journal article·2018-10

A multicaloric cooling cycle that exploits thermal hysteresis

Tino Gottschall, Adrià Gràcia-Condal, Maximilian Fries, Andreas Taubel, Lukas Pfeuffer, Lluís Mañosa, Antoni Planes, Konstantin P. Skokov, Oliver Gutfleisch

Nature Materials· Volume 17· Issue 10
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Abstract

The giant magnetocaloric effect, in which large thermal changes are induced in a material on the application of a magnetic field, can be used for refrigeration applications, such as the cooling of systems from a small to a relatively large scale. However, commercial uptake is limited. We propose an approach to magnetic cooling that rejects the conventional idea that the hysteresis inherent in magnetostructural phase-change materials must be minimized to maximize the reversible magnetocaloric effect. Instead, we introduce a second stimulus, uniaxial stress, so that we can exploit the hysteresis. This allows us to lock-in the ferromagnetic phase as the magnetizing field is removed, which drastically removes the volume of the magnetic field source and so reduces the amount of expensive Nd-Fe-B permanent magnets needed for a magnetic refrigerator. In addition, the mass ratio between the magnetocaloric material and the permanent magnet can be increased, which allows scaling of the cooling power of a device simply by increasing the refrigerant body. The technical feasibility of this hysteresis-positive approach is demonstrated using Ni-Mn-In Heusler alloys. Our study could lead to an enhanced usage of the giant magnetocaloric effect in commercial applications.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Shape Memory Alloy Transformations · Magnetic and transport properties of perovskites and related materials · Heusler alloys: electronic and magnetic properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Belman-Flores, J. M., Barroso-Maldonado, J. M., Rodríguez-Muñoz, A. P. & Camacho-Vázquez, G. Enhancements in domestic refrigeration, approaching a sustainable refrigerator— review. Renew. Sust. Energ. Rev. 51, 955–968 (2015).10.1016/j.rser.2015.07.003 ↗
2. Gutfleisch, O. et al. Magnetic materials and devices for the 21st century: stronger, lighter, and more energy efficient. Adv. Mater. 23, 821–842 (2011).10.1002/adma.201002180 ↗
3. Sandeman, K. G. Magnetocaloric materials: the search for new systems. Scripta Mater. 67, 566–571 (2012).10.1016/j.scriptamat.2012.02.045 ↗
4. Moya, X., Kar-Narayan, S. & Mathur, N. D. Caloric materials near ferroic phase transitions. Nat. Mater. 13, 439–450 (2014).10.1038/nmat3951 ↗
5. Takeuchi, I. & Sandeman, K. Solid-state cooling with caloric materials. Phys. Today 68, 48–54 (December, 2015).10.1063/PT.3.3022 ↗
6. Krenke, T. et al. Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys. Nat. Mater. 4, 450–454 (2005).10.1038/nmat1395 ↗
7. Liu, J., Gottschall, T., Skokov, K. P., Moore, J. D. & Gutfleisch, O. Giant magnetocaloric effect driven by structural transitions. Nat. Mater. 11, 620–626 (2012).10.1038/nmat3334 ↗
8. Mañosa, L. et al. Giant solid-state barocaloric effect in the Ni–Mn–In magnetic shape-memory alloy. Nat. Mater. 9, 478–481 (2010).10.1038/nmat2731 ↗
9. Matsunami, D., Fujita, A., Takenaka, K. & Kano, M. Giant barocaloric effect enhanced by the frustration of the antiferromagnetic phase in Mn3GaN. Nat. Mater. 14, 73–78 (2015).10.1038/nmat4117 ↗
10. Bonnot, E., Romero, R., Mañosa, L., Vives, E. & Planes, A. Elastocaloric effect associated with the martensitic transition in shape-memory alloys. Phys. Rev. Lett. 100, 125901 (2008).10.1103/PhysRevLett.100.125901 ↗
11. Tušek, J. et al. The elastocaloric effect: a way to cool efficiently. Adv. Energy Mater. 5, 1500361 (2015).10.1002/aenm.201500361 ↗
12. Smith, A. et al. Materials challenges for high performance magnetocaloric refrigeration devices. Adv. Eng. Mater. 2, 1288–1318 (2012).10.1002/aenm.201200167 ↗
13. Scarpa, F., Tagliafico, G. & Tagliafico, L. A. A classification methodology applied to existing room temperature magnetic refrigerators up to the year 2014. Renew. Sust. Energ. Rev. 50, 497–503 (2015).10.1016/j.rser.2015.05.029 ↗
14. Kitanovski, A., Plaznik, U., Tomc, U. & Poredoš, A. Present and future caloric refrigeration and heat-pump technologies. Int. J. Refrig. 57, 288–298 (2015).10.1016/j.ijrefrig.2015.06.008 ↗
15. Yu, B., Liu, M., Egolf, P. W. & Kitanovski, A. A review of magnetic refrigerator and heat pump prototypes built before the year 2010. Int. J. Refrig. 33, 1029–1060 (2010).10.1016/j.ijrefrig.2010.04.002 ↗
16. Gómez, J. R., Garcia, R. F., Catoira, A. D. M. & Gómez, M. R. Magnetocaloric effect: a review of the thermodynamic cycles in magnetic refrigeration. Renew. Sust. Energ. Rev. 17, 74–82 (2013).10.1016/j.rser.2012.09.027 ↗
17. Engelbrecht, K. et al. Experimental results for a novel rotary active magnetic regenerator. Int. J. Refrig. 35, 1498–1505 (2012).10.1016/j.ijrefrig.2012.05.003 ↗
18. Zimm, C. et al. Design and performance of a permanent-magnet rotary refrigerator. Int. J. Refrig. 29, 1302–1306 (2006).10.1016/j.ijrefrig.2006.07.014 ↗
19. Bjørk, R., Smith, A., Bahl, C. & Pryds, N. Determining the minimum mass and cost of a magnetic refrigerator. Int. J. Refrig. 34, 1805–1816 (2011).10.1016/j.ijrefrig.2011.05.021 ↗
20. Monfared, B., Furberg, R. & Palm, B. Magnetic vs. vapor-compression household refrigerators: A preliminary comparative life cycle assessment. Int. J. Refrig. 42, 69–76 (2014).10.1016/j.ijrefrig.2014.02.013 ↗
21. Gottschall, T., Skokov, K. P. & Gutfleisch, O. Kühlvorrichtung und ein Verfahren zum Kühlen. German patent 10 2016 110, 385.3 (2016).
22. Gottschall, T. et al. A matter of size and stress: understanding the first-order transition in materials for solid-state refrigeration. Adv. Funct. Mater. 27, 1606735 (2017).10.1002/adfm.201606735 ↗
23. Mañosa, L. et al. Inverse barocaloric effect in the giant magnetocaloric La–Fe–Si–Co compound. Nat. Commun. 2, 595 (2011).10.1038/ncomms1606 ↗
24. Gutfleisch, O. et al. Mastering hysteresis in magnetocaloric materials. Phil. Trans. R. Soc. A 374, 20150308 (2016).10.1098/rsta.2015.0308 ↗
25. Song, Y., Chen, X., Dabade, V., Shield, T. W. & James, R. D. Enhanced reversibility and unusual microstructure of a phase-transforming material. Nature 502, 85–88 (2013).10.1038/nature12532 ↗
26. Gottschall, T., Skokov, K. P., Benke, D., Gruner, M. E. & Gutfleisch, O. Contradictory role of the magnetic contribution in inverse magnetocaloric Heusler materials. Phys. Rev. B 93, 184431 (2016).10.1103/PhysRevB.93.184431 ↗
27. Pérez-Reche, F. J., Vives, E., Mañosa, L. & Planes, A. Athermal character of structural phase transitions. Phys. Rev. Lett. 87, 195701 (2001).10.1103/PhysRevLett.87.195701 ↗
28. Karaca, H. E. et al. Magnetic field-induced phase transformation in NiMnCoIn magnetic shape-memory alloys—a new actuation mechanism with large work output. Adv. Funct. Mater. 19, 983–998 (2009).10.1002/adfm.200801322 ↗
29. Gottschall, T., Skokov, K. P., Frincu, B. & Gutfleisch, O. Large reversible magnetocaloric effect in Ni–Mn–In–Co. Appl. Phys. Lett. 106, 021901 (2015).10.1063/1.4905371 ↗
30. Gottschall, T. et al. Reversibility of minor hysteresis loops in magnetocaloric Heusler alloys. Appl. Phys. Lett. 110, 223904 (2017).10.1063/1.4984797 ↗
31. Chirkova, A. et al. Giant adiabatic temperature change in FeRh alloys evidenced by direct measurements under cyclic conditions. Acta Mater. 106, 15–21 (2016).10.1016/j.actamat.2015.11.054 ↗