journal article·2020-11-02Open access

Hydrogen production via microwave-induced water splitting at low temperature

J. M. Serra, J. F. Borrás-Morell, B. García-Baños, M. Balaguer, P. Plaza-González, J. Santos-Blasco, D. Catalán-Martínez, L. Navarrete, J. M. Catalá-Civera

Nature Energy· Volume 5· Issue 11

Abstract

This work was supported by the Spanish Government (RTI2018-102161, SEV-2016-0683 and Juan de la Cierva grant IJCI-2017-34110). We thank the support of the Electronic Microscopy Service of the Universitat Politècnica de València.
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OpenAlex topics: Ammonia Synthesis and Nitrogen Reduction · Catalytic Processes in Materials Science · Catalysts for Methane Reforming

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References (51)

Show source-provided references
1. Serra, J. M. Electrifying chemistry with protonic cells. Nat. Energy 4, 178–179 (2019).10.1038/s41560-019-0353-y ↗
2. Wei, M., McMillan, C. A. & de la Rue du Can, S. Electrification of industry: potential, challenges and outlook. Curr. Sustain. Energy Rep. 6, 140–148 (2019).10.1007/s40518-019-00136-1 ↗
3. Malerød-Fjeld, H. et al. Thermo-electrochemical production of compressed hydrogen from methane with near-zero energy loss. Nat. Energy 2, 923–931 (2017).10.1038/s41560-017-0029-4 ↗
4. Schiffer, Z. J. & Manthiram, K. Electrification and decarbonization of the chemical industry. Joule 1, 10–14 (2017).10.1016/j.joule.2017.07.008 ↗
5. Ran, J., Zhang, J., Yu, J., Jaroniec, M. & Qiao, S. Z. Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting. Chem. Soc. Rev. 43, 7787–7812 (2014).10.1039/C3CS60425J ↗
6. Kudo, A. & Miseki, Y. Heterogeneous photocatalyst materials for water splitting. Chem. Soc. Rev. 38, 253–278 (2009).10.1039/B800489G ↗
7. Vøllestad, E. et al. Mixed proton and electron conducting double perovskite anodes for stable and efficient tubular proton ceramic electrolysers. Nat. Mater. 18, 752–759 (2019).10.1038/s41563-019-0388-2 ↗
8. Duan, C. et al. Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel production. Nat. Energy 4, 230–240 (2019).10.1038/s41560-019-0333-2 ↗
9. Service, R. F. New electrolyzer splits water on the cheap. Science 367, 1181 (2020).10.1126/science.367.6483.1181 ↗
10. Hamzehlouia, S., Jaffer, S. A. & Chaouki, J. Microwave heating-assisted catalytic dry reforming of methane to syngas. Sci. Rep. 8, 8940 (2018).10.1038/s41598-018-27381-6 ↗
11. Tsukahara, Y. et al. In situ observation of nonequilibrium local heating as an origin of special effect of microwave on chemistry. J. Phys. Chem. C 114, 8965–8970 (2010).10.1021/jp100509h ↗
12. Sholl, D. S. & Lively, R. P. Seven chemical separations to change the world. Nature 532, 435–437 (2016).10.1038/532435a ↗
13. Eigen, J. & Schroeder, M. Redox cycling stability of Fe2NiO4/YSZ composite storage materials for rechargeable oxide batteries. Energy Storage Mater. 28, 112–121 (2020).10.1016/j.ensm.2020.02.032 ↗
14. Catalá-Civera, J. M. et al. Dynamic measurement of dielectric properties of materials at high temperature during microwave heating in a dual mode cylindrical cavity. IEEE Trans. Microw. Theory Tech. 63, 2905–2914 (2012).10.1109/TMTT.2015.2453263 ↗
15. García-Baños, B., Reinosa, J. J., Peñaranda-Foix, F. L., Fernández, J. F. & Catalá-Civera, J. M. Temperature assessment of microwave-enhanced heating processes. Sci. Rep. 9, 10809 (2019).10.1038/s41598-019-47296-0 ↗
16. Campbell, C. T. & Peden, C. H. F. Oxygen vacancies and catalysis on ceria surfaces. Science 309, 713–714 (2005).10.1126/science.1113955 ↗
17. Naghavi, S. S. et al. Giant onsite electronic entropy enhances the performance of ceria for water splitting. Nat. Commun. 8, 1–6 (2017).10.1038/s41467-017-00381-2 ↗
18. Chueh, W. C. et al. High-flux solar-driven thermochemical dissociation of CO2 and H2O using nonstoichiometric ceria. Sci. 330, 1797–1801 (2010).10.1126/science.1197834 ↗
19. Bulfin, B. et al. Analytical model of CeO2 oxidation and reduction. J. Phys. Chem. C 117, 24129–24137 (2013).10.1021/jp406578z ↗
20. Geller, A. et al. Operando tracking of electrochemical activity in solid oxide electrochemical cells by using near-infrared imaging. ChemElectroChem 2, 1527–1534 (2015).10.1002/celc.201500150 ↗
21. Balaguer, M., Solís, C. & Serra, J. M. Structural-transport properties relationships on Ce1–xLnxO2–δ system (Ln = Gd, La, Tb, Pr, Eu, Er, Yb, Nd) and effect of cobalt addition. J. Phys. Chem. C 116, 7975–7982 (2012).10.1021/jp211594d ↗
22. Holstein, T. Studies of polaron motion. Part II. The ‘small’ polaron. Ann. Phys. (N. Y). 8, 343–389 (1959).10.1016/0003-4916(59)90003-X ↗
23. Seki, K. & Tachiya, M. Electric field dependence of charge mobility in energetically disordered materials: polaron aspects. Phys. Rev. B 65, 1–13 (2002).
24. Emin, D. Generalized adiabatic polaron hopping: Meyer–Neldel compensation and Poole–Frenkel behavior. Phys. Rev. Lett. 100, 166602 (2008).10.1103/PhysRevLett.100.166602 ↗
25. Bishop, S. R., Duncan, K. L. & Wachsman, E. D. Surface and bulk oxygen non-stoichiometry and bulk chemical expansion in gadolinium-doped cerium oxide. Acta Mater. 57, 3596–3605 (2009).10.1016/j.actamat.2009.04.017 ↗
26. Suzuki, T., Kosacki, I. & Anderson, H. U. Defect and mixed conductivity in nanocrystalline doped cerium oxide. J. Am. Ceram. Soc. 85, 1492–1498 (2002).10.1111/j.1151-2916.2002.tb00302.x ↗
27. Zeng, L., Cheng, Z., Fan, J. A., Fan, L. S. & Gong, J. Metal oxide redox chemistry for chemical looping processes. Nat. Rev. Chem. 2, 349–364 (2018).10.1038/s41570-018-0046-2 ↗
28. Liu, W., Song, M.-S., Kong, B. & Cui, Y. Flexible and stretchable energy storage: recent advances and future perspectives. Adv. Mater. 29, 1603436 (2017).10.1002/adma.201603436 ↗
29. Berger, C. M. et al. Development of storage materials for high-temperature rechargeable oxide batteries. J. Energy Storage 1, 54–64 (2015).10.1016/j.est.2014.12.001 ↗
30. Posdziech, O., Schwarze, K. & Brabandt, J. Efficient hydrogen production for industry and electricity storage via high-temperature electrolysis. Int. J. Hydrog. Energy 44, 19089–19101 (2019).10.1016/j.ijhydene.2018.05.169 ↗
31. Maric, R. & Yu, H. In Nanostructures in Energy Generation, Transmission and Storage (IntechOpen, 2018).
32. Dincer, I. & Acar, C. Review and evaluation of hydrogen production methods for better sustainability. Int. J. Hydrog. Energy 40, 11094–11111 (2015).10.1016/j.ijhydene.2014.12.035 ↗
33. Gielen, D. Hydrogen from Renewable Power Technology Outlook for the Energy Transition (2018).
34. Kuckshinrichs, W., Ketelaer, T. & Koj, J. C. Economic analysis of improved alkaline water electrolysis. Front. Energy Res. 5, 1 (2017).10.3389/fenrg.2017.00001 ↗
35. Holladay, J. D., Hu, J., King, D. L. & Wang, Y. An overview of hydrogen production technologies. Catal. Today 139, 244–260 (2009).10.1016/j.cattod.2008.08.039 ↗
36. Glenk, G. & Reichelstein, S. Economics of converting renewable power to hydrogen. Nat. Energy 4, 216–222 (2019).10.1038/s41560-019-0326-1 ↗
37. Marxer, D., Furler, P., Takacs, M. & Steinfeld, A. Solar thermochemical splitting of CO2 into separate streams of CO and O2 with high selectivity, stability, conversion, and efficiency. Energy Environ. Sci. 10, 1142–1149 (2017).10.1039/C6EE03776C ↗
38. Vogt, C., Monai, M., Kramer, G. J. & Weckhuysen, B. M. The renaissance of the Sabatier reaction and its applications on Earth and in space. Nat. Catal. 2, 188–197 (2019).10.1038/s41929-019-0244-4 ↗
39. Eckle, S., Anfang, H. G. & Behm, R. J. Reaction intermediates and side products in the methanation of CO and CO2 over supported Ru catalysts in H2-rich reformate gases. J. Phys. Chem. C 115, 1361–1367 (2011).10.1021/jp108106t ↗
40. Wei, Y. et al. Three-dimensionally ordered macroporous Ce0.8Zr0.2O2-supported gold nanoparticles: synthesis with controllable size and super-catalytic performance for soot oxidation. Energy Environ. Sci. 4, 2959–2970 (2011).10.1039/c0ee00813c ↗
41. Santos, V. P., Pereira, M. F. R., Órfão, J. J. M. & Figueiredo, J. L. The role of lattice oxygen on the activity of manganese oxides towards the oxidation of volatile organic compounds. Appl. Catal. B 99, 353–363 (2010).10.1016/j.apcatb.2010.07.007 ↗
42. Hickman, D. A. & Schmidt, L. D. Production of syngas by direct catalytic oxidation of methane. Science 259, 343–346 (1993).10.1126/science.259.5093.343 ↗
43. Feng, Z. A. et al. Fast vacancy-mediated oxygen ion incorporation across the ceria-gas electrochemical interface. Nat. Commun. 5, 1–9 (2014).
44. Flytzani-Stephanopoulos, M., Sakbodin, M. & Wang, Z. Regenerative adsorption and removal of H2S from hot fuel gas streams by rare earth oxides. Science 312, 1508–1510 (2006).10.1126/science.1125684 ↗
45. Paunović, V. et al. Europium oxybromide catalysts for efficient bromine looping in natural gas valorization. Angew. Chem. Int. Ed. 56, 9791–9795 (2017).10.1002/anie.201704406 ↗
46. Krupka, J. Contactless methods of conductivity and sheet resistance measurement for semiconductors, conductors and superconductors. Meas. Sci. Technol. 24, 62001 (2013).10.1088/0957-0233/24/6/062001 ↗
47. Altschuler, H. M. Handbook of Microwave Measurements Vol. 2 (Polytechnic Institute Brooklyn Press, 1963).
48. Arai, M., Binner, J. G. P. & Cross, T. E. Comparison of techniques for measuring high-temperature microwave complex permittivity: measurements on an alumina/zircona system. J. Microw. Power Electromagn. Energy 31, 12–18 (1996).10.1080/08327823.1996.11688287 ↗
49. López, R. & Gómez, R. Band-gap energy estimation from diffuse reflectance measurements on sol–gel and commercial TiO2: a comparative study. J. Sol.-Gel Sci. Technol. 61, 1–7 (2012).10.1007/s10971-011-2582-9 ↗
50. Murphy, A. B. Band-gap determination from diffuse reflectance measurements of semiconductor films, and application to photoelectrochemical water-splitting. Sol. Energy Mater. Sol. Cells 91, 1326–1337 (2007).10.1016/j.solmat.2007.05.005 ↗
51. Skorodumova, N. V. et al. Electronic, bonding, and optical properties of CeO2 and Ce2O3 from first principles. Phys. Rev. B 64, 1151081–1151089 (2001).10.1103/PhysRevB.64.115108 ↗