journal article·2022-10-28

Hydroxy-Rich Pillar[5]arene-Based Nanoporous Aromatic Frameworks (PAFs) for Efficient CO2 Uptake under Ambient Conditions

Ming-Ming Zhai, Cheng-Yu Wu, Yahu A. Liu, Wei-Bo Hu, Hui Yang, Ke Wen

ACS Applied Nano Materials· Volume 5· Issue 10
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Abstract

In this letter, we report our fabrication of a three-dimensional hydroxy-rich pillar[5]arene-extended nanoporous aromatic framework PAF-P5-OH for CO2 uptake. CO2 adsorption study demonstrated that PAF-P5-OH exhibited excellent CO2 uptake capacity (88 cm3 g–1 at 273 K and 76 cm3 g–1 at 298 K) under atmospheric pressure, which could be attributed to the favored dipole interactions between the adsorbed CO2 molecules and the hydroxy groups in PAF-P5-OH.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Luminescence and Fluorescent Materials

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Affiliations

School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China

Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

Medicinal Chemistry, ChemBridge Research Laboratories, San Diego, California 92127, United States

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China

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