journal article·2023-04-14

Sustainable CO2-Derived Nanoscale Carbon Support to a Platinum Catalyst for Oxygen Reduction Reaction

Erkin Najafli, Sander Ratso, Yurii P. Ivanov, Matija Gatalo, Luka Pavko, Can Rüstü Yörük, Peter Walke, Giorgio Divitini, Nejc Hodnik, Ivar Kruusenberg

ACS Applied Nano Materials· Volume 6· Issue 7
Publisher page

Abstract

While fuel cells have the potential to be among the key players in clean energy production, they are challenged by the sluggish electrochemical reactions that require an expensive and scarce platinum (Pt) catalyst. Commercial Pt-based catalysts used for facilitating the hydrogen oxidation reaction and oxygen reduction reaction (ORR) in fuel cells are commonly supported by petroleum-sourced carbon materials such as Vulcan XC-72. Thus, the replacement of such support materials with sustainable alternatives while enhancing the catalyst activity is highly desirable. For the first time, a Pt catalyst supported with a sustainably manufactured nanoscale CO 2 -derived carbon (Pt/CO 2 -C) was synthesized in this work. Physical and electrochemical characterization of the catalyst revealed the superior activity of Pt/CO 2 -C toward the ORR in comparison to commercial Pt/C with higher onset potential, mass activity, and specific activity values. Via further improvement, the prepared catalyst material is deemed to be a promising candidate for cheaper and more sustainable fuel cells.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Catalytic Processes in Materials Science · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Institute of Chemical Physics and Biophysics, Akadeemia Tee 23, Tallinn 12618, Estonia

Electron Spectroscopy and Nanoscopy, Italian Institute of Technology, Via Morego 30, Genova 16163, Italy

Department of Materials Chemistry, National Institute of Chemistry, Hajdrihova ulica 19, Ljubljana 1000, Slovenia

Department of Materials and Environmental Technology, Tallinn University of Technology, Ehitajate tee 5, Tallinn 19086, Estonia

Funding

Keemilise ja Bioloogilise F??sika Instituut · European Space Agency · Eesti Teadusagentuur

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