. Varma

doi:10.1021/acsanm.3c00324

journal article·2023-03-10

Microcrystalline Cellulose Decorated with Fe₃O₄ Nanoparticle Catalysts for the Microwave-Assisted Synthesis of Thioglyoxamides

Dharmesh J. Shah, Anuj S. Sharma, Vinay S. Sharma, Vinod Kumar Vishwakarma, Achalkumar Ammathnadu Sudhakar, Pranav S. Shrivastav, Rajender S. Varma

ACS Applied Nano Materials· Volume 6· Issue 5

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Source abstract

Abstract

Ferrite nanoparticles (Fe 3 O 4 NPs) supported on microcrystalline cellulose (MCC) are introduced as an active nanocatalyst for the preparation of the α-keto thioglyoxamides via a microwave (MW)-assisted protocol. This prepared catalyst shows consistent particle size of Fe 3 O 4 NPs as characterized by PXRD, XPS, SEM, EDS, EDX, TEM, HR-TEM, and FT-IR analysis. A wide variety of thioglyoxamindes are synthesized under optimized reaction conditions to afford a good yield in a short time. Importantly, the presented catalyst can be recycled up to five cycles with no major loss in its activity and is equally relevant for the gram-scale synthesis of thioglyoxamides. This environmentally benign approach offers several advantages and displays good green chemistry metrics (GCM), namely, process mass intensity (PMI), E-factor and atom economy (AE), and reaction mass efficiency (RME).

Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials Catalysis & surfaces

OpenAlex topics: Multicomponent Synthesis of Heterocycles · Chemical Synthesis and Reactions · Sulfur-Based Synthesis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Faculty of Basic and Applied Science, Madhav University, Sirohi, Rajasthan 307026, India

Department of Chemistry, School of Sciences, Gujarat University, Ahmedabad, Gujarat 380009, India

Department of Chemistry, Indian Institute of Technology, Guwahati 781039, Assam, India

Centre for Sustainable Polymers, Indian Institute of Technology, Guwahati 781039, Assam, India

Institute for Nanomaterials, Advanced Technologies and Innovation (CxI), Technical University of Liberec (TUL), Studentská 1402/2, Liberec 1 461 17, Czech Republic

Funding

Council of Scientific and Industrial Research · Science and Engineering Research Board · Board of Research in Nuclear Sciences · Ministry of Human Resource Development

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