journal article·2021-02-26

Nanoconfinement of Complex Borohydrides for Hydrogen Storage

Qiwen Lai, Chulaluck Pratthana, Yuwei Yang, Aditya Rawal, Kondo-Francois Aguey-Zinsou

ACS Applied Nano Materials· Volume 4· Issue 2
Publisher page

Abstract

The investigation of nanoscale complex hydrides for hydrogen storage application has gained the spotlight in the past decade. Herein, the thermodynamic behavior of complex borohydrides confined in mesoporous hollow carbon spheres is investigated. The pressure–composition–temperature (PCT) shows no variation of equilibrium plateau pressure upon changes in the hydrogen sorption temperatures. This is interpreted as a result of the high pressure within the carbon nanopores and provides a means to control the thermodynamics of nanosized hydrides.
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Research context

OpenAlex topics: Hydrogen Storage and Materials · Boron and Carbon Nanomaterials Research · Superconductivity in MgB2 and Alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

HERC and MERLin, School of Chemical Engineering, University of New South Wales (UNSW), Sydney, New South Wales 2052, Australia

International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Motooka, Nishiku, Fukuoka 819-0395, Japan

Mark Wainwright Analytical Centre, University of New South Wales (UNSW), Sydney, New South Wales 2052, Australia

Funding

University of New South Wales

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