The low-temperature deposition of a zincophilic carbon layer on the Zn foil for long-life zinc metal batteries
Source abstract
Abstract
Aqueous zinc metal batteries (ZMBs) which are environmentally benign and cheap can be used for grid-scale energy storage, but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aqueous electrolytes. A zincophilic carbon (ZC) layer was deposited on a Zn metal foil at 450 °C by the up-stream pyrolysis of a hydrogen-bonded supramolecular substance framework, assembled from melamine (ME) and cyanuric acid (CA). The zincophilic groups (C＝O and C＝N) in the ZC layer guide uniform zinc plating/stripping and eliminate dendrites and side reactions. so that assembled symmetrical batteries (ZC@Zn//ZC@Zn) have a long-term service life of 2500 h at 1 mA cm −2 and 1 mAh cm −2 , which is much longer than that of bare Zn anodes (180 h). In addition, ZC@Zn//V 2 O 5 full batteries have a higher capacity of 174 mAh g −1 after 1200 cycles at 2 A g −1 than a Zn//V 2 O 5 counterpart (100 mAh g −1 ). The strategy developed for the low-temperature deposition of the ZC layer is a new way to construct advanced zinc metal anodes for ZMBs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Advancements in Battery Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (47)
Show source-provided references
1. High-energy lithium-ion batteries: Recent progress and a promising future in applications[J]10.1002/eem2.12450 ↗
2. A review of solid-state proton-polymer batteries: Materials and characterizations[J]10.3390/polym15194032 ↗
3. Progress and prospect of low-temperature zinc metal batteries[J]10.1016/j.apmate.2021.10.002 ↗
4. Advances of Zn metal-free “rocking-chair”-type zinc ion batteries: Recent developments and future perspectives[J]10.1002/smll.202306111 ↗
5. An aqueous electrolyte densified by perovskite SrTiO3 enabling high-voltage zinc-ion batteries[J]10.1038/s41467-023-40462-z ↗
6. Selective ion transport layer for stable aqueous zinc-ion batteries[J]10.1002/adfm.202310884 ↗
7. Interface challenges and optimization strategies for aqueous zinc-ion batteries[J]10.1016/j.jechem.2022.11.028 ↗
8. Three-dimensional Zn-based alloys for dendrite-free aqueous Zn battery in dual-cation electrolytes[J]10.1038/s41467-022-35618-2 ↗
9. Bistate-type ion storage of azo polymer for aqueous zinc ion battery[J]10.1016/j.ensm.2023.103102 ↗
10. Advances in aqueous zinc ion batteries based on conversion mechanism: Challenges, strategies and prospects[J]10.1002/smll.202310972 ↗
11. CoFe2O4 nanoparticles modified amidation of N-doped carbon nanofibers hybrid catalysts to accelerate electrochemical kinetics of Li-S batteries with high sulfur loading[J]
12. Enhanced polysulfides conversion with hybrid bipolar membrane composed of CoSe2 and amidefunctionalized CNTs composites for lithium sulfur batteries[J]10.1016/j.est.2023.110087 ↗
13. On the dendrite-suppressing effect of laser-processed polylactic acid-derived carbon coated zinc anode in aqueous zinc ion batteries[J]10.1002/anie.202405048 ↗
14. Intrinsic interfacial dynamic engineering of zincophilic microbrushes via regulating Zn deposition for highly reversible aqueous zinc ion battery[J]10.1002/adma.202205206 ↗
15. Recent advances in interfacial modification of zinc anode for aqueous rechargeable zinc ion batteries[J]10.1016/j.jechem.2023.03.059 ↗
16. Regulating the redox reversibility of zinc anode toward stable aqueous zinc batteries[J]10.1016/j.nanoen.2022.107331 ↗
17. Multi-ion engineering strategies toward high performance aqueous zinc-based batteries[J]10.1002/adma.202304040 ↗
18. Thermal-gated polyanionic hydrogel films for stable and smart aqueous batteries[J]10.1016/j.ensm.2023.103136 ↗
19. One-step targeted treatment for Zn flatting and protection[J]10.1016/j.ensm.2022.08.045 ↗
20. Constructing a rapid ion-transport anode interface protective layer for zinc ion batteries to suppress solvation and improve surface electronic structure[J]
21. Boosted Zn-ion storage in high crystalline VS4 anode by enhanced diffusion-controlled kinetics[J]10.1016/j.cej.2023.146408 ↗
22. Peptide gel electrolytes for stabilized Zn metal anodes[J]10.1021/acsnano.3c04414 ↗
23. Designing carboxymethyl cellulose based hydrogel electrolyte membranes enhanced by inorganic nanoparticle toward stable zinc anode[J]
24. Manipulating crystallographic orientation of zinc deposition for dendrite- free zinc ion batteries[J]10.1002/aenm.202101299 ↗
25. Ultra- stable Zn anode enabled by fiber-directed ion migration using mass-producible separator[J]10.1002/adfm.202209301 ↗
26. Regulating Zn ion desolvation and deposition chemistry toward durable and fast rechargeable Zn metal batteries[J]10.1002/advs.202205874 ↗
27. Constructing defect-free zincophilic organic layer via ultrasonic coating for anticorrosive and dendrite-free zinc anode[J]10.1016/j.nanoen.2023.108810 ↗
28. Rational design of zincophilic Ag/permselective PEDOT: PSS heterogeneous interfaces for high-rate zinc electrodeposition[J]10.1002/smll.202303665 ↗
29. Long-cycling zinc metal anodes enabled by an in situ constructed ZnO coating layer[J]10.1002/adfm.202312220 ↗
30. Superhydrophobic metal-organic framework layers as multifunctional ion-conducting interfaces for ultra-stable Zn anodes[J]10.1016/j.jpowsour.2024.235364 ↗
31. An in-depth study of Zn metal surface chemistry for advanced aqueous Zn- ion batteries[J]10.1002/adma.202003021 ↗
32. Dendrites-free Zn metal anodes enabled by an artificial protective layer filled with 2D anionic nanosheets[J]10.1002/smtd.202100650 ↗
33. Polymeric molecular design towards horizontal Zn electrodeposits at constrained 2D Zn2+ diffusion: dendrite-free Zn anode for long-life and high-rate aqueous zinc metal battery[J]10.1002/adfm.202204066 ↗
34. Nanoporous CaCO3 coatings enabled uniform Zn stripping/plating for long- life zinc rechargeable aqueous batteries[J]10.1002/aenm.201801090 ↗
35. Dendrite-free Zn anodes enabled by functional nitrogen-doped carbon protective layers for aqueous zinc-ion batteries[J]10.1039/D0DT03459B ↗
36. A highly reversible zinc anode for rechargeable aqueous batteries[J]10.1021/acsami.1c15628 ↗
37. Zinc-tiered synthesis of 3D graphene for monolithic electrodes[J]10.1002/adma.201901186 ↗
38. Flexible zincophilic polypyrrole paper interlayers for stable Zn metal anodes: Higher surface flatness promises better reversibility[J]10.1016/j.nanoen.2022.107329 ↗
39. urea-mediated monoliths made of nitrogen- enriched mesoporous carbon nanosheets for high-performance aqueous zinc ion hybrid capacitors[J]10.1002/smll.202108057 ↗
40. Synergistic solvation and interface regulations of eco-friendly silk peptide additive enabling stable aqueous zinc- ion batteries[J]10.1002/adfm.202112693 ↗
41. Anode corrosion in aqueous Zn metal batteries[J]10.1016/j.esci.2023.100093 ↗
42. Synergistic manipulation of Zn2+ ion flux and desolvation effect enabled by anodic growth of a 3D ZnF2 matrix for long-lifespan and dendrite-free Zn metal anodes[J]10.1002/adma.202007388 ↗
43. Achieving ultra-long lifespan Zn metal anodes by manipulating desolvation effect and Zn deposition orientation in a multiple cross-linked hydrogel electrolyte[J]10.1016/j.ensm.2022.04.010 ↗
44. Interfacial engineering strategy for high-performance Zn metal anodes[J]10.1007/s40820-021-00764-7 ↗
45. Interfacial manipulation via in situ grown ZnSe cultivator toward highly reversible Zn metal anodes[J]10.1002/adma.202105951 ↗
46. Suppressing vanadium dissolution in 2D V2O5/MXene heterostructures via organic/aqueous hybrid electrolyte for stable zinc ion batteries[J]10.1016/j.cej.2022.139574 ↗
47. Promise and challenge of vanadium-based cathodes for aqueous zinc-ion batteries[J]10.1016/j.jechem.2020.06.013 ↗