journal article·2022-08

Permselective graphene-based membranes and their applications in seawater desalination

Yi-fu Gao, Yao Wang, Dong Zhou, Wei Lv, Fei-yu Kang

New Carbon Materials· Volume 37· Issue 4
Publisher page

Abstract

Two-dimensional materials represented by graphene are widely used to fabricate membranes with nanopores or nanochannels and have shown great promise in the field of mass separation, especially seawater desalination. We review the research progress and applications of graphene and its derivatives, including single-layer graphene, nanoporous graphene and graphene oxide, in the field of seawater desalination. Based on an overview of the intrinsic properties of graphene, the permeability and selectivity of porous graphene membranes with one-dimensional nanopores, and lamellar graphene oxide membranes with two-dimensional nanochannels are first discussed. In addition, different preparation processes and their effects on the permselectivity of graphene-based membranes are compared. Methods for regulating the mechanism of the permselectivity of graphene-based membranes for various solutions are analyzed. The use of graphene-based membranes in seawater desalination and the existing limitations are summarized, and prospects for future developments of this research area are proposed.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Graphene research and applications · Membrane Separation Technologies · Nanopore and Nanochannel Transport Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (73)

Show source-provided references
1. Four billion people facing severe water scarcity[J]10.1126/sciadv.1500323 ↗
2. Membrane distillation at the water-energy nexus: limits, opportunities, and challenges[J]10.1039/C8EE00291F ↗
3. Thermophysical properties of seawater: a review of existing correlations and data[J]
4. Growth patterns in mature desalination technologies and analogies with the energy field[J]10.1016/j.desal.2019.01.029 ↗
5. The state of desalination and brine production: a global outlook[J]10.1016/j.scitotenv.2018.12.076 ↗
6. Graphene oxide membranes for ionic and molecular sieving[J]10.1126/science.1250247 ↗
7. Ion selection of charge-modified large nanopores in a graphene sheet[J]10.1063/1.4821161 ↗
8. A review of clathrate hydrate based desalination to strengthen energy–water nexus[J]10.1021/acssuschemeng.8b01616 ↗
9. Mechanism of water transport in graphene oxide laminates[J]10.1039/C6SC03909J ↗
10. Biofouling of polyamide membranes: fouling mechanisms, current mitigation and cleaning strategies, and future prospects[J]10.3390/membranes9090111 ↗
11. A review of reverse osmosis membrane materials for desalination—development to date and future potential[J]10.1016/j.memsci.2010.12.036 ↗
12. Biomimetic artificial water channel membranes for enhanced desalination[J]10.1038/s41565-020-00796-x ↗
13. Graphene membranes for water desalination[J]10.1038/am.2017.135 ↗
14. Perfect proton selectivity in ion transport through two-dimensional crystals[J]10.1038/s41467-019-12314-2 ↗
15. Impermeable atomic membranes from graphene sheets[J]10.1021/nl801457b ↗
16. Can graphene and graphene oxide materials revolutionise desalination processes?[J]10.1016/j.desal.2020.114852 ↗
17. Two-dimensional nanofluidics[J]10.1126/science.aaf5289 ↗
18. Nanoporous graphene as a reverse osmosis membrane: recent insights from theory and simulation[J]10.1016/j.desal.2014.12.046 ↗
19. Water desalination using nanoporous single-layer graphene[J]10.1038/nnano.2015.37 ↗
20. Self-assembly: a facile way of forming ultrathin, high-performance graphene oxide membranes for water purification[J]10.1021/acs.nanolett.7b00148 ↗
21. Adjustable interlayer spacing of ultrathin mxene-derived membranes for ion rejection[J]10.1016/j.memsci.2019.117350 ↗
22. Experimental realization of few layer two-dimensional mos 2 membranes of near atomic thickness for high efficiency water desalination[J]10.1021/acs.nanolett.9b01577 ↗
23. Subatomic species transport through atomically thin membranes: present and future applications[J]10.1126/science.abd7687 ↗
24. Single-layer graphene membranes withstand ultrahigh applied pressure[J]10.1021/acs.nanolett.7b00442 ↗
25. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]10.1126/science.1157996 ↗
26. Ultrastrong adhesion of graphene membranes[J]10.1038/nnano.2011.123 ↗
27. Graphene: a perfect nanoballoon[J]10.1063/1.3021413 ↗
28. First principles study of the permeability of graphene to hydrogen atoms[J]10.1039/c3cp52318g ↗
29. Proton transport through one-atom-thick crystals[J]10.1038/nature14015 ↗
30. Sieving hydrogen isotopes through two-dimensional crystals[J]10.1126/science.aac9726 ↗
31. Scalable and efficient separation of hydrogen isotopes using graphene-based electrochemical pumping[J]10.1038/ncomms15215 ↗
32. Aqueous proton transfer across single-layer graphene[J]10.1038/ncomms7539 ↗
33. Measuring the proton selectivity of graphene membranes[J]10.1063/1.4936335 ↗
34. Hydrogenation facilitates proton transfer through two-dimensional honeycomb crystals[J]10.1021/acs.jpclett.7b02820 ↗
35. Quantum tunneling of thermal protons through pristine graphene[J]10.1063/1.5024317 ↗
36. Stone–wales defects cause high proton permeability and isotope selectivity of single‐layer graphene[J]10.1002/adma.202002442 ↗
37. Preparation of 2d material dispersions and their applications[J]10.1039/C8CS00254A ↗
38. Progress in large-scale production of graphene. part 2: vapor methods[J]10.1007/s11837-014-1237-z ↗
39. Electronic confinement and coherence in patterned epitaxial graphene[J]10.1126/science.1125925 ↗
40. Graphene on metal surfaces[J]10.1016/j.susc.2008.08.037 ↗
41. Large-scale pattern growth of graphene films for stretchable transparent electrodes[J]10.1038/nature07719 ↗
42. Water desalination across nanoporous graphene[J]10.1021/nl3012853 ↗
43. Selective molecular transport through intrinsic defects in a single layer of cvd graphene[J]10.1021/nn303869m ↗
44. Ultrafast nanofiltration through large-area single-layered graphene membranes[J]10.1021/acsami.7b00504 ↗
45. Nanofiltration across defect-sealed nanoporous monolayer graphene[J]10.1021/acs.nanolett.5b00456 ↗
46. Large total area membrane of suspended single layer graphene for water desalination[J]10.1016/j.desal.2017.12.050 ↗
47. Large-area graphene-nanomesh/carbon-nanotube hybrid membranes for ionic and molecular nanofiltration[J]10.1126/science.aau5321 ↗
48. Surface slip on rotating graphene membrane enables the temporal selectivity that breaks the permeability-selectivity trade-off[J]10.1126/sciadv.aba9471 ↗
49. Selective ion passage through functionalized graphene nanopores[J]10.1021/ja804409f ↗
50. Selective ionic transport through tunable subnanometer pores in single-layer graphene membranes[J]10.1021/nl404118f ↗
51. Ion selectivity of graphene nanopores[J]10.1038/ncomms11408 ↗
52. Tunable anion-selective transport through monolayer graphene and hexagonal boron nitride[J]10.1021/acsnano.9b08168 ↗
53. The role of sp 2 /sp 3 hybrid carbon regulation in the nonlinear optical properties of graphene oxide materials[J]10.1039/C7RA10505C ↗
54. Thermally reduced nanoporous graphene oxide membrane for desalination[J]10.1021/acs.est.9b01914 ↗
55. Preparation of graphitic oxide[J]10.1021/ja01539a017 ↗
56. Graphene oxide membranes: controlling their transport pathways[J]10.1039/D0TA02249G ↗
57. Unimpeded permeation of water through helium-leak–tight graphene-based membranes[J]10.1126/science.1211694 ↗
58. Ultrafast liquid water transport through graphene-based nanochannels measured by isotope labelling[J]10.1039/C4CC10103K ↗
59. Selective ion penetration of graphene oxide membranes[J]10.1021/nn304471w ↗
60. Precise and ultrafast molecular sieving through graphene oxide membranes[J]10.1126/science.1245711 ↗
61. Ultrathin water-stable metal-organic framework membranes for ion separation[J]10.1126/sciadv.aay3998 ↗
62. Enabling graphene oxide nanosheets as water separation membranes[J]10.1021/es400571g ↗
63. Ultrathin graphene nanofiltration membrane for water purification[J]10.1002/adfm.201202601 ↗
64. Salt concentration, ph and pressure controlled separation of small molecules through lamellar graphene oxide membranes[J]10.1039/c3cc41953c ↗
65. Electro- and magneto-modulated ion transport through graphene oxide membranes[J]
66. Highly efficient quasi-static water desalination using monolayer graphene oxide/titania hybrid laminates[J]10.1038/am.2015.7 ↗
67. Controllable ion transport by surface-charged graphene oxide membrane[J]
68. Swelling of graphene oxide membranes in aqueous solution: characterization of interlayer spacing and insight into water transport mechanisms[J]10.1021/acsnano.7b02999 ↗
69. Hydrogen bond networks in graphene oxide composite paper: structure and mechanical properties[J]10.1021/nn901934u ↗
70. Tunable sieving of ions using graphene oxide membranes[J]10.1038/nnano.2017.21 ↗
71. Ion sieving in graphene oxide membranes via cationic control of interlayer spacing[J]10.1038/nature24044 ↗
72. Water permeability and water/salt selectivity tradeoff in polymers for desalination[J]10.1016/j.memsci.2010.11.054 ↗
73. Square ice in graphene nanocapillaries[J]10.1038/nature14295 ↗