journal article·2022-04-22

Silicon-Enriched Nickel Nanoparticles for Hydrogenation of N-Heterocycles in Aqueous Media

Shuxin Mao, Pavel Ryabchuk, Sarim Dastgir, Muhammad Anwar, Kathrin Junge, Matthias Beller

ACS Applied Nano Materials· Volume 5· Issue 4
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Abstract

Herein, we report a heterogeneous intermetallic nickel silicide catalyst prepared by the impregnation of nickel acetate/1,10-phenanthroline on fumed silica and subsequent pyrolysis. The optimal catalyst exhibits good activity and selectivity for the hydrogenation of N-heterocycles including pyridines and quinolines under comparably mild conditions using water as the solvent. To our knowledge, it is the first reported efficient nickel-based heterogeneous catalyst for catalytic pyridine hydrogenation.
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Research context

OpenAlex topics: Nanomaterials for catalytic reactions · Asymmetric Hydrogenation and Catalysis · Catalysis for Biomass Conversion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Leibniz-Institut für Katalyse eV, Albert-Einstein-Straße 29a, 18059 Rostock, Germany

Qatar Environment and Energy Research Institute (QEERI), Hamad Bin Khalifa University, Qatar Foundation, Education City, 34110 Doha, Qatar

Funding

Qatar National Research Fund · Ministerium f?r Bildung, Wissenschaft und Kultur Mecklenburg-Vorpommern · H2020 European Research Council

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