journal article·2024-05-24

Electrostatic Spinning to Construct Al/Fe-MOF/PAN Nanofibrous Membranes for the Selective Adsorption of Se(IV) in Water

Qianglong Chen, Ruibin Guo, Bingjie Wang, Fangxia Wang, Hebing Pei, Li Li, Wenjing Qin, Yanchun Tan, Nijuan Liu, Zunli Mo

ACS Applied Nano Materials· Volume 7· Issue 10
Publisher page

Abstract

The emerging pollutant selenium has an immeasurable impact on production and life, and selective adsorption and effective utilization of excessive selenium in water bodies is very challenging. In this paper, nanoscale Al/Fe-MOF was obtained by in situ modification of Fe-MOF by Al 3+, and Al/Fe-MOF- X /PAN nanofibrous membranes were prepared by combining with electrostatic spinning technology for the selective adsorption and enrichment of Se(IV) in water bodies. The adsorption experiments showed that the Al/Fe-MOF-2/PAN nanofibrous membranes had a high adsorption capacity and good selectivity for Se(IV), and the maximum adsorption capacity was up to 228.5 mg/g. The adsorption capacity of the adsorbent for Se(IV) in the actual water body was 220 mg/g. The five adsorption–desorption cycles demonstrated the multiple uses of the materials. X-ray photoelectron spectroscopy (XPS) confirmed that Se(IV) plays an important role in the anion exchange between the −OH in Se and Al species. This study is expected to shed light on the adsorption, enrichment, and transformation of selenium in real water bodies.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Mercury impact and mitigation studies · Carbon and Quantum Dots Applications · Selenium in Biological Systems

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Research Center of Gansu Military and Civilian Integration Advanced Structural Materials, Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

College of Science, Gansu Agricultural University, Lanzhou 730070, China

Funding

Northwest Normal University · National Natural Science Foundation of China · Gansu Association for Science and Technology Innovation-Driven and Assistance Project

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