journal article·2004-06-01

Probing the dynamics of nanoparticle growth in a flame using synchrotron radiation

Gregory Beaucage, Hendrik K. Kammler, Roger Mueller, Reto Strobel, Nikhil Agashe, Sotiris E. Pratsinis, Theyencheri Narayanan

Nature Materials· Volume 3· Issue 6
Publisher page

Abstract

Flame synthesis is one of the most versatile and promising technologies for large-scale production of nanoscale materials. Pyrolysis has recently been shown to be a useful route for the production of single-walled nanotubes, quantum dots and a wide variety of nanostructured ceramic oxides for catalysis and electrochemical applications. An understanding of the mechanisms of nanostructural growth in flames has been hampered by a lack of direct observations of particle growth, owing to high temperatures (2,000 K), rapid kinetics (submillisecond scale), dilute growth conditions (10(-6) volume fraction) and optical emission of synthetic flames. Here we report the first successful in situ study of nanoparticle growth in a flame using synchrotron X-ray scattering. The results indicate that simple growth models, first derived for colloidal synthesis, can be used to facilitate our understanding of flame synthesis. Further, the results indicate the feasibility of studies of nanometre-scale aerosols of toxicological and environmental concern.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Coagulation and Flocculation Studies · nanoparticles nucleation surface interactions · Thermochemical Biomass Conversion Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Friedlander, S.K. Smoke, Dust, and Haze: Fundamentals of Aerosol Dynamics 2nd edn (Oxford Univ. Press, New York, 2000).
2. Ulrich, G.D. Flame synthesis of fine particles. Chem. Eng. News 62, 22–29 (1984).10.1021/cen-v062n032.p022 ↗
3. Pratsinis, S.E. Flame aerosol synthesis of ceramic powders. Prog. Energy Combust. Sci. 24, 197–219 (1998).10.1016/S0360-1285(97)00028-2 ↗
4. Van der Wal, R.L., Berger, G.M. & Hall, L.J. Single-walled carbon nanotube synthesis via a multi-stage flame configuration. J. Phys. Chem. B 106, 3564–3567 (2002).10.1021/jp012844q ↗
5. Madler, L., Stark, W.J. & Pratsinis, S.E. Rapid synthesis of stable ZnO quantum dots. J. Appl. Phys. 92, 6537–6540 (2002).10.1063/1.1518132 ↗
6. Stark, W.J., Pratsinis, S.E. & Baiker, A. Flame made titania/silica epoxidation catalysts. J. Catal. 203, 516–524 (2001).10.1006/jcat.2001.3365 ↗
7. Madler, L., Stark, W.J. & Pratsinis, S.E. Flame-made ceria nanoparticles. J. Mater. Res. 17, 1356–1362 (2002).10.1557/JMR.2002.0202 ↗
8. Anala, S. et al. In situ NMR spectroscopy of combustion. J. Am. Chem. Soc. 125, 13298–13302 (2003).10.1021/ja035838b ↗
9. Tsantilis, S., Briesen, H. & Pratsinis, S.E. Sintering time for silica particle growth. Aerosol Sci. Technol. 34, 237–246 (2001).10.1080/02786820119149 ↗
10. Arabi-Katbi, O.I., Pratsinis, S.E., Morrison, P.W. Jr & Megaridis, C.M. Monitoring the flame synthesis of TiO2 particles by in-situ FTIR spectroscopy and thermophoretic sampling. Combust. Flame 124, 560–572 (2001).10.1016/S0010-2180(00)00227-3 ↗
11. Morrison, P.W., Raghavan, R., Timpone, A.J., Artelt, C.P. & Pratsinis, S.E. In situ Fourier transform infrared characterization of the effect of electrical fields on the flame synthesis of TiO2 particles. Chem. Mater. 9, 2702–2708 (1997).10.1021/cm960508u ↗
12. Dobbins, R.A. & Megaridis, C.M. Morphology of flame-generated soot as determined by thermophoretic sampling. Langmuir 3, 254–259 (1987).10.1021/la00074a019 ↗
13. Köylü, Ü.Ö., McEnally, C.S., Rosner, D.E. & Pfefferle, L.D. Simultaneous measurements of soot volume fraction and particle size / microstructure in flames using a thermophoretic sampling technique. Combust. Flame 110, 494–507 (1997).10.1016/S0010-2180(97)00089-8 ↗
14. Hurd, A.J. & Flower, W.L. In situ growth and structure of fractal silica aggregates in a flame. J. Colloid Interface Sci. 122, 178–192 (1988).10.1016/0021-9797(88)90301-3 ↗
15. Xing, Y., Köylü, Ü.Ö. & Rosner, D.E. In situ light-scattering measurements of morphologically evolving flame-synthesized oxide nanoaggregates. Appl. Opt. 38, 2686–2697 (1999).10.1364/AO.38.002686 ↗
16. King, G.B., Sorensen, C.M., Lester, T.W. & Merklin, J.F. Direct measurements of aerosol diffusion constants in the intermediate Knudsen regime. Phys. Rev. Lett. 50, 1125–1128 (1983).10.1103/PhysRevLett.50.1125 ↗
17. Chowdhury, D.P., Sorensen, C.M., Taylor, T.W., Merklin, J.F. & Lester, T.W. Application of photon correlation spectroscopy to flowing brownian motion systems. Appl. Opt. 23, 4149–4154 (1984).10.1364/AO.23.004149 ↗
18. Taylor, T.W. & Sorensen, C.M. Gaussian beam effects on the photon correlation spectrum from a flowing brownian motion system. Appl. Opt. 25, 2421–2426 (1986).10.1364/AO.25.002421 ↗
19. Sorensen, C.M., Hageman, W.B., Rush, T.J., Huang, H. & Oh, C. Aerogelation in a flame soot aerosol. Phys. Rev. Lett. 80, 1782–1785 (1998).10.1103/PhysRevLett.80.1782 ↗
20. Sorensen, C.M., Hagemann, W.B. Two-dimensional soot. Langmuir 17, 5431–5434 (2001).10.1021/la0104065 ↗
21. Zachariah, M.R. & Semerjian, H.G. Simulation of ceramic particle formation: Comparison with in-situ measurements. Am. Inst. Chem. Eng. J. 35, 2003–2012 (1989).10.1002/aic.690351211 ↗
22. Sugimoto, T. Monodisperse Particles (Elsevier, New York, 2001).
23. Pyne, S. Small particles add up to big disease risk. Science 295, 1994 (2002).10.1126/science.295.5562.1994a ↗
24. Chameides, W.L. & Bergin, M. Soot takes center stage. Science 297, 2214–2215 (2002).10.1126/science.1076866 ↗
25. Guinier, A. & Fournet, G. Small Angle Scattering of X-rays (John Wiley & Sons, New York, 1955).
26. Glatter, O. & Kratky, O. Small-angle X-ray Scattering (Academic, London, 1982).
27. Roe, R.-J. Methods of X-Ray and Neutron Scattering in Polymer Science (Oxford Univ. Press, New York, 2000).
28. Beaucage, G., Kammler, H.K. & Pratsinis, S.E. Estimate of particle-size polydispersity from small-angle scattering. J. Appl. Crystallogr. (in the press).
29. Beaucage, G. Approximations leading to a unified exponential/power-law approach to small-angle scattering. J. Appl. Crystallogr. 28, 717–728 (1995).10.1107/S0021889895005292 ↗
30. Beaucage, G. Small-angle scattering from polymeric mass fractals of arbitrary mass-fractal dimension. J. Appl. Crystallogr. 29, 134–146 (1996).10.1107/S0021889895011605 ↗
31. Hyeon-Lee, J., Beaucage, G., Pratsinis, S.E. & Vemury, S. Fractal analysis of flame-synthesized nanostructured silica and titania powders using small-angle X-ray scattering. Langmuir 14, 5751–5756 (1998).10.1021/la980308s ↗
32. Kammler, H.K., Beaucage, G., Mueller, R. & Pratsinis, S.E. Structure of flame-made silica nanoparticles by ultra small-angle x-ray scattering. Langmuir 20, 1915–1921 (2004).10.1021/la030155v ↗
33. Pontoni, D., Narayanan, T. & Rennie, A.R. Time-resolved SAXS study of nucleation and growth of silica colloids. Langmuir 18, 56–59 (2002).10.1021/la015503c ↗