journal article·2022-03-25

Carbon Nanotube-Threaded Mesocrystalline CeO2 for Enhanced Photocatalytic NO Removal

Shuning Xiao, Ningyu Zhang, Ying Tao, Xueling Song, Guisheng Li, Hexing Li, Dieqing Zhang

ACS Applied Nano Materials· Volume 5· Issue 3
Publisher page

Abstract

The synthesis of photocatalysts with rapid photogenerated electron transfer, strong reactant adsorption, and activation is urgent to promote photocatalytic NO oxidation. Herein, we construct a series of carbon nanotube (CNT)-threaded CeO2 mesocrystalline photocatalysts applying the microwave thermal method. The noncontinuous CNT-threaded structure provides two interfacial charge transport pathways for the efficient separation of photogenerated carriers. The introduction of CNTs induces mesocrystalline CeO2 with surface Ce3+ and oxygen vacancies, which is in favor of adsorption and activation for reactants, further facilitating a deep oxidation pathway for NO removal. The optimal photocatalyst exhibits a remarkable conversion ratio for NO oxidation and NO3– selectivity in a recyclable way.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Catalytic Processes in Materials Science · Ammonia Synthesis and Nitrogen Reduction

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, China

Key Laboratory of Resource Chemistry of Ministry of Education, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China

Funding

National Natural Science Foundation of China · Shanghai Scientific and Technological Innovation Project

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