A review of graphynes: Properties, applications and synthesis
Source abstract
Abstract
Graphyne, a kind of sp-sp2 hybrid all-carbon two-dimensional material, is currently one of the most interesting carbon allotropes besides graphene. It has potential applications and characteristic properties because of its unique electronic structure. First,the concept and properties of graphyne are summarized, then the characteristic properties of graphynes and their potential applications are reviewed, before some methods and ways to synthesize the two-dimensional structures are proposed, and finally a short perspective on the study of graphynesis given.
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Research context
OpenAlex topics: Graphene research and applications · Advancements in Battery Materials · 2D Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
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1. Inagaki · 2011 · 3
2. Inagaki · 2013 · 2
3. A new allotropic form of carbon from the Ries Crater [J]10.1126/science.161.3839.363 ↗
4. Carbon: A new view of its high-temperature behavior [J]10.1126/science.200.4343.763 ↗
5. Carbynes: carriers of priomordial noble gases in meteorites [J]10.1126/science.209.4464.1512 ↗
6. Carbynes in meteorites: detection, low-temperature origin, and implications for interstellar molecules[J]10.1126/science.209.4464.1515 ↗
7. C60: Buckminsterfullerene [J]10.1038/318162a0 ↗
8. Helical microtubules of graphitic carbon [J]10.1038/354056a0 ↗
9. Electric field effect in atomically thin carbon films [J]10.1126/science.1102896 ↗
10. Graphene derivatives: Graphane, fluorographene, graphene oxide, graphyne and graphdiyne [J]10.1039/C4TA01183J ↗
11. Two-dimensional atomic crystals [J]10.1073/pnas.0502848102 ↗
12. heterostructures [J]10.1038/nature12385 ↗
13. All-carbon scaffolds by rational design [J]10.1002/adma.200902623 ↗
14. The era of carbon allotropes [J]10.1038/nmat2885 ↗
15. Carbon scaffolding: Building acetylenic all-carbon and carbon-rich compounds [J]10.1038/369199a0 ↗
16. Carbon networks based on dehydrobenzoannulenes: Synthesis of graphdiyne substructures [J]10.1002/anie.199708361 ↗
17. Carbon network based on dehydrobenzoannulenes: Part 2 synthesis of expanded graphdiyne substructures [J]10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y ↗
18. Carbon network based on dehydrobenzoannulenes. 3. Synthesis of graphyne substructures [J]10.1021/ol005623w ↗
19. Carbon networks based on dehydrobenzoannulenes. 4. Synthesis of “Star” and “Trefoil” graphdiyne substructures via sixfoldcross-coupling of hexaiodobenzene [J]10.1021/jo010183n ↗
20. Carbon networks based on dehydrobenzoannulenes. 5. Extension of two-dimensionalconjugation in graphdiynenanoarchitectures [J]10.1021/jo050926v ↗
21. Graphdiyne: Synthesis, properties, and applications [J]10.1039/C8CS00773J ↗
22. Exploring approaches for the synthesis of few-layered graphdiyne [J]10.1002/adma.201803758 ↗
23. Two dimensional polymers-progress of full carbon graphyne [J]
24. Graphdiyne and graphyne: From theoretical predictions to practical construction[J]10.1039/c3cs60388a ↗
25. Graphynes and graphdiynes[J]10.1016/j.progsolidstchem.2012.12.001 ↗
26. Structure-property predictions for new planar forms of carbon: Layere phases containing sp2 and sp atoms [J]10.1063/1.453405 ↗
27. Extended graphynes: Simple scaling laws for stiffness, strength and fracture [J]10.1039/c2nr31644g ↗
28. Competition for graphene: Graphynes with direction-dependent Dirac cones [J]10.1103/PhysRevLett.108.086804 ↗
29. Can graphynes turn into graphene at room temperature [J]?10.1016/j.carbon.2014.02.065 ↗
30. Optimized geometries and electronic structures of graphyne and its family [J]10.1103/PhysRevB.58.11009 ↗
31. Electronic structure of three-dimesionalgraphyne [J]10.1103/PhysRevB.62.11146 ↗
32. Quasiparticle energies and excitonic effects of the two-dimensional carbon allotrope graphdiyne: Theory and experiment [J]10.1103/PhysRevB.84.075439 ↗
33. Electronic structure and carrier mobility in graphdiyne sheet and nanoribbons: Theoretical predictions [J]10.1021/nn102472s ↗
34. Two-dimensional second-order topological insulator in graphdiyne [J]10.1103/PhysRevLett.123.256402 ↗
35. Electronic properties of graphyne and graphdiyne in tight-binding model [J]10.1149/2162-8777/ab801b ↗
36. Electronic transport properties of graphyne and its family [J]10.1016/j.commatsci.2013.05.026 ↗
37. Electronic properties and carrier mobilities of 6,6,12-graphyne nanoribbons [J]10.1063/1.4927497 ↗
38. Electronic properties of bilayer and trilayergraphyne in the presence of electric field [J]10.1007/s11224-013-0350-x ↗
39. Electronic and magnetic properties of zigzag α-graphyne nanoribbons with edge fluorine modification [J]10.1016/j.jmmm.2019.166194 ↗
40. Investigation of electronic and optical properties of zigzag α-graphyne nanotubes by using a tight-binding method [J]10.1007/s11664-019-07257-9 ↗
41. Electronic properties of β-graphyne bilayers [J]10.1016/j.cplett.2014.12.038 ↗
42. Electronic, phononic, and thermoelectric properties of graphyne sheets [J]10.1063/1.4902920 ↗
43. Molecular dynamics investigation of the mechanical properties of two different grraphyne allotropes: α-grraphyne and α2-graphyne [J]10.1016/j.physe.2020.114022 ↗
44. N-, B-, P-, Al-, As-, and Ga-graphdiyne/graphynelattics: First-principles investigation of mechanical, optical and electronic properties [J]10.1039/C9TC00082H ↗
45. Mechanical properties of graphyne [J]10.1016/j.carbon.2011.05.024 ↗
46. Strength and fracture of graphyne and graphdiyne nanotubes [J]10.1016/j.commatsci.2019.109233 ↗
47. Mechanical properties of graphidyne sheet [J]10.1016/j.physb.2012.07.026 ↗
48. On the mechanical properties of the graphdiyne nanotubes: a molecular dynamics investigation [J]10.1007/s13538-019-00673-6 ↗
49. Mechanical properties of graphyne monolayers: a first-principles study [J]10.1039/c2cp42387a ↗
50. Mechanical properties of hydrogen functionalized graphyne - A molecular dynamics investigation [J]10.4028/www.scientific.net/AMR.472-475.1813 ↗
51. Unusual mechanical and electronic behaviors of bulk layered hydrogen substituted graphdiyne under biaxial strain [J]10.1016/j.apsusc.2020.145694 ↗
52. State-of-the-art reviews and analyses of emerging research findings and achievements of thermoelectric materials over the past years [J]10.1007/s11664-018-06838-4 ↗
53. Thermoelectric properties of gamma-graphyne nanoribbons and nanojunctions [J]10.1063/1.4818616 ↗
54. The origin of intrinsic charge transport for Dirac carbon sheet materials: Roles of acetylenic linkage and electron-phonon couplings [J]10.1039/C9NR01734H ↗
55. A molecular dynamics investigation on thermal conductivity of graphynes [J]10.1016/j.commatsci.2012.07.044 ↗
56. Optimizing the thermoelectric performance of γ-graphyne nanoribbons via introducing disordered surface fluctutation [J]10.1016/j.ssc.2019.113646 ↗
57. Tunable thermal conductivity in carbon allotrope sheets: Role of acetylenic linkages [J]10.1063/1.4936111 ↗
58. Tunable thermal transport and mechanical properties of graphyne heterojunctions [J]10.1039/C6CP02927B ↗
59. Magnetic and electronic properties of α-graphyne nanoribbons [J]10.1063/1.4730325 ↗
60. Two-dimensional ferromagnetism and spin filtering in Cr and Mn-doped graphdiyne [J]10.1016/j.jpcs.2017.02.009 ↗
61. Single-atom vacancy induced changes in electronic and magnetic properties of graphyne [J]10.1016/j.carbon.2017.01.068 ↗
62. Tuning the magnetic property of vancancy-defected graphyne by transition metal absorption[J]10.1063/1.4917707 ↗
63. Magnetic properties of single transition-metal atom absorbed graphdiyne and graphyne sheet from DFT+U calculations [J]10.1021/jp307408u ↗
64. Ferromagnetism and perfect spin filtering in transition-metal-doped graphyne nanoribbons [J]10.1103/PhysRevB.92.205429 ↗
65. First principles investigation of hydrogen physical adsorption on graphynes' layers [J]10.1016/j.carbon.2015.08.118 ↗
66. Ultra-high hydrogen storage capacity of Li-decorated graphyne: A first-principles prediction [J]10.1063/1.4759235 ↗
67. A comparative investigation of metal (Li, Ca and Sc)-decorated 6,6,12-graphyne monolayers and 6,6,12-graphyne nanotubes for hydrogen storage [J]10.1016/j.apsusc.2019.143763 ↗
68. Calcium-decorated graphyne nanotubes as promising hydrogen storage media: A first-principles study [J]10.1016/j.jssc.2012.09.004 ↗
69. Mechanical properties of two-dimensional graphyne sheet under hydrogen adsorption [J]10.1016/j.ssc.2012.07.024 ↗
70. Lithium and sodium decorated graphdiyne as a candidate for hydrogen storage: First-principles and grand canonical Monte Carlo study [J]10.1016/j.apsusc.2019.144855 ↗
71. A comparative study for hydrogen storage in metal decorated graphyne nanotubes and graphyne monolayers [J]10.1016/j.jssc.2015.08.004 ↗
72. Multiscale design of graphyne-based materials for high-performance separation membranes [J]10.1002/adma.201805665 ↗
73. Graphenylene-1 membrane: An excellent candidate for hydrogen purification and helium separation [J]10.1016/j.carbon.2019.10.064 ↗
74. High mobility and high storage capacity of lithium in sp-sp2 hybridized carbon network: The case of graphyne [J]10.1021/jp201062m ↗
75. Study of Li adsorption on graphdiyne using hybrid DFT calculations [J]10.1021/acsami.8b03482 ↗
76. Graphdiyne: A promising anode material for lithium ion batteries with high capacity and rate capability [J]
77. 2D graphdiyne: An excellent untraviolet nonlinear absorption material [J]10.1039/C9NR10704E ↗
78. Two-dimensional γ-graphyne for ultrafast nonlinear optical applications [J]10.1364/OME.377354 ↗
79. Theoretical study on novel superalkali doped graphdiyne complexes: Unique approach for the enhancement of electronic and nonlinear optical response [J]10.1016/j.jmgm.2020.107573 ↗
80. Two-dimensional halogen-substituted graphdiyne: first-principles investigation of mechanical, electronic, optical, and photocatalytic properties [J]10.1007/s10853-020-04597-4 ↗
81. Rigid unit modes in sp-sp2 hybridized carbon systems: Origin of negative thermal expansion [J]10.1103/PhysRevB.92.245434 ↗
82. Evaluation of carbon nanscroll materials for post-combustion CO2capture [J]10.1016/j.carbon.2016.01.072 ↗
83. Investigation of the electronic and structural properties of graphyne oxide toward CO, CO2 and NH3 adsorption: A DFT and MD study [J]10.1016/j.apsusc.2019.145134 ↗
84. Doping and vacancy effect of graphyne on SO2 adsorption [J]10.1016/j.jcis.2017.01.019 ↗
85. Molecular dynamics simulations of the adsorption of polymer chains on graphyne and its family [J]10.1016/j.physb.2014.08.017 ↗
86. Density functional theory study of acrolein adsorption on graphyne [J]10.1139/cjc-2015-0267 ↗
87. Graphynes for water desalination and gas separation [J]
88. Single-layer graphyne membranes for super-excellent brine separation in forward osmosis [J]10.1039/C5RA09512C ↗
89. Advances of graphdiyne supported metal atomic catalysts [J]
90. Ultrathin nanosheet of graphdiyne-supported palladium atom catalyst for efficient hydrogen production [J]
91. Detection of hydrogen peroxide with graphyne [J]10.1016/j.physe.2013.06.029 ↗
92. Detection of toxic gases with graphyne nanotubes: A density functional theory study [J]10.1246/cl.150333 ↗
93. Decorated graphyne and its boron nitride analogue as versatile nanomaterials for CO detection [J]10.1080/00268976.2015.1080388 ↗
94. Graphdiyne as a promising material for detecting amino acids [J]
95. Impact of graphyne on structural and dynamic properties of calmodulin [J]10.1039/C7CP00720E ↗
96. Mechanisms of graphyne-enabled cholesterol extraction from protein clusters [J]10.1039/C4RA16944A ↗
97. Graphyne as a promising substrate for high density magnetic storage bits [J]10.1039/C5RA18767B ↗
98. Architecture of graphdiyne nanoscale films [J]10.1039/b922733d ↗
99. Synthesis of graphdiynenanowalls using acetylenic coupling reaction [J]10.1021/jacs.5b04057 ↗
100. Superlyophilicity-facilitated synthesis reaction at the microscale: ordered graphdiyne stripe arrays [J]10.1002/smll.201602265 ↗