journal article·2025-06Open access

A review of graphene assembled films as platforms for electrochemical reactions

Yong-fang ZHU, Xiao-dong JI, Wen-kai PAN, Geng WU, Peng LI, Bo LIU, Da-ping HE

New Carbon Materials· Volume 40· Issue 3

Abstract

: Because of their low electrical conductivity, sluggish ion diffusion, and poor stability, conventional electrode materials are not able to meet the growing demands of energy storage and portable devices. Graphene assembled films (GAFs) formed from graphene nanosheets have an ultrahigh conductivity, a unique 2D network structure, and exceptional mechanical strength, which give them the potential to solve these problems. However, a systematic understanding of GAFs as an advanced electrode material is lacking. This review focuses on the use of GAFs in electrochemistry, providing a comprehensive analysis of their synthesis methods, surface/structural characteristics, and physical properties, and thus understand their structure-property relationships. Their advantages in batteries, supercapacitors, and electrochemical sensors are systematically evaluated, with an emphasis on their excellent electrical conductivity, ion transport kinetics, and interfacial stability. The existing problems in these devices, such as chemical inertness and mechanical brittleness, are discussed and potential solutions are proposed, including defect engineering and hybrid structures. This review should deepen our mechanistic understanding of the use of GAFs in electrochemical systems and provide actionable strategies for developing stable, high-performance electrode materials. Download: Download high-res image (117KB) Download: Download full-size image
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Research context

OpenAlex topics: Advancements in Battery Materials · Electrocatalysts for Energy Conversion · Supercapacitor Materials and Fabrication

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References (100+)

Show source-provided references
1. Chemical preparation of graphene-based nanomaterials and their applications in chemical and biological sensors[J]10.1002/smll.201002352 ↗
2. A review of the high-concentration processing, densification, and applications of graphene oxide and graphene[J]10.1016/S1872-5805(24)60856-5 ↗
3. A review of the use of grapheme-based materials in electromagnetic-shielding[J]10.1016/S1872-5805(24)60840-1 ↗
4. Influence of functionalized graphene on the bacterial and fungal diversity of vicia faba rhizosphere soil[J]10.1016/S1872-5805(24)60890-5 ↗
5. Miniaturized electrochemiluminescence platform with laser-induced grapheme-based single electrode for interference-free sensing of dopamine, xanthine, and glucose[J]10.1109/TIM.2021.3071215 ↗
6. Electrochemical approaches to the production of graphene flakes and their potential applications[J]10.1016/j.carbon.2012.11.030 ↗
7. Electrochemical modification of graphene[J]10.1002/adma.200800198 ↗
8. Preparation, structure and electrochemical properties of reduced graphene sheet films[J]10.1002/adfm.200900377 ↗
9. Structural design of graphene for use in electrochemical energy storage devices[J]10.1039/C5CS00147A ↗
10. 3D graphene-based material: overview, perspective, advancement, energy storage, biomedical engineering and environmental applications a bibliometric analysis[J]10.1016/j.jece.2023.110339 ↗
11. Graphene-based electrochemical energy conversion and storage: fuel cells, supercapacitors and lithium ion batteries[J]10.1039/c1cp21915d ↗
12. Graphene-related nanomaterials: tuning properties by functionalization[J]10.1039/c3nr33218g ↗
13. Progress in the electrochemical modification of graphene-based materials and their applications[J]10.1016/j.electacta.2013.06.030 ↗
14. Recent developments in graphene and graphene oxide: properties, synthesis, and modifications: a review[J]10.1002/slct.202002501 ↗
15. Strategies for chemical modification of graphene and applications of chemically modified graphene[J]10.1039/c2jm31218b ↗
16. Graphene-based electrodes for electrochemical energy storage[J]10.1039/c3ee23870a ↗
17. Layer-by-layer self-assembly of graphene nanoplatelets[J]10.1021/la900126g ↗
18. Layer-by-layer self-assembly of pillared two-dimensional multilayers[J]10.1038/s41467-019-10631-0 ↗
19. Introduction to nanocoatings produced by layer-by-layer (LBL) self-assembly[J]10.1016/j.addr.2011.05.011 ↗
20. A review of testing methods for thermal spray coatings[J]10.1179/1743280414Y.0000000029 ↗
21. A review on thermal spray coating processes[J]
22. Cold spray coating: review of material systems and future perspectives[J]10.1179/1743294414Y.0000000270 ↗
23. Doping of graphene films: open the way to applications in electronics and optoelectronics[J]10.1002/adfm.202203179 ↗
24. Non-noble-metal catalyst and Zn/graphene film for low-cost and ultra-long-durability solid-state Zn-air batteries in harsh electrolytes[J]10.1002/adfm.202200397 ↗
25. Effects of reduction methods on the structure and thermal conductivity of free-standing reduced graphene oxide films[J]10.1016/j.diamond.2015.06.005 ↗
26. Enhanced reduction of graphene oxide on recyclable cu foils to fabricate graphene films with superior thermal conductivity[J]
27. Humidity-sensing properties of chemically reduced graphene oxide/polymer nanocomposite film sensor based on layer-by-layer nano self-assembly[J]10.1016/j.snb.2014.02.078 ↗
28. Large area orientation films based on graphene oxide self-assembly and low-temperature thermal reduction[J]10.1063/1.4764549 ↗
29. Self-assembled free-standing graphite oxide membrane[J]10.1002/adma.200803726 ↗
30. Toward the commercialization of chemical vapor deposition graphene films[J]10.1063/5.0056413 ↗
31. Graphene in macroscopic order: liquid crystals and wet-spun fibers[J]10.1021/ar4002813 ↗
32. Template-directed hierarchical self-assembly of graphene based hybrid structure for electrochemical biosensing[J]10.1016/j.bios.2013.04.004 ↗
33. Concisely modularized assembling of graphene-based thin films with promising electrode performance[J]10.1039/C8QM00628H ↗
34. Nanocomposites of titania/reduced graphene oxide: flexible humidity sensors tuned via photocatalytic reduction[J]10.1021/acsanm.4c06524 ↗
35. Thermally conductive reduced graphene oxide thin films for extreme temperature sensors[J]10.1002/adfm.201901388 ↗
36. Highly efficient, electro-thermal heater based on marangoni-driven, oriented reduced graphene oxide/poly (ether imide) nanolaminates[J]10.1021/acsami.4c17273 ↗
37. Graphene-based films: fabrication, interfacial modification, and applications[J]10.3390/nano11102539 ↗
38. Flux accentuation and improved rejection in graphene-based filtration membranes produced by capillaryforce-assisted self-assembly[J]
39. Capillary-force-assisted self-assembly (cas) of highly ordered and anisotropic graphene-based thin films[J]10.1021/jp4080114 ↗
40. Two-minute assembly of pristine large-area graphene based films[J]10.1021/nl404446f ↗
41. Reduced-grapheneoxide-based thin films: an alternative coating for harsh space environments[J]10.1021/acsami.4c11126 ↗
42. Nanocarbon hybrid films of reduced graphene oxide and n-doped graphene quantum dots as a metal-free platform for grapheneenhanced raman scattering[J]10.1021/acsami.4c21874 ↗
43. RGO-Si QDs hybrid photodetector with enhanced photosensitivity[J]10.1016/j.physb.2025.417133 ↗
44. Spray-evaporation assembled graphene oxide membranes for selective hydrogen transport[J]10.1016/j.seppur.2016.10.012 ↗
45. Ultrahigh thermal conductive yet superflexible graphene films[J]10.1002/adma.201700589 ↗
46. High-throughput fabrication of uniform and homogenous mof coatings[J]10.1002/adfm.201101592 ↗
47. Efficient fabrication and characterization of doped nanocomposites for thermoelectric materials[J]10.1016/j.nwnano.2025.100109 ↗
48. Principles for fabricating moisture barrier films via stacked janus graphene layers[J]
49. Effect of microstructure of graphene oxide fabricated through different self-assembly techniques on 1-butanol dehydration[J]10.1016/j.memsci.2014.12.039 ↗
50. Wafer-scale reduced graphene oxide films for nanomechanical devices[J]10.1021/nl8023092 ↗
51. General route toward patterning of graphene oxide by a combination of wettability modulation and spin-coating[J]10.1021/nn101463j ↗
52. A chemical route to graphene for device applications[J]10.1021/nl0717715 ↗
53. A novel mxene/go thermoacoustic loudspeaker with high sound pressure[J]10.1109/JSEN.2025.3558925 ↗
54. Effects of non-uniform current distribution on energy density of li-ion cells[J]10.1149/2.061311jes ↗
55. Ambient fabrication of large-area graphene films via a synchronous reduction and assembly strategy[J]10.1002/adma.201300586 ↗
56. Bottom-up fabrication of B,N-doped graphene electrodes from thiolterminated borazine molecules working in solar cells[J]10.1021/acsami.4c23116 ↗
57. Graphene oxide/Ni/carbon nanocoils synergizing dielectric/magnetic/chiral multiple losses for weatherresistant electromagnetic protective application[J]10.1016/j.cej.2025.162263 ↗
58. Effects of high-temperature thermal reduction on thermal conductivity of reduced graphene oxide polymer composites[J]10.1016/j.apsusc.2023.159140 ↗
59. Controllable preparation of grapheme-based film deposited on cemented carbides by chemical vapor deposition[J]10.1007/s10853-019-04268-z ↗
60. Designed CVD growth of graphene via process engineering[J]10.1021/ar400057n ↗
61. A review on high-efficiency transfer of graphene films free from defects and contamination[J]10.1002/eem2.70009 ↗
62. Synthesis of graphene films on copper foils by chemical vapor deposition[J]10.1002/adma.201504760 ↗
63. Flexible and lightweight graphene grown by rapid thermal processing chemical vapor deposition for thermal management in consumer electronics[J]10.1016/S1872-5805(23)60737-1 ↗
64. Graphene film growth on polycrystalline metals[J]10.1021/ar3001266 ↗
65. Fabrication of strain-sensing fibers with silver nanoparticles and reduced graphene oxide via wet spinning[J]10.1088/1361-6528/ada2f4 ↗
66. Wet spinning for high-performance fiber supercapacitor based on Fe-doped MnO2 and graphene[J]10.1016/j.carbon.2024.119572 ↗
67. Tri-high designed graphene electrodes for long cycle-life supercapacitors with high mass loading[J]10.1016/j.ensm.2018.07.001 ↗
68. Advances in porous graphene and scalable wet-spinning fiber assembly[J]10.1021/accountsmr.2c00186 ↗
69. Wet-spinning assembly of continuous, neat and macroscopic graphene fibers[J]10.1038/srep00613 ↗
70. Wet-spun continuous graphene films[J]10.1021/cm5033089 ↗
71. Graphene chiral liquid crystals and macroscopic assembled fibres[J]10.1038/ncomms1583 ↗
72. Intercross-linked aramid nanofibers/graphene hybrid films toward high mechanical strength and electrical conductivity[J]10.1016/j.jallcom.2023.173390 ↗
73. Electrostatic-induced ion-confined partitioning in graphene nanolaminate membrane for breaking anion–cation co-transport to enhance desalination[J]
74. High power and energy density graphene phase change composite materials for efficient thermal management of li-ion batteries[J]10.1016/j.ensm.2025.104003 ↗
75. Scalable fabrication of graphene-assembled multifunctional electrode with efficient electrochemical detection of dopamine and glucose[J]10.1007/s12274-023-5459-7 ↗
76. Rapid soldering of flexible graphene assembled films at low temperature in air with ultrasonic assistance[J]10.1016/j.carbon.2019.11.089 ↗
77. Dual-circularly polarized and flexible metasurface antenna based on graphene assembled film for satellite communications[J]10.1021/acsami.4c01211 ↗
78. Large-Scale current collectors for regulating heat transfer and enhancing battery safety[J]10.1038/s44286-024-00103-8 ↗
79. Comparison of copper and graphene-assembled films in 5G wireless communication and thz electromagnetic-interference shielding[J]10.1073/pnas.2209807120 ↗
80. Self-assembled three-dimensional graphene macrostructures: synthesis and applications in supercapacitors[J]10.1021/acs.accounts.5b00117 ↗
81. Three-dimensional macrostructures of two-dimensional nanomaterials[J]10.1039/C6CS00218H ↗
82. Graphene electrochemistry: an overview of potential applications[J]10.1039/c0an00590h ↗
83. Graphene electrochemistry: fundamental concepts through to prominent applications[J]10.1039/c2cs35105f ↗
84. One-step electrochemical synthesis of graphene/polyaniline composite film and its applications[J]10.1002/adfm.201100038 ↗
85. Recent advances in electrochemical biosensing schemes using graphene and graphene-based nanocomposites[J]10.1016/j.carbon.2014.12.052 ↗
86. Graphene-coated plastic film as current collector for lithium/sulfur batteries[J]10.1016/j.jpowsour.2013.02.008 ↗
87. Highly reduced graphene assembly film as current collector for lithium ion batteries[J]10.1021/acssuschemeng.1c02414 ↗
88. Roll-to-roll scale fabrication of high-performance graphene-assembled film cathode current collectors for lithium-ion batteries[J]10.1021/acssuschemeng.3c03939 ↗
89. Graphene-based ternary composites for supercapacitors[J]10.1002/er.4001 ↗
90. Significantly improved electrochemical characteristics of nickel sulfide nanoplates using graphene oxide thin film for supercapacitor applications[J]10.1016/j.est.2020.102091 ↗
91. Macroporous graphene frameworks for sensing and supercapacitor applications[J]10.1002/adfm.202203101 ↗
92. Graphene-based materials for supercapacitor electrodes–a review[J]10.1016/j.jmat.2016.01.001 ↗
93. Electrolyte-mediated dense integration of graphene-mxene films for high volumetric capacitance flexible supercapacitors[J]10.1007/s12274-020-3100-6 ↗
94. Mechanically flexible reduced graphene oxide/carbon composite films for high-performance quasi-solid-state lithium-ion capacitors[J]10.1016/j.jechem.2023.01.031 ↗
95. A high-performance covalently bonded self-doped polyaniline–graphene assembly film with superior stability for supercapacitors[J]10.1016/j.jpowsour.2021.229538 ↗
96. Optimization strategy of molecular modified graphene films for high-performance aqueous zinc-ion hybrid supercapacitors[J]10.1016/j.jelechem.2023.117850 ↗
97. Application of graphene in elctrochemical sensing[J]10.1016/j.cocis.2015.10.011 ↗
98. Electrochemical sensors based on grapheme materials[J]10.1007/s00604-011-0639-7 ↗
99. Graphene-based electrochemical sensors[J]10.1002/smll.201202896 ↗
100. Flexible, scalable hierarchical graphene foam decorated with nickel layer for highly sensitive enzyme-free glucose sensing[J]10.1016/j.jallcom.2024.175902 ↗