journal article·2003-10-01

Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties

Akihisa Inoue, Baolong Shen, Hisato Koshiba, Hidemi Kato, Alain R. Yavari

Nature Materials· Volume 2· Issue 10
Publisher page

Abstract

Bulk metallic glasses--formed by supercooling the liquid state of certain metallic alloys--have potentially superior mechanical properties to crystalline materials. Here, we report a Co(43)Fe(20)Ta(5.5)B(31.5) glassy alloy exhibiting ultrahigh fracture strength of 5,185 MPa, high Young's modulus of 268 GPa, high specific strength of 6.0 x 10(5) Nm kg(-1) and high specific Young's modulus of 31 x 10(6) Nm kg(-1). The strength, specific strength and specific Young's modulus are higher than previous values reported for any bulk crystalline or glassy alloys. Excellent formability is manifested by large tensile elongation of 1,400% and large reduction ratio in thickness above 90% in the supercooled liquid region. The ultrahigh-strength alloy also exhibited soft magnetic properties with extremely high permeability of 550,000. This alloy is promising as a new ultrahigh-strength material with good deformability and soft magnetic properties.
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Research context

OpenAlex topics: Metallic Glasses and Amorphous Alloys · Theoretical and Computational Physics · Magnetic properties of thin films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (22)

Show source-provided references
1. Zhang, T. & Inoue, A. New bulk glassy Ni-based alloys with high strength of 3000 MPa. Mater. Trans. 43, 708–711 (2002).10.2320/matertrans.43.708 ↗
2. Maki, T. Recent progress in microstructure control of steels. Materia Japan 36, 937–940 (1997).10.2320/materia.36.937 ↗
3. Metals Databook (The Japan Institute of Metals, Maruzen, Tokyo, Japan, 1983).
4. Turnbull, D. The undercooling of liquids. Sci. Am. 212, 38–43 (1965).10.1038/scientificamerican0165-38 ↗
5. Perepezko, J.H. & Wilde, G. Amorphization and alloy metastability in undercooled systems. J. Non-Cryst. Solids 274, 271–281 (2000).10.1016/S0022-3093(00)00219-2 ↗
6. Drehman, A.J., Greer, A.L. & Turnbull, D. Bulk formation of a metallic glass: Pd40Ni40P20 . Appl. Phys. Lett. 41, 716–717 (1982).10.1063/1.93645 ↗
7. Inoue, A., Zhang, T. & Masumoto, T. Al-La-Ni amorphous alloys with a wide supercooled liquid region. Mater. Trans. JIM 30, 965–972 (1989).10.2320/matertrans1989.30.965 ↗
8. Pecker, A. & Johnson, W.L. A highly processable metallic glass: Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 . Appl. Phys. Lett. 63, 2342–2344 (1993).10.1063/1.110520 ↗
9. Inoue, A. & Zhang, T. Fabrication of bulky Zr-based glassy alloys by suction casting into copper mold. Mater. Trans. JIM 36, 1184–1187 (1995).10.2320/matertrans1989.36.1184 ↗
10. Inoue, A. in Bulk Amorphous Alloys Ch. 3, 2–21 (Trans Tech, Brandrain 6, CH-8707 Uetikon-Zurich, Switzerland, 1998).
11. Inoue, A. Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279–306 (2000).10.1016/S1359-6454(99)00300-6 ↗
12. Spaepen, F. A microscopic mechanism for steady state inhomogeneous flow in metallic glasses. Acta Metall. 25, 407–415 (1977).10.1016/0001-6160(77)90232-2 ↗
13. Greer, A.L. Metallic glasses. Science 267, 1947–1953 (1995).10.1126/science.267.5206.1947 ↗
14. Zhang, Z.F., Eckert, J. & Schultz, L. Difference in compressive and tensile fracture mechanisms of Zr59Cu20Al10Ni8Ti3 bulk metallic glass. Acta Metall. 51, 1167–1179 (2003).
15. De Boer, F.R., Boom, R., Mattens, W.C.M., Miedema, A.R. & Niessen, A.K. in Cohesion in Metals Ch. 3, 217–290 (North-Holland, Amsterdam, The Netherlands, 1988).
16. Villars, P. & Calvert, L.D. in Pearson's Handbook of Crystallographic Data for Intermetallic Phases Vol. 2, 1428 (ASM International, Materials Park, Ohio 44073, USA, 1991).
17. Imafuku, M., Sato, S., Koshiba, H., Matsubara, E. & Inoue, A. Crystallization behavior of amorphous Fe90-XNb10BX (X = 10 and 30) alloys. Mater. Trans. JIM 41, 1526–1529 (2002).10.2320/matertrans1989.41.1526 ↗
18. Imafuku, M. et al. Structural study of Fe-based glassy alloys with a large supercooled liquid region. Mater. Res. Symp. Proc. 644, L1.6.1–L1.6.10 (2001).
19. Imafuku, M., Sato, S., Koshiba, H., Matsubara, E. & Inoue, A. Structural variation of Fe-Nb-B metallic glasses during crystallization process. Scripta Mater. 44, 2369–2372 (2001).10.1016/S1359-6462(01)00776-X ↗
20. Imafuku, M., Li C., Matsushita, M. & Inoue, A. Formation of τ-phase in Fe60Nb10B30 amorphous alloy with a large supercooled liquid region. Jpn J. Appl. Phys. 41, 219–221 (2002).10.1143/JJAP.41.219 ↗
21. Inoue, A., Shen, B.L., Yavari, A.R. & Greer, A.L. Mechanical properties of Fe-based bulk glassy alloys in Fe-B-Si-Nb and Fe-Ga-P-C-B-Si systems. J. Mater. Res. 18, 1487–1492 (2003).10.1557/JMR.2003.0205 ↗
22. Inoue, A. Bulk amorphous and nanocrystalline alloys with high functional properties. Mater. Sci. Eng. 304–306, 1–10 (2001).10.1016/S0921-5093(00)01551-3 ↗