journal article·2020-07

Preparation and performance of electrochemical glucose sensors based on copper nanoparticles loaded on flexible graphite sheet

Ji-hui Li, Jia-xin Tang, Luo Wei, Shuai-jie He, Li-qiang Ma, Wan-ci Shen, Fei-yu Kang, Zheng-hong Huang

New Carbon Materials· Volume 35· Issue 4
Publisher page

Abstract

Abstract A flexible graphite sheet can be used as a self-supported substrate material for sensors owing to its excellent conductivity and flexibility. Copper nanoparticle/flexible graphite sheet self-supporting enzyme-free glucose sensors were prepared by a hydrothermal method using copper sulfate as the elemental copper source and ascorbic acid as the reducing agent. Results indicate that both the molar ratio of copper sulfate to ascorbic acid and the hydrothermal temperature affect the microstructure and sensor performance. The optimal sensor obtained with a ratio of 1:0.5 at 150 oC has a low detection limit of 1.05 μmol/L, and high sensitivities of 7 254.1 μA·mM-1·cm-2 R2 = 0.996 1 from 0.1 to 3.4 mmol/L and 3 804.5 μA·mM-1·cm-2 (R2 = 0.999 5) from 3.4 to 5.6 mmol/L The sensor possesses excellent anti-interference properties against sodium chloride, acetaminophenol, ascorbic acid, dopamine, and uric acid, and has good reproducibility.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrochemical sensors and biosensors · Analytical Chemistry and Sensors · Advanced biosensing and bioanalysis techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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