journal article·2022-05-27

Au-Doped CuOx Nanoparticles as Electrocatalysts for Oxygen Evolution Reaction

Jiayi Zhang, Biao Guo, Jing Liang, Lie Zou, Jun Lu, Jinxuan Liu

ACS Applied Nano Materials· Volume 5· Issue 5
Publisher page

Abstract

Here, we report an efficient Au-doped CuOx nanoparticle electrocatalyst (Au-CuOx-80) for oxygen evolution reaction (OER). The Au-CuOx-80 catalyst is prepared using a galvanic replacement reaction and exhibited excellent catalytic activity for OER in 1 M Na2CO3 solution (pH = 11.4) with an overpotential of 380 mV and a Tafel slope of 74 mV dec–1 at a current density of 10 mA·cm–2 and long-term stability up to 24 h. We attribute the superior electrocatalytic performance to the high electronegativity of Au doped inside the Cu2O cubes.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Electrochemical Analysis and Applications

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Affiliations

State Key Laboratory of Fine Chemicals, Dalian University of Technology, 116024 Dalian, P.R. China

Funding

State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University · Central University Basic Research Fund of China · National Natural Science Foundation of China

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