journal article·2023-10-13Open access

Removal of Cr(III) Ions from Water Using Magnetically Separable Graphene-Oxide-Decorated Nickel Ferrite Nanoparticles

Jose Luis Ortiz-Quiñonez, Francisco Enrique Cancino-Gordillo, Umapada Pal

ACS Applied Nano Materials· Volume 6· Issue 19

Abstract

High Resolution Image Download MS PowerPoint Slide Removing toxic metal ions from water is a challenging task due to the increasing demand for potable water worldwide. Utilization of an efficient adsorbent has been the key strategy for addressing this issue. However, the adsorbents utilized so far, whether carbon-based or silica-based, present difficulties in separation from water and pose a harm to aquatic life. In this study, we present a novel approach involving the fabrication of well-dispersed NiFe 2 O 4 nanoparticles, averaging approximately 7 nm in size, integrated with graphene oxide. This nanocomposite proves to be highly effective in removing Cr(III) ions from water. At room temperature, it exhibits a superparamagnetic behavior, enabling easy magnetic separation of the adsorbent from the water. By utilizing the nanocomposite, we achieved a removal rate of approximately 17 mg/g for Cr(III) ions dissolved in water. This ensures that their concentration in the water remains below the EPA-prescribed permissible level of 0.1 mg L –1 . Additionally, we propose a simple and cost-effective optical method for detecting Cr(III) ions in water. This innovative approach shows great promise in tackling the challenge of toxic metal ion removal from water, offering an efficient and environmentally friendly solution.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Graphene and Nanomaterials Applications · Nanomaterials for catalytic reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Instituto de Física, Benemérita Universidad Autónoma de Puebla, C.U., Puebla, Pue 72570, Mexico

Instituto de Ciencias Básicas e Ingeniería, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca Tulancingo, km. 4.5, Ciudad Universitaria, Mineral de la Reforma, Hidalgo C. P. 42184, Mexico

Funding

Consejo Nacional de Ciencia y Tecnolog?a

References (70)

Show source-provided references
1. Chromium in drinking-water. Background document for development of WHO Guidelines for drinking-water quality. https://apps.who.int/iris/bitstream/handle/10665/338062/WHO-HEP-ECH-WSH-2020.3-eng.pdf?sequence=1&isAllowed=y (accessed Jul 28, 2023).
2. 10.1016/j.jhazmat.2005.07.05710.1016/j.jhazmat.2005.07.057 ↗
3. 10.1016/j.scitotenv.2021.14576210.1016/j.scitotenv.2021.145762 ↗
4. 10.1016/j.ijbiomac.2019.09.24910.1016/j.ijbiomac.2019.09.249 ↗
5. 10.1016/j.jhazmat.2021.12607310.1016/j.jhazmat.2021.126073 ↗
6. 10.1016/j.colsurfa.2021.12681910.1016/j.colsurfa.2021.126819 ↗
7. Hexavalent chromium in drinking water. https://portal.ct.gov/-/media/Departments-and-Agencies/DPH/dph/drinking_water/pdf/HexavalentChromiuminDrinkingWaterpdf.pdf (accessed Jul 28, 2023).
8. 10.1016/j.reactfunctpolym.2020.10472010.1016/j.reactfunctpolym.2020.104720 ↗
9. 10.1007/s00216-009-3417-110.1007/s00216-009-3417-1 ↗
10. Housecroft C. E. · 2018
11. 10.1016/j.envpol.2019.11368510.1016/j.envpol.2019.113685 ↗
12. 10.1016/j.geoderma.2011.06.01210.1016/j.geoderma.2011.06.012 ↗
13. 10.1016/j.micromeso.2019.10975410.1016/j.micromeso.2019.109754 ↗
14. 10.1021/acsanm.8b0064310.1021/acsanm.8b00643 ↗
15. 10.1016/j.colsurfa.2014.05.06210.1016/j.colsurfa.2014.05.062 ↗
16. 10.1016/j.molliq.2020.11343210.1016/j.molliq.2020.113432 ↗
17. 10.1039/C8DT01685B10.1039/C8DT01685B ↗
18. 10.1016/j.chemosphere.2020.12731610.1016/j.chemosphere.2020.127316 ↗
19. 10.1016/j.colsurfa.2021.12683210.1016/j.colsurfa.2021.126832 ↗
20. 10.1016/j.jhazmat.2019.02.01310.1016/j.jhazmat.2019.02.013 ↗
21. 10.1016/j.cej.2013.07.10010.1016/j.cej.2013.07.100 ↗
22. 10.1021/acsomega.7b0075710.1021/acsomega.7b00757 ↗
23. 10.1016/j.cjche.2020.04.01910.1016/j.cjche.2020.04.019 ↗
24. 10.3390/s2209329710.3390/s22093297 ↗
25. 10.1039/C6RA28745J10.1039/C6RA28745J ↗
26. 10.1021/acsanm.0c0159710.1021/acsanm.0c01597 ↗
27. 10.1016/j.cej.2018.11.20610.1016/j.cej.2018.11.206 ↗
28. 10.1021/nn100636810.1021/nn1006368 ↗
29. 10.1039/C3DT52242C10.1039/C3DT52242C ↗
30. 10.1007/978-1-4613-4452-010.1007/978-1-4613-4452-0 ↗
31. Breternitz, J. A Contribution toward the Performance and Structural Understanding of Copper and Nickel Salts as Ammonia Stores; Doctoral dissertation, Glasgow University, 2016.
32. 10.1021/am400735310.1021/am4007353 ↗
33. 10.1016/j.apsusc.2022.15368110.1016/j.apsusc.2022.153681 ↗
34. 10.1016/j.matpr.2020.07.60010.1016/j.matpr.2020.07.600 ↗
35. 10.1016/j.pmatsci.2022.10099510.1016/j.pmatsci.2022.100995 ↗
36. 10.1039/D0NA00591F10.1039/D0NA00591F ↗
37. 10.1016/j.jallcom.2019.15201110.1016/j.jallcom.2019.152011 ↗
38. 10.1021/acs.iecr.1c0142410.1021/acs.iecr.1c01424 ↗
39. 10.1021/acs.iecr.8b0021810.1021/acs.iecr.8b00218 ↗
40. 10.1016/j.apsusc.2015.05.10110.1016/j.apsusc.2015.05.101 ↗
41. 10.1039/C6RA26948F10.1039/C6RA26948F ↗
42. 10.1016/j.inoche.2022.11007310.1016/j.inoche.2022.110073 ↗
43. 10.1016/j.matpr.2022.01.48510.1016/j.matpr.2022.01.485 ↗
44. 10.1016/j.apsusc.2016.01.03110.1016/j.apsusc.2016.01.031 ↗
45. 10.1016/j.jallcom.2019.03.00910.1016/j.jallcom.2019.03.009 ↗
46. 10.3390/molecules2519442810.3390/molecules25194428 ↗
47. 10.1186/s11671-016-1691-310.1186/s11671-016-1691-3 ↗
48. 10.1007/s10853-016-0719-510.1007/s10853-016-0719-5 ↗
49. 10.1002/chem.20210171610.1002/chem.202101716 ↗
50. 10.1103/PhysRevB.65.09430510.1103/PhysRevB.65.094305 ↗
51. 10.1016/j.jssc.2010.10.01910.1016/j.jssc.2010.10.019 ↗
52. 10.1016/j.ssc.2007.03.05210.1016/j.ssc.2007.03.052 ↗
53. 10.1021/acs.jpcc.1c0115210.1021/acs.jpcc.1c01152 ↗
54. 10.1038/nnano.2013.4610.1038/nnano.2013.46 ↗
55. 10.1098/rsta.2010.021310.1098/rsta.2010.0213 ↗
56. 10.1039/C7RA10809E10.1039/C7RA10809E ↗
57. Larkin P. J. · 2011
58. Moulder, J. F.; Stickle, W. F.; Sobol, P. F.; Kenneth, B. D. Handbook of X-Ray Photoelectron Spectroscopy, 1st ed. Perkin-Elmer Corporation: Eden Prairie, 1992.
59. 10.1038/s41598-020-63935-310.1038/s41598-020-63935-3 ↗
60. 10.1021/ja907098f10.1021/ja907098f ↗
61. 10.1021/acscatal.2c0152310.1021/acscatal.2c01523 ↗
62. 10.1351/pac19855704060310.1351/pac198557040603 ↗
63. 10.1016/j.cis.2009.08.00310.1016/j.cis.2009.08.003 ↗
64. 10.1088/2053-1591/2/9/09500110.1088/2053-1591/2/9/095001 ↗
65. 10.1016/j.jallcom.2023.16990210.1016/j.jallcom.2023.169902 ↗
66. 10.1016/j.eti.2022.10229610.1016/j.eti.2022.102296 ↗
67. 10.1205/09575829852969610.1205/095758298529696 ↗
68. 10.1016/j.jece.2018.08.05810.1016/j.jece.2018.08.058 ↗
69. 10.1016/j.chemosphere.2016.08.02010.1016/j.chemosphere.2016.08.020 ↗
70. 10.1088/1742-6596/1504/1/01201110.1088/1742-6596/1504/1/012011 ↗