The use of carbon materials in persulfate-based advanced oxidation processes: A review
Source abstract
Abstract
With their unique nanostructure, excellent conductivity, chemical stability and adsorption properties, carbon materials have awiderange of application possibilities in the field of catalysis, and are expected to become a new generation of green non-metallic catalysts. In recent years, worldwide research on the applications of various carbon materials in the advanced oxidation technology using activated persulfate (PS) has developed rapidly. Here, theoretical and applied research progress on graphene-based materials, carbon nanotubes, carbon fibers, porous carbons, carbon aerogels, carbon microspheres, carbon nanobubbles and carbon quantum dots as heterogeneous catalysts to activate peroxymonosulfate and peroxydisulfate are reviewed. The preparation methods and structural characteristics of the carbon catalysts, the relationship between their structure and activity in the activation of PS, the paths for the generation of free radicals and non-free radicals, and the uses of carbon materials in the degradation of pollutants by activated PS are summarized. Finally, the challenges of poor stability, environmental risks and high costs of carbon catalysts in practical applications and their solutions are pointed out, with the aimof providing references for the further applications of carbon materials in advanced oxidation technologies.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced oxidation water treatment · Advanced Photocatalysis Techniques · Industrial Gas Emission Control
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
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1. Emerging contaminants of high concern and their enzyme-assisted biodegradation-A review[J]10.1016/j.envint.2019.01.011 ↗
2. Research progress in remediation of organic contaminated soil by activated persulfate oxidation[J]
3. Activated persulfate for organic chemical degradation: A review[J]10.1016/j.chemosphere.2016.02.055 ↗
4. Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: Review[J]10.1016/j.cej.2016.10.064 ↗
5. Metal-free carbocatalysis in advanced oxidation reactions[J]10.1021/acs.accounts.7b00535 ↗
6. Carbon-based magnetic nanocopsite as catalyst for persulfate activation: A critical review[J]10.1007/s11356-019-06403-4 ↗
7. Graphene- and CNTs-based carbocatalysts in persulfates activation: Material design and catalytic mechanisms[J]10.1016/j.cej.2018.08.049 ↗
8. Persulfate-based advanced oxidation processes (AOPs) for organic-contaminated soil remediation: A review[J]10.1016/j.cej.2019.04.213 ↗
9. Persulfate-based advanced oxidation: Critical assessment of opportunities and roadblocks[J]10.1021/acs.est.9b07082 ↗
10. Unveiling the active sites of graphene-catalyzed peroxymonosulfateactivation[J]10.1016/j.carbon.2016.06.016 ↗
11. Oxidative degradation of bisphenol A by carbocatalytic activation of persulfate and peroxymonosulfate with reduced graphene oxide[J]10.1016/j.jhazmat.2018.07.098 ↗
12. Simultaneous enhancement of adsorption and peroxymonosulfate activation of Nitrogen-doped reduced graphene oxide for bisphenol A removal[J]10.1016/j.jece.2017.08.018 ↗
13. Nitrogen-doped graphene as peroxymonosulfate activator and electron transfer mediator for the enhanced degradation of sulfamethoxazole[J]10.1016/j.cej.2019.122041 ↗
14. An insight into metal organic framework derived N-doped graphene for the oxidative degradation of persistent contaminants: formation mechanism and generation of singlet oxygen from peroxymonosulfate[J]
15. Enhancing sulfacetamide degradation by peroxymonosulfate activation with N-doped graphene produced through delicately-controlled nitrogen functionalization via tweaking thermal annealing processes[J]10.1016/j.apcatb.2017.11.071 ↗
16. Nitrogen-sulfur co-doped industrial graphene as an efficient peroxymonosulfate activator: Singlet oxygen-dominated catalytic degradation of organic contaminants[J]10.1016/j.apcatb.2019.03.085 ↗
17. Insights into nitrogen and boron-co-doped graphene toward high-performance peroxymonosulfate activation: Maneuverable N-B bonding configurations and oxidation pathways[J]10.1016/j.apcatb.2019.04.018 ↗
18. Synthesis of Co3O4/graphene composite catalysts through CTAB-assisted method for Orange II degradation by activation of peroxymonosulfate[J]
19. Magnetic CoFe2O4 nanoparticles supported on graphene oxide (CoFe2O4/GO) with high catalytic activity for peroxymonosulfate activation and degradation of rhodamine B[J]10.1039/C7RA09949E ↗
20. Magnetic cobalt–graphene nanocomposite derived from self-assembly of MOFs with graphene oxide as an activator for peroxymonosulfate[J]10.1039/C4TA06516F ↗
21. Hydrothermal synthesis of Co3O4–graphene for heterogeneous activation of peroxymonosulfate for decomposition of phenol[J]10.1021/ie301642g ↗
22. Degradation of norfloxacin by CoFe2O4-GO composite coupled with peroxymonosulfate: A comparative study and mechanistic consideration[J]10.1016/j.cej.2017.10.040 ↗
23. Environmental application of graphene-based CoFe2O4 as an activator of peroxymonosulfate for the degradation of a plasticizer[J]10.1016/j.cej.2014.11.065 ↗
24. Facile green synthetic graphene-based Co-Fe Prussian blue analogues as an activator of peroxymonosulfate for the degradation of levofloxacin hydrochloride[J]10.1016/j.jcis.2018.04.070 ↗
25. Graphene oxide–supported cobalt phthalocyanine as heterogeneous catalyst to activate peroxymonosulfate for efficient degradation of norfloxacin antibiotics[J]10.1061/(ASCE)EE.1943-7870.0001395 ↗
26. Cobalt phthalocyanine-supported reduced graphene oxide: A highly efficient catalyst for heterogeneous activation of peroxymonosulfate for rhodamine B and pentachlorophenol degradation[J]10.1016/j.cej.2017.12.009 ↗
27. Fast and complete degradation of norfloxacin by using Fe/Fe3C@NG as a bifunctional catalyst for activating peroxymonosulfate[J]10.1016/j.seppur.2018.03.049 ↗
28. Magnetic recoverable MnFe2O4 and MnFe2O4-graphene hybrid as heterogeneous catalysts of peroxymonosulfate activation for efficient degradation of aqueous organic pollutants[J]10.1016/j.jhazmat.2014.01.027 ↗
29. Coupling metal–organic frameworks and g-C3N4to derive Fe@N-doped graphene-like carbon for peroxymonosulfate activation: Upgrading framework stability and performance[J]
30. Efficient activation of peroxymonosulfate by magnetic Mn-MGO for degradation of bisphenol A[J]10.1016/j.jhazmat.2016.08.021 ↗
31. Oxidation of bromophenols by carbon nanotube activated peroxymonosulfate (PMS) and formation of brominated products: Comparison to peroxydisulfate (PDS)[J]10.1016/j.cej.2017.12.083 ↗
32. Decolorization of azo dye by peroxymonosulfate activated by carbon nanotube: Radical versus non-radical mechanism[J]10.1016/j.jhazmat.2016.07.038 ↗
33. Non-radical-dominated catalytic degradation of bisphenol A by ZIF-67 derived nitrogen-doped carbon nanotubes frameworks in the presence of peroxymonosulfate[J]10.1016/j.cej.2017.11.164 ↗
34. Temperature-dependent evolution of hydroxyl radicals from peroxymonosulfate activation over nitrogen-modified carbon nanotubes[J]10.1016/j.susmat.2018.e00082 ↗
35. Fe/Mn nanoparticles encapsulated in nitrogen-doped carbon nanotubes as a peroxymonosulfate activator for acetamiprid degradation[J]
36. One-step synthesis of novel Fe3C@nitrogen-doped carbon nanotubes/graphene nanosheets for catalytic degradation of Bisphenol A in the presence of peroxymonosulfate[J]10.1016/j.cej.2018.09.093 ↗
37. Activated carbon fiber as heterogeneous catalyst of peroxymonosulfate activation for efficient degradation of acid orange 7 in aqueous solution[J]10.1016/j.seppur.2015.01.022 ↗
38. Role of surface chemistry in modified ACF (activated carbon fiber)-catalyzed peroxymonosulfate oxidation[J]10.1016/j.apsusc.2016.04.163 ↗
39. Reuse performance of granular-activated carbon and activated carbon fiber in catalyzed peroxymonosulfateoxidation[J]10.1080/09593330.2016.1205147 ↗
40. Iodine-doped carbon fibers as an efficient metal-free catalyst to activate peroxymonosulfate for the removal of organic pollutants[J]10.1039/C8CY01537F ↗
41. Electrospun magnetic cobalt–carbon nanofiber composites with axis-sheath structure for efficient peroxymonosulfateactivation[J]10.1016/j.apsusc.2018.05.065 ↗
42. Key role of activated carbon fibers in enhanced decomposition of pollutants using heterogeneous cobalt/peroxymonosulfatesystem[J]10.1002/jctb.4715 ↗
43. Cobalt ferrite nanoparticles supported on electrospun carbon fiber as a magnetic heterogeneous catalyst for activating peroxymonosulfate[J]10.1016/j.chemosphere.2018.05.127 ↗
44. Peroxymonosulfate enhanced photoelectrocatalytic degradation of phenol activated by Co3O4 loaded carbon fiber cathode[J]10.1016/j.jcat.2017.09.016 ↗
45. ZIF-8 derived nitrogen-doped porous carbon as metal-free catalyst of peroxymonosulfateactivation[J]10.1007/s11356-017-9191-2 ↗
46. Enhanced activation of peroxymonosulfate by nitrogen doped porous carbon for effective removal of organic pollutants[J]10.1016/j.carbon.2017.01.060 ↗
47. N-doped hierarchically porous carbon for highly efficient metal-free catalytic activation of peroxymonosulfate in water: A non-radical mechanism[J]10.1016/j.chemosphere.2018.10.175 ↗
48. Human-hair-derived N, S-doped porous carbon: An enrichment and degradation system for wastewater remediation in the presence of peroxymonosulfate[J]10.1021/acssuschemeng.8b05801 ↗
49. Enhanced heterogeneous activation of peroxymonosulfate by Co and N codoped porous carbon for degradation of organic pollutants: The synergism between Co and N[J]
50. Enhancement of Fe@porous carbon to be an efficient mediator for peroxymonosulfate activation for oxidation of organic contaminants: Incorporation NH2-group into structure of its MOF precursor[J]10.1016/j.cej.2018.08.060 ↗
51. Fe/Fe3C@N-doped porous carbon hybrids derived from nano-scale MOFs: Robust and enhanced heterogeneous catalyst for peroxymonosulfate activation[J]10.1039/C6CY02130A ↗
52. nanocarbons in different structural dimensions(0-3D) for phenol adsorption and metal-free catalytic oxidation[J]10.1016/j.apcatb.2015.05.049 ↗
53. Highly effective catalytic peroxymonosulfate activation on N-doped mesoporous carbon for o-phenylphenol degradation[J]10.1016/j.chemosphere.2018.01.031 ↗
54. Insights into heterogeneous catalysis of peroxymonosulfate activation by boron-doped ordered mesoporous carbon[J]10.1016/j.carbon.2018.01.106 ↗
55. Heterogeneous degradation of refractory pollutants by peroxymonosulfate activated by CoOx-doped ordered mesoporous carbon[J]10.1016/j.cej.2017.07.042 ↗
56. Monolithic cobalt-doped carbon aerogel for efficient catalytic activation of peroxymonosulfate in water[J]10.1016/j.jhazmat.2017.03.010 ↗
57. Co3O4 nanocrystals/3D nitrogen-doped graphene aerogel: A synergistic hybrid for peroxymonosulfate activation toward the degradation of organic pollutants[J]10.1016/j.chemosphere.2018.07.065 ↗
58. Prussian blue analogues derived porous nitrogen-doped carbon microspheres as high-performance metal-free peroxymonosulfate activators for non-radical-dominated degradation of organic pollutants[J]10.1039/C7TA08472B ↗
59. Carbon microspheres supported cobalt catalysts for phenol oxidation with peroxymonosulfate[J]10.1016/j.cherd.2015.07.009 ↗
60. Template synthesis of nitrogen-doped carbon nanocages–encapsulated carbon nanobubbles as catalyst for activation of peroxymonosulfate[J]10.1039/C8QI00256H ↗
61. Graphene: A new activator of sodium persulfate for the advanced oxidation of parabens in water[J]10.1016/j.watres.2017.09.020 ↗
62. Metal-free catalysis of persulfate activation and organic-pollutant degradation by nitrogen-doped graphene and aminatedgraphene[J]10.1016/j.envpol.2016.04.088 ↗
63. Metal-free graphene-based catalytic membrane for degradation of organic contaminants by persulfate activation[J]10.1016/j.cej.2019.02.211 ↗
64. Zero-valent iron nanofibers (ZVINFs) immobilized on the surface of reduced ultra-large graphene oxide (rULGO) as a persulfate activator for treatment of landfill leachate[J]10.1016/j.jece.2018.10.011 ↗
65. Efficient degradation of trichloroethylene in water using persulfate activated by reduced graphene oxide-iron nanocomposite[J]10.1007/s11356-015-5034-1 ↗
66. Insights into atrazine degradation by persulfate activation using composite of nanoscale zero-valent iron and graphene: Performances and mechanisms[J]10.1016/j.cej.2018.01.136 ↗
67. Degradation of trichloroethylene by activated persulfate using a reduced graphene oxide supported magnetite nanoparticle[J]10.1016/j.cej.2016.01.085 ↗
68. Sono-assisted synthesis of CuOnanorods–graphene oxide as a synergistic activator of persulfate for bisphenol A removal[J]10.1016/j.jece.2018.06.010 ↗
69. Degradation of dye wastewater by persulfate activated with Fe3O4/graphene nanocomposite[J]10.2166/wrd.2016.187 ↗
70. Heterogeneous activation of persulfate by reduced graphene oxide–elemental silver/magnetite nanohybrids for the oxidative degradation of pharmaceuticals and endocrine disrupting compounds in water[J]10.1016/j.apcatb.2017.11.058 ↗
71. Enhanced visible-light activation of persulfate by Ti3+ self-doped TiO2/graphene nanocomposite for the rapid and efficient degradation of micropollutants in water[J]10.1016/j.jhazmat.2018.10.090 ↗
72. An efficient graphene supported copper salen catalyst for the activation of persulfate to remove chlorophenols in aqueous solution[J]10.1016/j.cej.2018.11.208 ↗
73. Facile synthesis of nitrogen doped reduced grapheme oxide as a superior metal-free catalyst for oxidation[J]10.1039/c3cc43401j ↗
74. Nitrogen-doped grapheme for generation and evolution of reactive redicals by metal-free catalysis[J]10.1021/am508416n ↗
75. Heterogeneous metals and metal-free carbon meterials for oxidative degradation through persulfate activation: A review of heterogeneous catalytic activation of persulfate related to oxidation mechanism[J]10.1007/s11814-019-0398-4 ↗
76. Oxidation dinetics of bromophenols by nonradical activation of peroxydisulfate in the presence of carbon nanotube and formation of brominated polymeric products[J]10.1021/acs.est.7b02271 ↗
77. Insights into the mechanism of nonradical reactions of persulfate activated by carbon nanotubes: Activation performance and structure-function relationship[J]10.1016/j.watres.2019.03.096 ↗
78. Non-photochemical production of singlet oxygen via activation of persulfate by carbon nanotubes[J]10.1016/j.watres.2017.02.016 ↗
79. Activation of persulfates by carbon nanotubes: Oxidation of organic compounds by nonradicalmechanism[J]10.1016/j.cej.2014.12.065 ↗
80. Activation of peroxydisulfate on carbon nanotubes: Electron-transfer mechanism[J]10.1021/acs.est.9b05475 ↗
81. Effect of iodide on transformation of phenolic compounds by nonradical activation of peroxydisulfate in the presence of carbon nanotube: Kinetics, impacting factors, and formation of iodinated aromatic products[J]10.1016/j.chemosphere.2018.06.019 ↗
82. Enhanced activation of persulfate by nitric acid/annealing modified multi-walled carbon nanotubes via non-radical process[J]10.1016/j.chemosphere.2018.12.136 ↗
83. Catalytic degradation of diethyl phthalate in aqueous solution by persulfate activated with nano-scaled magnetic CuFe2O4/MWCNTs[J]10.1016/j.cej.2016.04.096 ↗
84. Oxidation of 2,4-dichlorophenol by non-radical mechanism using persulfate activated by Fe/S modified carbon nanotubes[J]10.1016/j.jcis.2016.01.067 ↗
85. Nitrogen-doped bamboo-like carbon nanotubes with Ni encapsulation for persulfate activation to remove emerging contaminants with excellent catalytic stability[J]10.1016/j.cej.2017.09.102 ↗
86. Degradation of flumequine in aqueous solution by persulfate activated with common methods and polyhydroquinone-coated magnetite/multi-walled carbon nanotubes catalysts[J]10.1016/j.watres.2015.08.011 ↗
87. Activated carbon fiber for heterogeneous activation of persulfate: Implication for the decolorization of azo dye[J]10.1007/s11356-016-7015-4 ↗
88. Ultrasound enhanced activation of peroxydisulfate by activated carbon fiber for decolorization of azo dye[J]10.1007/s11356-018-1442-3 ↗
89. Removal of carbamazepine in water by electro-activated carbon fiber-peroxydisulfate: Comparison, optimization, recycle, and mechanism study[J]10.1016/j.cej.2018.02.114 ↗
90. Enhanced activation process of persulfate by mesoporous carbon for degradation of aqueous organic pollutants: Electron transfer mechanism[J]10.1016/j.apcatb.2018.02.059 ↗
91. Metal-free activation of persulfate by cubic mesoporous carbons for catalytic oxidation via radical and nonradicalprocesses[J]10.1016/j.cattod.2017.04.038 ↗
92. Highly efficient utilization of nano-Fe(0) embedded in mesoporous carbon for activation of peroxydisulfate[J]10.1021/acs.est.9b02170 ↗
93. Catalytic degradation of tetracycline hydrochloride by persulfate activated with nano Fe0 immobilized mesoporous carbon[J]10.1016/j.cej.2018.02.034 ↗
94. Enhanced activation of persulfate by carbohydrate-derived carbon cryogels for effective removal of organic pollutants[J]10.1016/j.cej.2018.07.072 ↗
95. Oxidation of rhodamine B by persulfate activated with porous carbon aerogel through a non-radical mechanism[J]10.1016/j.jhazmat.2018.06.048 ↗
96. Activation of sodium persulfate by magnetic carbon xerogels (CX/CoFe) for the oxidation of bisphenol A: Process variables effects, matrix effects and reaction pathways[J]10.1016/j.watres.2017.07.046 ↗
97. Degradation of propyl paraben by activated persulfate using iron-containing magnetic carbonxerogels: Investigation of water matrix and process synergy effects[J]10.1007/s11356-017-0178-9 ↗
98. Enhanced persulfate degradation of PAH-contaminated sediments using magnetic carbon microspheres as the catalyst substrate[J]10.1016/j.psep.2019.03.011 ↗
99. Supported N-doped carbon quantum dots as the highly effective peroxydisulfate catalysts for bisphenol F degradation[J]10.1016/j.apcatb.2018.07.032 ↗
100. Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: current development, challenges and prospects[J]10.1016/j.apcatb.2016.04.003 ↗