journal article·2013-07Open access

Interface-induced superconductivity and strain-dependent spin density waves in FeSe/SrTiO3 thin films

Shiyong Tan, Yan Zhang, Miao Xia, Zirong Ye, Fei Chen, Xin Xie, Rui Peng, Difei Xu, Qin Fan, Haichao Xu, Juan Jiang, Tong Zhang, Xinchun Lai, Tao Xiang, Jiangping Hu, Binping Xie, Donglai Feng

Nature Materials· Volume 12· Issue 7

Abstract

The record superconducting transition temperature (T(c)) for the iron-based high-temperature superconductors (Fe-HTS) has long been 56 K. Recently, in single-layer FeSe films grown on SrTiO3 substrates, indications of a new record of 65 K have been reported. Using in situ photoemission measurements, we substantiate the presence of spin density waves (SDWs) in FeSe films--a key ingredient of Fe-HTS that was missed in FeSe before--and we find that this weakens with increased thickness or reduced strain. We demonstrate that the superconductivity occurs when the electrons transferred from the oxygen-vacant substrate suppress the otherwise pronounced SDWs in single-layer FeSe. Beyond providing a comprehensive understanding of FeSe films and directions to further enhance its T(c), we map out the phase diagram of FeSe as a function of lattice constant, which contains all the essential physics of Fe-HTS. With the simplest structure, cleanest composition and single tuning parameter, monolayer FeSe is an ideal system for testing theories of Fe-HTS.
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Research context

OpenAlex topics: Iron-based superconductors research · Corporate Taxation and Avoidance · Physics of Superconductivity and Magnetism

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References (33)

Show source-provided references
1. Hsu, F. C. et al. Superconductivity in the PbO-type structure α-FeSe. Proc. Natl Acad. Sci. USA 105, 14262–14264 (2008).10.1073/pnas.0807325105 ↗
2. Medvedev, S. et al. Electronic and magnetic phase diagram of β-Fe1.01Sewith superconductivity at 36.7 K under pressure. Nature Mater. 8, 630–633 (2009).10.1038/nmat2491 ↗
3. Ma, F. et al. First-principles calculations of the electronic structure of tetragonal α-FeTe and α-FeSe crystals: Evidence for a bicollinear AFM order. Phys. Rev. Lett. 102, 177003 (2009).10.1103/PhysRevLett.102.177003 ↗
4. Li, S. L. et al. First-order magnetic and structural phase transition in Fe1+ySexTe1−x . Phys. Rev. B 79, 054503 (2009).10.1103/PhysRevB.79.054503 ↗
5. Bao, W. et al. Tunable (δ π,δ π) -type AFM order in α-Fe(Te,Se) superconductors. Phys. Rev. Lett. 102, 247001 (2009).10.1103/PhysRevLett.102.247001 ↗
6. Wang, Q. Y. et al. Interface induced high temperature superconductivity in single unit-cell FeSe films on SrTiO3 . Chin. Phys. Lett. 29, 037402 (2012).10.1088/0256-307X/29/3/037402 ↗
7. Liu, D.F. et al. Electronic origin of high-temperature superconductivity in single-layer FeSe superconductor. Nature Commun. 3, 931 (2012).10.1038/ncomms1946 ↗
8. He, S. L. et al. Phase diagram and high temperature superconductivity at 65K in tuning carrier concentration of single-layer FeSe films. Nature Mater.http://dx.doi.org/10.1038/nmat3648 (2012).10.1038/nmat3648 ↗
9. Xiang, Y. Y. et al. High-temperature superconductivity at the FeSe/SrTiO3 interface. Phys. Rev. B 86, 134508 (2012).10.1103/PhysRevB.86.134508 ↗
10. Zhang, Y. et al. Nodeless superconducting gap in AxFe2Se2 (A = K,Cs) revealed by angle-resolved photoemission spectroscopy. Nature Mater. 10, 273–277 (2011).10.1038/nmat2981 ↗
11. Yang, L. X. et al. Electronic structure and unusual exchange splitting in the spin-density wave state of BaFe2As2 parent compound of iron based superconductors. Phys. Rev. Lett. 102, 107002 (2009).10.1103/PhysRevLett.102.107002 ↗
12. Zhou, B. et al. High-resolution angle-resolved photoemission spectroscopy study of the electronic structure of EuFe2As2 . Phys. Rev. B 81, 155124 (2010).10.1103/PhysRevB.81.155124 ↗
13. Zvanut, M. E. et al. An annealing study of an oxygen vacancy related defect in SrTiO3 substrates. J. Appl. Phys. 104, 064122 (2008).10.1063/1.2986244 ↗
14. Szot, K., Speier, W., Carius, R., Zastrow, U. & Beyer, W. Localized metallic conductivity and self-healing during thermal reduction of SrTiO3 . Phys. Rev. Lett. 88, 075508 (2002).10.1103/PhysRevLett.88.075508 ↗
15. Tamai, A. et al. Strong electron correlations in the normal state of the iron-based FeSe0.42Te0.58 superconductor observed by angle-resolved photoemission spectroscopy. Phys. Rev. Lett. 104, 097002 (2010).10.1103/PhysRevLett.104.097002 ↗
16. He, C. et al. Electronic-structure-driven magnetic and structure transitions in superconducting NaFeAs single crystals measured by angle-resolved photoemission spectroscopy. Phys. Rev. Lett. 105, 117002 (2010).10.1103/PhysRevLett.105.117002 ↗
17. Zhang, Y. et al. Unusual doping dependence of the electronic structure and coexistence of spin-density-wave and superconductor phase in single crystalline Sr1−xKxFe2As2 . Phys. Rev. Lett. 102, 127003 (2009).10.1103/PhysRevLett.102.127003 ↗
18. Zhang, Y. et al. Symmetry breaking via orbital-dependent reconstruction of electronic structure in detwinned NaFeAs. Phys. Rev. B 85, 085121 (2012).10.1103/PhysRevB.85.085121 ↗
19. Zhang, Y. et al. Strong correlations and spin-density-wave phase induced by a massive spectral weight redistribution in α-Fe1.06Te. Phys. Rev. B 82, 165113 (2010).10.1103/PhysRevB.82.165113 ↗
20. Yi, M. et al. Symmetry-breaking orbital anisotropy observed for detwinned Ba(Fe1−xCox)2As2 above the spin density wave transition. Proc. Natl Acad. Sci. USA 108, 6878–6883 (2011).10.1073/pnas.1015572108 ↗
21. Yi, M. et al. Electronic reconstruction through the structural and magnetic transitions in detwinned NaFeAs. New J. Phys. 14, 073019 (2012).10.1088/1367-2630/14/7/073019 ↗
22. Yin, Z. P., Haule, K. & Kotilar, G. Magnetism and charge dynamics in iron pnictides. Nature Phys. 7, 294–297 (2011).10.1038/nphys1923 ↗
23. Yin, Z. P., Haule, K. & Kotilar, G. Kinetic frustration and the nature of the magnetic and paramagnetic states in iron pnictides and iron chalcogenides. Nature Mater. 10, 932–935 (2011).10.1038/nmat3120 ↗
24. Jiang, J. et al. The distinct in-plane resistivity anisotropy in the nematic states of detwinned NaFeAs and FeTe single crystals: Evidences for Hund’s rule metal. Preprint at http://arxiv.org/abs/1210.0397 (2012).
25. Yi, M. et al. Unconventional electronic reconstruction in undoped (Ba,Sr)Fe2As2 across the spin density wave transition. Phys. Rev. B 80, 174510 (2009).10.1103/PhysRevB.80.174510 ↗
26. Ge, Q. Q. et al. Anisotropic but nodeless superconducting gap in the presence of spin-density wave in ion-pnictide superconductor NaFe1−xCoxAs. Phys. Rev. X 3, 011020 (2013).
27. Wen, Y. C. et al. Gap opening and orbital modification of superconducting FeSe above the structural distortion. Phys. Rev. Lett. 108, 267002 (2012).10.1103/PhysRevLett.108.267002 ↗
28. Kasahara, S. et al. Evolution from non-Fermi to Fermi-liquid transport via isovalent doping in BaFe2(As1−xPx)2 superconductor. Phys. Rev. B 81, 184519 (2010).10.1103/PhysRevB.81.184519 ↗
29. Albenque, F. R. et al. Hole and electron contributions to the transport properties of Ba(Fe1−xRux)2As2 single crystals. Phys. Rev. B 81, 224503 (2010).10.1103/PhysRevB.81.224503 ↗
30. Matthew, B. L. et al. Enhancement of the superconducting transition temperature of FeSe by intercalation of a molecular spacer layer. Nature Mater. 12, 15–19 (2013).10.1038/nmat3464 ↗
31. Sun, L. L. et al. Re-emerging superconductivity at 48 kelvin in iron chalcogenides. Nature 483, 67–69 (2012).10.1038/nature10813 ↗
32. Chen, F. et al. Electronic identification of the parental phase and mesoscopic phase separation of KxFe2−ySe2 superconductors. Phys. Rev. X 1, 021020 (2011).
33. Liu, K., Lu, Z. Y. & Xiang, T. Atomic and electronic structures of monolayer and bilayer thin films on SrTiO3(001): First-principles study. Phys. Rev. B 85, 235123 (2012).10.1103/PhysRevB.85.235123 ↗