Approaching the theoretical density limit of ultrahigh-nickel cathodes via cation-disorder-free 10-μm single-crystalline particles
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Transition Metal Oxide Nanomaterials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (59)
Show source-provided references
1. Li, W., Erickson, E. M. & Manthiram, A. High-nickel layered oxide cathodes for lithium-based automotive batteries. Nat. Energy 5, 26–34 (2020).10.1038/s41560-019-0513-0 ↗
2. Sharma, S. S. & Manthiram, A. Towards more environmentally and socially responsible batteries. Energy Environ. Sci. 13, 4087–4097 (2020).10.1039/D0EE02511A ↗
3. Kim, J. et al. Prospect and reality of Ni-rich cathode for commercialization. Adv. Energy Mater. 8, 1702028 (2018).10.1002/aenm.201702028 ↗
4. Zhao, C. et al. Suppressing strain propagation in ultrahigh-Ni cathodes during fast charging via epitaxial entropy-assisted coating. Nat. Energy 9, 345–356 (2024).10.1038/s41560-024-01465-2 ↗
5. Sim, R. & Manthiram, A. Factors influencing gas evolution from high-nickel layered oxide cathodes in lithium-based batteries. Adv. Energy Mater. 14, 2303985 (2024).10.1002/aenm.202303985 ↗
6. Yang, T. et al. Ultrahigh-nickel layered cathode with cycling stability for sustainable lithium-ion batteries. Nat. Sustain. 7, 1204–1214 (2024).10.1038/s41893-024-01402-x ↗
7. Cha, H. et al. Boosting reaction homogeneity in high-energy lithium-ion battery cathode materials. Adv. Mater. 32, 2003040 (2020).10.1002/adma.202003040 ↗
8. Li, J., Fleetwood, J., Hawley, W. B. & Kays, W. From materials to cell: state-of-the-art and prospective technologies for lithium-ion battery electrode processing. Chem. Rev. 122, 903–956 (2021).10.1021/acs.chemrev.1c00565 ↗
9. Wu, X. et al. High-performance, low-cost, and dense-structure electrodes with high mass loading for lithium-ion batteries. Adv. Funct. Mater. 29, 1903961 (2019).10.1002/adfm.201903961 ↗
10. Noh, H.-J., Youn, S., Yoon, C. S. & Sun, Y.-K. Comparison of the structural and electrochemical properties of layered Li [NixCoyMnz] O2 (x= 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries. J. Power Sources 233, 121–130 (2013).10.1016/j.jpowsour.2013.01.063 ↗
11. Lin, F. et al. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Nat. Commun. 5, 3529 (2014).10.1038/ncomms4529 ↗
12. Jung, S. K. et al. Understanding the degradation mechanisms of LiNi0.5Co0.2Mn0.3O2 cathode material in lithium ion batteries. Adv. Energy Mater. 4, 1300787 (2014).10.1002/aenm.201300787 ↗
13. Giménez, C. S., Finke, B., Schilde, C., Froböse, L. & Kwade, A. Numerical simulation of the behavior of lithium-ion battery electrodes during the calendaring process via the discrete element method. Powder Technol. 349, 1–11 (2019).10.1016/j.powtec.2019.03.020 ↗
14. Qian, G. et al. Single-crystal nickel-rich layered-oxide battery cathode materials: synthesis, electrochemistry, and intra-granular fracture. Energy Storage Mater. 27, 140–149 (2020).10.1016/j.ensm.2020.01.027 ↗
15. Yoon, M. et al. Eutectic salt-assisted planetary centrifugal deagglomeration for single-crystalline cathode synthesis. Nat. Energy 8, 482–491 (2023).10.1038/s41560-023-01233-8 ↗
16. Liu, X. et al. Origin and regulation of oxygen redox instability in high-voltage battery cathodes. Nat. Energy 7, 808–817 (2022).10.1038/s41560-022-01036-3 ↗
17. Kim, U.-H. et al. Heuristic solution for achieving long-term cycle stability for Ni-rich layered cathodes at full depth of discharge. Nat. Energy 5, 860–869 (2020).10.1038/s41560-020-00693-6 ↗
18. Park, G.-T. et al. Introducing high-valence elements into cobalt-free layered cathodes for practical lithium-ion batteries. Nat. Energy 7, 946–954 (2022).10.1038/s41560-022-01106-6 ↗
19. Yu, H. et al. Surface enrichment and diffusion enabling gradient-doping and coating of Ni-rich cathode toward Li-ion batteries. Nat. Commun. 12, 4564 (2021).10.1038/s41467-021-24893-0 ↗
20. Lin, Q. et al. Ni–Li anti-site defect induced intragranular cracking in Ni-rich layer-structured cathode. Nano Energy 76, 105021 (2020).10.1016/j.nanoen.2020.105021 ↗
21. Ryu, H.-H. et al. Capacity fading mechanisms in Ni-rich single-crystal NCM cathodes. ACS Energy Lett. 6, 2726–2734 (2021).10.1021/acsenergylett.1c01089 ↗
22. Cho, D.-H. et al. Effect of residual lithium compounds on layer Ni-rich Li [Ni0.7Mn0.3] O2. J. Electrochem. Soc. 161, A920 (2014).10.1149/2.042406jes ↗
23. Park, H. et al. In situ multiscale probing of the synthesis of a Ni-rich layered oxide cathode reveals reaction heterogeneity driven by competing kinetic pathways. Nat. Chem. 14, 614–622 (2022).10.1038/s41557-022-00915-2 ↗
24. Wang, L. et al. High-energy all-solid-state lithium batteries enabled by Co-free LiNiO2 cathodes with robust outside-in structures. Nat. Nanotechnol. 19, 208–218 (2024).10.1038/s41565-023-01519-8 ↗
25. Yoon, C. S. et al. Cation ordering of Zr-doped LiNiO2 cathode for lithium-ion batteries. Chem. Mater. 30, 1808–1814 (2018).10.1021/acs.chemmater.8b00619 ↗
26. Zhou, T. et al. Stabilizing lattice oxygen in slightly Li-enriched nickel oxide cathodes toward high-energy batteries. Chem 8, 2817–2830 (2022).10.1016/j.chempr.2022.07.023 ↗
27. Bianchini, M., Roca-Ayats, M., Hartmann, P., Brezesinski, T. & Janek, J. There and back again—the journey of LiNiO2 as a cathode active material. Angew. Chem. Int. Ed. 58, 10434–10458 (2019).10.1002/anie.201812472 ↗
28. Bi, Y. et al. Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode. Science 370, 1313–1317 (2020).10.1126/science.abc3167 ↗
29. Mesnier, A. & Manthiram, A. Heuristics for molten-salt synthesis of single-crystalline ultrahigh-nickel layered oxide cathodes. ACS Appl. Mater. Interfaces 15, 12895–12907 (2023).10.1021/acsami.2c16326 ↗
30. Ding, G. et al. Molten salt-assisted synthesis of single-crystalline nonstoichiometric Li1+xNi1–xO2 with improved structural stability. Adv. Energy Mater. 13, 2300407 (2023).10.1002/aenm.202300407 ↗
31. Karger, L. et al. Low-temperature ion exchange synthesis of layered LiNiO2 single crystals with high ordering. Chem. Mater. 35, 648–657 (2023).10.1021/acs.chemmater.2c03203 ↗
32. Eum, D. et al. Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes. Nat. Mater. 19, 419–427 (2020).10.1038/s41563-019-0572-4 ↗
33. Kang, K., Meng, Y. S., Breger, J., Grey, C. P. & Ceder, G. Electrodes with high power and high capacity for rechargeable lithium batteries. Science 311, 977–980 (2006).10.1126/science.1122152 ↗
34. Lee, J. et al. Unlocking the potential of cation-disordered oxides for rechargeable lithium batteries. Science 343, 519–522 (2014).10.1126/science.1246432 ↗
35. Park, K.-Y. et al. Lithium-excess olivine electrode for lithium rechargeable batteries. Energy Environ. Sci. 9, 2902–2915 (2016).10.1039/C6EE01266C ↗
36. Ou, X. et al. Enabling high energy lithium metal batteries via single-crystal Ni-rich cathode material co-doping strategy. Nat. Commun. 13, 2319 (2022).10.1038/s41467-022-30020-4 ↗
37. Qin, Z. et al. A universal molten salt method for direct upcycling of spent Ni-rich cathode towards single-crystalline Li-rich cathode. Angew. Chem. 135, e202218672 (2023).10.1002/ange.202218672 ↗
38. Saleem, A. et al. Manganese and cobalt-free ultrahigh-Ni-rich single-crystal cathode for high-performance lithium batteries. ACS Appl. Mater. Interfaces 15, 20843–20853 (2023).10.1021/acsami.2c19687 ↗
39. Tan, Z. et al. In situ constructing ultrastable mechanical integrity of single-crystalline LiNi0.9Co0.05Mn0.05O2 cathode by interior and exterior decoration strategy. Small 20, 2305618 (2024).10.1002/smll.202305618 ↗
40. Ryu, H.-H., Lee, S.-B., Yoon, C. S. & Sun, Y.-K. Morphology-dependent battery performance of Ni-rich layered cathodes: single-crystal versus refined polycrystal. ACS Energy Lett. 7, 3072–3079 (2022).10.1021/acsenergylett.2c01670 ↗
41. Tan, Z. et al. Construction of planar gliding restriction buffer and kinetic self-accelerator stabilizing single-crystalline LiNi0.9Co0.05Mn0.05O2 cathode. ACS Appl. Mater. Interfaces 15, 8555–8566 (2023).10.1021/acsami.2c22815 ↗
42. Lv, F., Zhang, Y., Wu, M. & Gu, Y. A molten-salt method to synthesize ultrahigh-nickel single-crystalline LiNi0.92Co0.06Mn0.02O2 with superior electrochemical performance as cathode material for lithium-ion batteries. Small 18, 2201946 (2022).10.1002/smll.202201946 ↗
43. Ni, L. et al. Crack-free single-crystalline Co-free Ni-rich LiNi0.95Mn0.05O2 layered cathode. EScience 2, 116–124 (2022).10.1016/j.esci.2022.02.006 ↗
44. Kaneda, H., Furuichi, Y., Ikezawa, A. & Arai, H. Single-crystal-like durable LiNiO2 positive electrode materials for lithium-ion batteries. ACS Appl. Mater. Interfaces 14, 52766–52778 (2022).10.1021/acsami.2c13421 ↗
45. Kim, M. et al. Improving LiNiO2 cathode performance through particle design and optimization. J. Mater. Chem. A 10, 12890–12899 (2022).10.1039/D2TA02492F ↗
46. Lee, D. -h et al. Regulating single-crystal LiNiO2 size and surface coating toward a high-capacity cathode for lithium-ion batteries. ACS Appl. Energy Mater. 6, 5309–5317 (2023).10.1021/acsaem.3c00275 ↗
47. Ge, M. et al. Kinetic limitations in single-crystal high-nickel cathodes. Angew. Chem. Int. Ed. 60, 17350–17355 (2021).10.1002/anie.202012773 ↗
48. Qu, M. et al. Nanomechanical quantification of elastic, plastic, and fracture properties of LiCoO. Adv. Energy Mater. 2 2, 940–944 (2012).10.1002/aenm.201200107 ↗
49. del Rio-Santos, D., de la Torre-Gamarra, C., Fernández-Ropero, A., Levenfeld, B. & Varez, A. Optimisation of powder extrusion moulding process for thick ceramic electrodes of LiCoO2 for enhanced energy-density lithium-ion batteries. Ceram. Int. 50, 32954–32963 (2024).10.1016/j.ceramint.2024.06.109 ↗
50. Li, W., Asl, H. Y., Xie, Q. & Manthiram, A. Collapse of LiNi1–x–yCoxMnyO2 lattice at deep charge irrespective of nickel content in lithium-ion batteries. J. Am. Chem. Soc. 141, 5097–5101 (2019).10.1021/jacs.8b13798 ↗
51. Zhang, F. et al. Surface regulation enables high stability of single-crystal lithium-ion cathodes at high voltage. Nat. Commun. 11, 3050 (2020).10.1038/s41467-020-16824-2 ↗
52. Jang, H.-Y. et al. Structurally robust lithium-rich layered oxides for high-energy and long-lasting cathodes. Nat. Commun. 15, 1288 (2024).10.1038/s41467-024-45490-x ↗
53. Kang, K. et al. Electro-chemo-mechanical failure in layered oxide cathodes caused by rotational stacking faults. Nat. Mater. 23, 1093–1099 (2024).10.1038/s41563-024-01899-9 ↗
54. Kim, J.-H., Ryu, H.-H., Kim, S. J., Yoon, C. S. & Sun, Y.-K. Degradation mechanism of highly Ni-rich Li[NixCoyMn1–x–y] O2 cathodes with x> 0.9. ACS Appl. Mater. Interfaces 11, 30936–30942 (2019).10.1021/acsami.9b09754 ↗
55. Meng, X.-H. et al. Kinetic origin of planar gliding in single-crystalline Ni-rich cathodes. JACS 144, 11338–11347 (2022).10.1021/jacs.2c03549 ↗
56. Liu, K., Liu, Y., Lin, D., Pei, A. & Cui, Y. Materials for lithium-ion battery safety. Sci. Adv. 4, eaas9820 (2018).10.1126/sciadv.aas9820 ↗
57. Sun, Y.-K. et al. High-energy cathode material for long-life and safe lithium batteries. Nat. Mater. 8, 320–324 (2009).10.1038/nmat2418 ↗
58. de Biasi, L. et al. Phase transformation behavior and stability of LiNiO2 cathode material for Li-ion batteries obtained from in situ gas analysis and operando X-ray diffraction. ChemSusChem 12, 2240–2250 (2019).10.1002/cssc.201900032 ↗
59. Sun, Y.-K., Lee, D.-J., Lee, Y. J., Chen, Z. & Myung, S.-T. Cobalt-free nickel rich layered oxide cathodes for lithium-ion batteries. ACS Appl. Mater. Interfaces 5, 11434–11440 (2013).10.1021/am403684z ↗