journal article·2013-02

Preparation of TiO2/mesoporous carbon composites and their photocatalytic performance for methyl orange degradation

Bo YIN, Ji-tong WANG, Wei XU, Dong-hui LONG, Wen-ming QIAO, Li-cheng LING

New Carbon Materials· Volume 28· Issue 1
Publisher page

Abstract

Mesoporous carbon (MC) prepared using colloidal silica templates was used as a support to synthesize TiO2/MC composites using a sol-gel method. The TiO2 content and the crystalline structure of TiO2/MC photocatalysts can be tuned by the precursor composition and calcination temperature, respectively. MC and TiO2/MC composites were characterized by nitrogen adsorption, XRD, TG, SEM, TEM and electron energy dispersive spectroscopy. Results showed that the anatase TiO2 nanoparticles were highly dispersed on the surface of the carbon framework. As-prepared composites exhibited high photocatalytic activities for methyl orange (MO) degradation under UV irradiation, and a synergistic effect of adsorption and photocatalytic degradation was observed. The MO removal rate reached 89% after UV irradiation for 75 min. The kinetics of MO degradation can be well fitted with a first-order reaction model and the largest rate constant observed was 0.015 min−1.
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Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Photocatalysis in water environments using artificial and solar light [J]10.1016/S0920-5861(00)00252-2 ↗
2. Recent developments in titanium oxide-based photocatalysts [J]10.1016/j.apcata.2007.03.013 ↗
3. Photocatalysis for the formation of the C-C bond [J]10.1021/cr068352x ↗
4. Some applications of photocatalysis [J]
5. Photocatalysis on TiO2 surfaces: Principles, mechanisms, aselected results [J]10.1021/cr00035a013 ↗
6. Titanium dioxide photocatalysis [J]10.1016/S1389-5567(00)00002-2 ↗
7. An overview of semiconductor photocatalysis [J]10.1016/S1010-6030(97)00118-4 ↗
8. Heterogeneous photocatalysis: Fundamentals and applications to the removal of various types of aqueous pollutants [J]10.1016/S0920-5861(99)00107-8 ↗
9. Preparation, characterization, and photoactivity of polycrystalline nanostructured TiO2 catalysts [J]10.1021/jp0312924 ↗
10. Studies on photodegradation of two commercial dyes in aqueous phase using different photocatalysts [J]10.1016/j.jhazmat.2006.07.035 ↗
11. A novel approach towards high-performance composite photocatalyst of TiO2 deposited on activated carbon [J]10.1016/j.apsusc.2008.10.083 ↗
12. Photocatalytic degradation of toluene in the gas phase: Comparative study of some TiO2 supports [J]10.1016/S1010-6030(02)00088-6 ↗
13. Photocatalytic degradation of triazinic ring-containing azo dye (Reactive Red 198) by using immobilized TiO2 photoreactor: Bench scale study [J]10.1016/j.jhazmat.2005.09.057 ↗
14. Effect of inert supports for titanium dioxide loading on enhancement of photodecomposition rate of gaseous propionaldehyde [J]10.1021/j100024a047 ↗
15. Properties of mesoporous carbons prepared from different carbon precursors using nanosize silica as a template [J]10.1016/S1872-5805(09)60045-7 ↗
17. Surface chemistry of ordered mesoporous carbons [J]10.1016/S0008-6223(02)00187-2 ↗
18. Ordered mesoporous carbons: Implication of surface chemistry, pore structure and adsorption of methyl mercaptan [J]10.1016/j.carbon.2005.02.035 ↗
19. Simplified novel synthesis of ordered mesoporous carbon with a bimodal pore system [J]
20. Pore development of thermosetting phenol resin derived mesoporous carbon through a commercially nanosized template [J]10.1016/j.msea.2007.04.082 ↗
21. Development of mesophase pitch derived mesoporous carbons through a commercially nanosized template [J]10.1021/la052494p ↗
22. Hard-templating synthesis of mesoporous carbon spheres with controlled particle size and mesoporous structure for enzyme immobilization [J]10.1016/j.matchemphys.2011.05.085 ↗
23. Physicochemical properties and photocatalytic activities of TiO2-films prepared by sol-gel methods [J]10.1016/S0926-3373(02)00120-0 ↗
24. Carbon-coated TiO2 composites for the photocatalytic degradation of low concentration benzene [J]10.1016/S1872-5805(11)60067-X ↗
25. Synthesis of CdS/CNT-TiO2 with a high photocatalytic activity in photodegradation of methylene blue [J]10.1016/S1872-5805(12)60011-0 ↗
26. Reporting physisorption data for gas/solid systems with special reference to the determination of surface rea and porosity [J]10.1351/pac198254112201 ↗
27. TiO2 nanoparticles in mesoporous TUD-1: Synthesis, characterization and photocatalytic performance in propane oxidation [J]10.1002/chem.200500649 ↗
28. Photostabilization of organic dyes on Poly(styrenesulfonate)-capped TiO2 nanoparticles [J]10.1021/la970075p ↗
29. Structural characterization of DC magnetron-sputtered TiO2 thin films using XRD and Raman scattering studies [J]10.1016/j.mssp.2003.05.012 ↗
30. Visible-light responsive cerium ion modified titania sol and nanocrystallites for X-3B dye photodegradation [J]10.1016/S0926-3373(03)00211-X ↗
31. Photocatalytic degradation of X-3B by titania-coated magnetic activated carbon under UV and visible irradiation [J]10.1016/j.jallcom.2008.04.001 ↗
32. Synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon [J]10.1016/S0926-3373(98)00051-4 ↗