CoMoO4-N-doped carbon hybrid nanoparticles loaded on a petroleum asphalt-based porous carbon for lithium storage
Source abstract
Abstract
超精细过渡金属氧化物（TMO）在储锂方面具有巨大潜力，但在实际应用中还存在易团聚、电导率低等挑战。本文采用双炭复合方法，首先将ZIFs-67固定于模板法制备的石油沥青基多孔炭骨架上，然后将配位Co2+原位转化为CoMoO4@炭纳米颗粒，生成CoMoO4@炭纳米颗粒/多孔炭骨架（CoMoO4@CP/CF）。通过ZIFs-67热解制备出N掺杂炭骨架，从本质上提高CoMoO4电子传输能力，而超细炭纳米颗粒可以有效阻止CoMoO4聚集。基于上述优点，将该复合材料用做锂离子电池负极，电流密度为1 A g-1时，可提供高达818 mAh g-1的可逆比容量。该合成方法为高性能储能电极材料的设计提供了新途径。
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Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies
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