journal article·2023-03-10

Bismuth Nanoparticles Supported on Biobased Chitosan as Sustainable Catalysts for the Selective Hydrogenation of Nitroarenes

Mustapha El kadiri, Taha El Assimi, Pascal Thébault, Abdellatif El Meziane, Sébastien Royer, Abdelkrim El Kadib, Géraldine Gouhier, Mohammed Lahcini

ACS Applied Nano Materials· Volume 6· Issue 5
Publisher page

Abstract

The use of chitosan as a support in the field of catalysis has gained tremendous interest because of its abundance and sustainability. We herein disclose a straightforward strategy to trap and stabilize bismuth nanoparticles (BiNPs) on chitosan biopolymer Bi@CS and their use for catalytic applications. Bi@CS was configured as micrometer-thick films, porous beads, and native powders analyzed and next used for the controlled and selective reduction of nitroaromatic compounds to their corresponding anilines and azoarenes, respectively, by varying the concentration medium in reducing NaBH 4 . A regioselective mechanism has been suggested. Powder nanocomposites CSp-BiNPs exhibited high catalytic capacity, and 10 corresponding anilines and 15 azoarenes were obtained with very high yields. The reductions were achieved under mild and sustainable reaction conditions (water solvent and room temperature) with easy processing and 12 recovery cycles. Shaped catalysts were easily recovered by simple filtration. This catalyst, derived from nontoxic and affordable bismuth metal supported on chitosan ocean waste, presents significant improvements in the realm of sustainable chemistry and could open a new channel of possibilities for green catalysis.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Nanomaterials for catalytic reactions · Ammonia Synthesis and Nitrogen Reduction · Asymmetric Hydrogenation and Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

IMED-Lab, Faculty of Sciences and Techniques, Cadi Ayyad University, Avenue Abdelkrim Elkhattabi, B.P. 549, 40000 Marrakech, Morocco

Normandie Université, PBS UMR 6270, UNIROUEN, INSA Rouen, CNRS, 76821 Mont-Saint-Aignan, France

Laboratory of Agrobiotechnoloy and Bioengineering, Department of Biology, Cadi Ayyad University, Avenue Abdelkrim Elkhattabi, B.P. 549, 40000 Marrakech, Morocco

Unité de Catalyse et Chimie du Solide, Université Lille, CNRS, Centrale Lille, Université Artois, UMR 8181, 59000 Lille, France

Department Euromed Research Center, Engineering Division, Euro-Med University of Fes, Route de Meknes, Rond-point de Bensouda, 30070 Fès, Morocco

Normandie Université, COBRA, UMR 6014, FR 3038, INSA Rouen, CNRS, IRCOF, 1 rue Tesnière, 76821 Mont-Saint-Aignan, France

Mohammed VI Polytechnic University, 43150 Ben Guerir, Morocco

Funding

Centre National pour la Recherche Scientifique et Technique · Minist?re de l'Enseignement sup?rieur, de la Recherche et de l'Innovation · Agence Nationale de la Recherche · Campus France · Universit? de Rouen · European Regional Development Fund · R?gion Hauts-de-France · Centre National de la Recherche Scientifique · Labex SynOrg · M?tropole Europ?enne de Lille · Carnot Institute I2C, Normandy University · National Institute of Applied Sciences of Rouen, University of Rouen

References (63)

Show source-provided references
1. 10.1002/cctc.20120044310.1002/cctc.201200443 ↗
2. 10.1016/j.catcom.2007.07.03210.1016/j.catcom.2007.07.032 ↗
3. 10.1039/c0cs00183j10.1039/c0cs00183j ↗
4. 10.1002/9780470871737.ch910.1002/9780470871737.ch9 ↗
5. 10.1016/j.watres.2022.11879710.1016/j.watres.2022.118797 ↗
6. 10.1016/j.chemosphere.2021.13347210.1016/j.chemosphere.2021.133472 ↗
7. 10.1039/C5RA10076C10.1039/C5RA10076C ↗
8. 10.1021/acsami.9b1758210.1021/acsami.9b17582 ↗
9. 10.1039/D1NJ03297F10.1039/D1NJ03297F ↗
10. 10.1039/C1CY00358E10.1039/C1CY00358E ↗
11. 10.1039/b705619b10.1039/b705619b ↗
12. 10.1002/anie.20140454310.1002/anie.201404543 ↗
13. 10.1016/j.jcat.2013.12.01410.1016/j.jcat.2013.12.014 ↗
14. 10.1021/acscatal.5b0184610.1021/acscatal.5b01846 ↗
15. 10.1021/acsami.9b2180210.1021/acsami.9b21802 ↗
16. 10.1016/j.cej.2021.12885610.1016/j.cej.2021.128856 ↗
17. 10.1016/j.apcatb.2022.12148710.1016/j.apcatb.2022.121487 ↗
18. 10.1039/c3cy00533j10.1039/c3cy00533j ↗
19. 10.1039/c3gc41360h10.1039/c3gc41360h ↗
20. 10.1021/acssuschemeng.7b0433310.1021/acssuschemeng.7b04333 ↗
21. 10.1021/acs.biomac.0c0020110.1021/acs.biomac.0c00201 ↗
22. 10.1021/acsomega.9b0173610.1021/acsomega.9b01736 ↗
23. 10.2174/15701930978937158710.2174/157019309789371587 ↗
24. 10.1002/ejoc.20160093710.1002/ejoc.201600937 ↗
25. 10.3390/molecules1604288410.3390/molecules16042884 ↗
26. 10.1002/ejoc.20030075410.1002/ejoc.200300754 ↗
27. 10.1021/acscatal.1c0489710.1021/acscatal.1c04897 ↗
28. 10.1007/s13204-022-02547-x10.1007/s13204-022-02547-x ↗
29. 10.1002/macp.20100051710.1002/macp.201000517 ↗
30. 10.1021/acssuschemeng.5b0003310.1021/acssuschemeng.5b00033 ↗
31. 10.1007/s10876-021-02156-810.1007/s10876-021-02156-8 ↗
32. 10.1002/ange.20210283210.1002/ange.202102832 ↗
33. 10.1016/j.jmst.2013.04.00410.1016/j.jmst.2013.04.004 ↗
34. 10.1016/j.catcom.2014.08.02210.1016/j.catcom.2014.08.022 ↗
35. 10.1016/j.apsusc.2013.02.11010.1016/j.apsusc.2013.02.110 ↗
36. 10.1002/cssc.20080022710.1002/cssc.200800227 ↗
37. 10.1021/ie501142a10.1021/ie501142a ↗
38. 10.1016/j.apcata.2016.09.00510.1016/j.apcata.2016.09.005 ↗
39. 10.1002/cssc.20140271810.1002/cssc.201402718 ↗
40. 10.1016/j.ccr.2019.02.01810.1016/j.ccr.2019.02.018 ↗
41. 10.1016/j.progpolymsci.2004.12.00110.1016/j.progpolymsci.2004.12.001 ↗
42. 10.1002/tcr.20190008910.1002/tcr.201900089 ↗
43. 10.1039/C4GC02175D10.1039/C4GC02175D ↗
44. 10.1002/cctc.20150056510.1002/cctc.201500565 ↗
45. 10.1002/cctc.20150056510.1002/cctc.201500565 ↗
46. 10.1016/j.foodhyd.2010.08.00810.1016/j.foodhyd.2010.08.008 ↗
47. 10.1016/j.matlet.2003.07.01310.1016/j.matlet.2003.07.013 ↗
48. Balau L. · Cent. Eur. J. Chem. · 2004 · 2 · 638
49. 10.1016/j.carbpol.2019.11563410.1016/j.carbpol.2019.115634 ↗
50. 10.1016/j.ijbiomac.2022.09.03410.1016/j.ijbiomac.2022.09.034 ↗
51. 10.1088/1361-6528/ab808710.1088/1361-6528/ab8087 ↗
52. 10.1039/b915299g10.1039/b915299g ↗
53. 10.1038/nprot.2006.44110.1038/nprot.2006.441 ↗
54. 10.1039/C5CY00285K10.1039/C5CY00285K ↗
55. 10.1002/aoc.645210.1002/aoc.6452 ↗
56. 10.1002/asia.20110031110.1002/asia.201100311 ↗
57. 10.1039/b924228g10.1039/b924228g ↗
58. 10.1016/j.apmt.2020.10067810.1016/j.apmt.2020.100678 ↗
59. 10.1021/acssuschemeng.5b0145310.1021/acssuschemeng.5b01453 ↗
60. 10.1021/ol052120n10.1021/ol052120n ↗
61. 10.1016/j.tet.2014.01.04810.1016/j.tet.2014.01.048 ↗
62. 10.1016/j.cej.2013.01.07410.1016/j.cej.2013.01.074 ↗
63. 10.1039/C5RA17994G10.1039/C5RA17994G ↗