journal article·2016-02

Towards a calcium-based rechargeable battery

A. Ponrouch, C. Frontera, F. Bardé, M. R. Palacín

Nature Materials· Volume 15· Issue 2
Publisher page

Abstract

The development of a rechargeable battery technology using light electropositive metal anodes would result in a breakthrough in energy density. For multivalent charge carriers (M(n+)), the number of ions that must react to achieve a certain electrochemical capacity is diminished by two (n = 2) or three (n = 3) when compared with Li(+) (ref. ). Whereas proof of concept has been achieved for magnesium, the electrodeposition of calcium has so far been thought to be impossible and research has been restricted to non-rechargeable systems. Here we demonstrate the feasibility of calcium plating at moderate temperatures using conventional organic electrolytes, such as those used for the Li-ion technology. The reversibility of the process on cycling has been ascertained and thus the results presented here constitute the first step towards the development of a new rechargeable battery technology using calcium anodes.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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