journal article·2017-10-01Open access

Bronze-mean hexagonal quasicrystal

Tomonari Dotera, Shinichi Bekku, Primož Ziherl

Nature Materials· Volume 16· Issue 10

Abstract

The most striking feature of conventional quasicrystals is their non-traditional symmetry characterized by icosahedral, dodecagonal, decagonal or octagonal axes. The symmetry and the aperiodicity of these materials stem from an irrational ratio of two or more length scales controlling their structure, the best-known examples being the Penrose and the Ammann-Beenker tiling as two-dimensional models related to the golden and the silver mean, respectively. Surprisingly, no other metallic-mean tilings have been discovered so far. Here we propose a self-similar bronze-mean hexagonal pattern, which may be viewed as a projection of a higher-dimensional periodic lattice with a Koch-like snowflake projection window. We use numerical simulations to demonstrate that a disordered variant of this quasicrystal can be materialized in soft polymeric colloidal particles with a core-shell architecture. Moreover, by varying the geometry of the pattern we generate a continuous sequence of structures, which provide an alternative interpretation of quasicrystalline approximants observed in several metal-silicon alloys.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Quasicrystal Structures and Properties · Mineralogy and Gemology Studies · Nanocluster Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Levine, D. & Steinhardt, P. J. Quasicrystals: a new class of ordered structures. Phys. Rev. Lett. 53, 2477–2480 (1984).10.1103/PhysRevLett.53.2477 ↗
2. Shechtman, D., Blech, I., Gratias, D. & Cahn, J. W. Metallic phase with long-range orientational order and no translational symmetry. Phys. Rev. Lett. 53, 1951–1953 (1984).10.1103/PhysRevLett.53.1951 ↗
3. Ishimasa, T., Nissen, H.-U. & Fukao, Y. New ordered state between crystalline and amorphous in Ni-Cr particles. Phys. Rev. Lett. 55, 511–513 (1985).10.1103/PhysRevLett.55.511 ↗
4. Tsai, A. P., Inoue, A. & Masumoto, T. A stable quasicrystal in Al–Cu–Fe system. Jpn. J. Appl. Phys. 26, L1505–L1507 (1987).10.1143/JJAP.26.L1505 ↗
5. Janssen, T., Chapuis, G. & de Boissieu, M. Aperiodic Crystals: From Modulated Phases to Quasicrystals (Oxford Univ. Press, 2007).10.1093/acprof:oso/9780198567776.001.0001 ↗
6. Steurer, W. & Deloudi, S. Crystallography of Quasicrystals: Concepts, Methods and Structures (Springer, 2009).
7. Penrose, R. The role of aesthetics in pure and applied mathematical research. Bull. Inst. Math. Appl. 10, 266–271 (1974).
8. Mackay, A. Crystallography and the Penrose pattern. Physica A 114, 609–613 (1982).10.1016/0378-4371(82)90359-4 ↗
9. Grünbaum, B. & Shephard, G. C. Tilings and Patterns (Freeman, 1987).
10. Beenker, F. P. M. Algebraic theory of non-periodic tilings of the plane by two simple building blocks: a square and a rhombus. TH-Report Vol. 82-WSK04 1–64 (Eindhoven University of Technology, 1982).
11. Oxborrow, M. & Henley, C. L. Random square-triangle tilings: a model for twelvefold-symmetric quasicrystals. Phys. Rev. B 48, 6966–6998 (1993).10.1103/PhysRevB.48.6966 ↗
12. Zeng, X. et al. Supramolecular dendritic liquid quasicrystals. Nature 428, 157–160 (2004).10.1038/nature02368 ↗
13. Chanpuriya, S. et al. Cornucopia of nanoscale ordered phases in sphere-forming tetrablock terpolymers. ACS Nano 10, 4961–4972 (2016).10.1021/acsnano.6b00495 ↗
14. Fischer, S. et al. Colloidal quasicrystals with 12-fold and 18-fold diffraction symmetry. Proc. Natl Acad. Sci. USA 108, 1810–1814 (2011).10.1073/pnas.1008695108 ↗
15. Iacovella, C. R., Keys, A. S. & Glotzer, S. C. Self-assembly of soft-matter quasicrystals and their approximants. Proc. Natl. Acad. Sci. USA 108, 20935–20940 (2011).10.1073/pnas.1019763108 ↗
16. Engel, M. & Trebin, H.-R. Self-assembly of monatomic complex crystals and quasicrystals with a double-well interaction potential. Phys. Rev. Lett. 98, 225505 (2007).10.1103/PhysRevLett.98.225505 ↗
17. Dotera, T., Oshiro, T. & Ziherl, P. Mosaic two-lengthscale quasicrystals. Nature 506, 208–211 (2014).10.1038/nature12938 ↗
18. Ishimasa, T. Dodecagonal quasicrystals still in progress. Isr. J. Chem. 51, 1216–1225 (2011).10.1002/ijch.201100134 ↗
19. Gumbs, G. & Ali, M. K. Dynamical maps, Cantor spectra, and localization for Fibonacci and related quasiperiodic lattices. Phys. Rev. Lett. 60, 1081–1084 (1988).10.1103/PhysRevLett.60.1081 ↗
20. Suzuki, T.-K. & Dotera, T. Dynamical systems for quasiperiodic chains and new self-similar polynomials. J. Phys. A: Math. Gen. 26, 6101–6113 (1993).10.1088/0305-4470/26/22/013 ↗
21. Buitrago, A. R. Polygons, diagonals, and the bronze mean. Nexus Netw. J. 9, 321–326 (2008).10.1007/s00004-007-0046-x ↗
22. Stampfli, P. Dodecagonal quasiperiodic lattice in two dimensions. Helv. Phys. Acta 59, 1260–1263 (1986).
23. Niizeki, K. A step toward an MLD classification of selfsimilar quasilattices. Prog. Theor. Phys. 128, 629–691 (2012).10.1143/PTP.128.629 ↗
24. Socolar, J. E. S., Lubensky, T. C. & Steinhardt, P. J. Phonons, phasons, and dislocations in quasicrystals. Phys. Rev. B 34, 3345–3360 (1986).10.1103/PhysRevB.34.3345 ↗
25. Dotera, T. & Steinhardt, P. J. Ising-like transition and phason unlocking in icosahedral quasicrystals. Phys. Rev. Lett. 72, 1670–1673 (1994).10.1103/PhysRevLett.72.1670 ↗
26. Iga, H., Mihalkovič, M. & Ishimasa, T. Approximant of dodecagonal quasicrystal formed in MnSiV alloy. Philos. Mag. 91, 2624–2633 (2011).10.1080/14786435.2010.508448 ↗
27. Ishimasa, T., Iwami, S., Sakaguchi, N., Oota, R. & Mihalkovič, M. Phason space analysis and structure modelling of 100 Å-scale dodecagonal quasicrystal in Mn-based alloy. Philos. Mag. 95, 3745–3767 (2015).10.1080/14786435.2015.1095365 ↗
28. Förster, S. et al. Observation and structure determination of an oxide quasicrystal approximant. Phys. Rev. Lett. 117, 095501 (2016).10.1103/PhysRevLett.117.095501 ↗
29. Ye, X. et al. Quasicrystalline nanocrystal superlattice with partial matching rules. Nat. Mater. 16, 214–219 (2017).10.1038/nmat4759 ↗
30. Sasisekharan, V., Baranidharan, S., Balagurusamy, V. S. K., Srinivasan, A. & Gopal, E. S. R. Non-periodic tilings in 2-dimensions with 4, 6, 8, 10 and 12-fold symmetries. Pramana J. Phys. 33, 405–420 (1989).10.1007/BF02845832 ↗