A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability
Source abstract
Abstract
Because of their high electrochemical activity, good structural stability, and abundant active sites, multi-metal sulfide/carbon (MMS/C) composites are of tremendous interest in diverse fields, including catalysis, energy, sensing, and environmental science. However, their cumbersome, inefficient, and environmentally unfriendly synthesis is hindering their practical application. We report a straightforward and universal method for their production which is based on homogeneous multi-phase interface engineering. The method has enabled the production of 14 different MMS/C composites, as examples, with well-organized composite structures, different components, and dense heterointerfaces. Because of their composition and structure, a typical composite has efficient, fast, and persistent lithium-ion storage. A ZnS-Co9S8/C composite anode showed a remarkable rate performance and an excellent capacity of 651 mAh·g−1 at 0.1 A·g−1 after 600 cycles. This work is expected to pave the way for the easy fabrication of MMS/C composites.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (49)
Show source-provided references
1. Lithium-ion battery development takes nobel[J]10.1126/science.366.6463.292 ↗
2. 30 years of lithium-ion batteries[J]10.1002/adma.201800561 ↗
3. A review of rechargeable batteries for portable electronic devices[J]10.1002/inf2.12000 ↗
4. The lithium-ion battery: State of the art and future perspectives[J]10.1016/j.rser.2018.03.002 ↗
5. Recent progress of advanced anode materials of lithium-ion batteries[J]10.1016/j.jechem.2020.08.056 ↗
6. Electrode degradation in lithium-ion batteries[J]10.1021/acsnano.9b04365 ↗
7. High-performance anode materials for rechargeable lithium-ion batteries[J]10.1007/s41918-018-0001-4 ↗
8. Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries[J]10.1039/C7CS00863E ↗
9. Fast charging anode materials for lithium-ion batteries: Current status and perspectives[J]10.1002/adfm.202200796 ↗
10. Recent advances and perspectives of carbon-based nanostructures as anode materials for li-ion batteries[J]10.3390/ma12081229 ↗
11. Design and synthesis of carbon-based nanomaterials for electrochemical energy storage[J]10.1016/S1872-5805(22)60579-1 ↗
12. The application of nanostructured transition metal sulfides as anodes for lithium ion batteries[J]10.1016/j.jechem.2018.01.009 ↗
13. A review on design strategies for carbon based metal oxides and sulfides nanocomposites for high performance li and na ion battery anodes[J]10.1002/aenm.201601424 ↗
14. Applications of tin sulfide-based materials in lithium-ion batteries and sodium-ion batteries[J]10.1002/adfm.202001298 ↗
15. Interconnected CoC2/NC-CNTs network as high-performance anode materials for lithium-ion batteries[J]10.1007/s40843-020-1477-0 ↗
16. Edge-enriched MoS2@C/rGO film as self-standing anodes for high-capacity and long-life lithium-ion batteries[J]10.1007/s40843-020-1348-y ↗
17. High-entropy sulfides as electrode materials for li-ion batteries[J]
18. Built-in electric field induced interfacial effect enables ultrasmall snsx nanoparticles with high-rate lithium/sodium storage[J]10.1016/j.cej.2022.137286 ↗
19. Synergetic anion vacancies and dense heterointerfaces into bimetal chalcogenide nanosheet arrays for boosting electrocatalysis sulfur conversion[J]10.1002/adma.202109552 ↗
20. Bimetallic sulfide Sb2S3@FeS2 hollow nanorods as high-performance anode materials for sodium-ion batteries[J]10.1021/acsnano.0c00020 ↗
21. Dual-defect surface engineering of bimetallic sulfide nanotubes towards flexible asymmetric solid-state supercapacitors[J]10.1039/D0TA08979F ↗
22. Hierarchical trimetallic sulfide FeCo2S4-NiCo2S4 nanosheet arrays supported on a ti mesh: An efficient 3d bifunctional electrocatalyst for full water splitting[J]10.1016/j.electacta.2020.135957 ↗
23. Trimetallic sulfide hollow superstructures with engineered d-band center for oxygen reduction to hydrogen peroxide in alkaline solution[J]10.1002/advs.202104768 ↗
24. Electrodeposition-derived defect-rich heterogeneous trimetallic sulfide/hydroxide nanotubes/nanobelts for efficient electrocatalytic oxygen production[J]10.1016/j.cej.2021.133073 ↗
25. Hierarchical Sb2S3/SnS2/C heterostructure with improved performance for sodium-ion batteries[J]10.1007/s40843-021-1931-0 ↗
26. Bimetallic metal-organic framework derived transition metal sulfide microspheres as high-performance lithium/sodium storage materials[J]10.1016/j.cej.2022.137154 ↗
27. Observation of pseudocapacitive effect and fast ion diffusion in bimetallic sulfides as an advanced sodium-ion battery anode[J]
28. Carbon coated bimetallic sulfide hollow nanocubes as advanced sodium ion battery anode[J]10.1002/aenm.201700180 ↗
29. Versatile bimetal sulfides nanoparticles-embedded N-doped hierarchical carbonaceous aerogels (N-NixSy/CoxSy@C) for excellent supercapacitors and microwave absorption[J]10.1016/j.carbon.2021.04.029 ↗
30. Rational design of perforated bimetallic (Ni, Mo) sulfides/N-doped graphitic carbon composite microspheres as anode materials for superior Na-ion batteries[J]
31. Yolk-shell-structured zinc-cobalt binary metal sulfide@N-doped carbon for enhanced lithium-ion storage[J]10.1016/j.nanoen.2019.103899 ↗
32. Bimetallic SnS2/NiS2@S-rGO nanocomposite with hierarchical flower-like architecture for superior high rate and ultra-stable half/full sodium-ion batteries[J]10.1016/j.cej.2021.131784 ↗
33. RGO wrapped trimetallic sulfide nanowires as an efficient bifunctional catalyst for electrocatalytic oxygen evolution and photocatalytic organic degradation[J]10.1039/D0TA04383D ↗
34. Recent advances of bimetallic sulfide anodes for sodium ion batteries[J]10.3389/fchem.2020.00353 ↗
35. Recent progress in core@shell sulfide electrode materials for advanced supercapacitor devices[J]10.1002/batt.202100017 ↗
36. Phosphorous-doped bimetallic sulfides embedded in heteroatom-doped carbon nanoarrays for flexible all-solid-state supercapacitors[J]10.1007/s40843-020-1667-1 ↗
37. The advance of nickel-cobalt-sulfide as ultra-fast/high sodium storage materials: The influences of morphology structure, phase evolution and interface property[J]10.1016/j.ensm.2018.06.006 ↗
38. A bimetallic sulfide Co9S8/MoS2/C heterojunction in a three-dimensional carbon structure for increasing sodium ion storage[J]10.1016/S1872-5805(23)60731-0 ↗
39. Study on the removal of chromium(iii) from leather waste by a two-step method[J]10.1016/j.jiec.2019.06.030 ↗
40. Removal of Pb2+ from aqueous solutions by a high-efficiency resin[J]10.1016/j.apsusc.2013.06.161 ↗
41. Removal of impurities from scandium chloride solution using 732-type resin[J]10.1016/j.jre.2017.09.009 ↗
42. Homogeneous triple-phase interfaces enabling one-pot route to metal compound/carbon composites[J]10.1016/j.jcis.2021.04.054 ↗
43. Synthesis and physical properties of sulfonated syndiotactic polystyrene ionomers[J]10.1002/pi.646 ↗
44. Sorption of Ni(ii) ions from aqueous solution by lewatit cation-exchange resin[J]10.1016/j.jhazmat.2009.01.073 ↗
45. Removal of metal ions from aqueous solutions using carboxymethyl cellulose/sodium styrene sulfonate gels prepared by radiation grafting[J]10.1016/j.carbpol.2016.09.049 ↗
46. Copper-doped sulfonic acid-functionalized MIL-101(Cr) metal-organic framework for efficient aerobic oxidation reactions[J]10.1002/aoc.5445 ↗
47. Evidencing enhanced oxygen and hydrogen evolution reactions using In-Zn-Co ternary transition metal oxide nanostructures: A novel bifunctional electrocatalyst[J]10.1016/j.ijhydene.2019.07.069 ↗
48. Metal organic framework-templated synthesis of bimetallic selenides with rich phase boundaries for sodium-ion storage and oxygen evolution reaction[J]10.1021/acsnano.9b00816 ↗
49. Co-construction of sulfur vacancies and heterojunctions in tungsten disulfide to induce fast electronic/ionic diffusion kinetics for sodium-ion batteries[J]10.1002/adma.202005802 ↗