Long-life lithium-ion batteries realized by low-Ni, Co-free cathode chemistry
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OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
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References (43)
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1. Liu, H. et al. A disordered rock salt anode for fast-charging lithium-ion batteries. Nature 585, 63–67 (2020).10.1038/s41586-020-2637-6 ↗
2. Manthiram, A. & Goodenough, J. B. Layered lithium cobalt oxide cathodes. Nat. Energy 6, 323–323 (2021).10.1038/s41560-020-00764-8 ↗
3. Lu, Y., Zhang, Y., Zhang, Q., Cheng, F. & Chen, J. Recent advances in Ni-rich layered oxide particle materials for lithium-ion batteries. Particuology 53, 1–11 (2020).10.1016/j.partic.2020.09.004 ↗
4. Bhutada, G. Breaking down the cost of an EV battery cell. Visual Capitalist https://www.visualcapitalist.com/breaking-down-the-cost-of-an-ev-battery-cell/ (2022).
5. Booth, S. G. et al. Perspectives for next generation lithium-ion battery cathode materials. APL Mater. 9, 109201 (2021).10.1063/5.0051092 ↗
6. Li, W., Lee, S. & Manthiram, A. High-nickel NMA: a cobalt-free alternative to NMC and NCA cathodes for lithium-ion batteries. Adv. Mater. 32, 2002718 (2020).10.1002/adma.202002718 ↗
7. Liu, T. et al. Understanding Co roles towards developing Co-free Ni-rich cathodes for rechargeable batteries. Nat. Energy 6, 277–286 (2021).10.1038/s41560-021-00776-y ↗
8. Wang, C., Zhang, R., Kisslinger, K. & Xin, H. L. Atomic-scale observation of O1 faulted phase-induced deactivation of LiNiO2 at high voltage. Nano Lett. 21, 3657–3663 (2021).10.1021/acs.nanolett.1c00862 ↗
9. Wang, C. et al. Chemomechanically stable ultrahigh-Ni single-crystalline cathodes with improved oxygen retention and delayed phase degradations. Nano Lett. 21, 9797–9804 (2021).10.1021/acs.nanolett.1c03852 ↗
10. Lin, R. et al. Hierarchical nickel valence gradient stabilizes high-nickel content layered cathode materials. Nat. Commun. 12, 2350 (2021).10.1038/s41467-021-22635-w ↗
11. Feng, X., Ren, D., He, X. & Ouyang, M. Mitigating thermal runaway of lithium-ion batteries. Joule 4, 743–770 (2020).10.1016/j.joule.2020.02.010 ↗
12. Wang, C. et al. Resolving atomic-scale phase transformation and oxygen loss mechanism in ultrahigh-nickel layered cathodes for cobalt-free lithium-ion batteries. Matter 4, 2013–2026 (2021).10.1016/j.matt.2021.03.012 ↗
13. Wang, C. et al. Resolving complex intralayer transition motifs in high-Ni-content layered cathode materials for lithium-ion batteries. Nat. Mater. 22, 235–241 (2023).10.1038/s41563-022-01461-5 ↗
14. Desai, Pratima. Explainer: Costs of nickel and cobalt used in electric vehicle batteries. Reuters https://www.reuters.com/business/autos-transportation/costs-nickel-cobalt-used-electric-vehicle-batteries-2022-02-03/ (3 Feb. 2022).
15. Bernhart, W. Recycling of lithium-ion batteries in the context of technology and price developments. ATZelectronics Worldw. 14, 38–43 (2019).10.1007/s38314-018-0092-z ↗
16. Burton, Mark, Cherry, Libby & Stringer, David. Elon Musk is going to have a hard time finding clean nickel. Bloomberg News https://www.mining.com/web/elon-musk-is-going-to-have-a-hard-time-finding-clean-nickel/ (24 Aug. 2020).
17. Nickel, 2022 data, 1993–2021 historical, 2023 forecast. Trading Economics https://tradingeconomics.com/commodity/nickel (2022).
18. Murdock, B. E., Toghill, K. E. & Tapia-Ruiz, N. A perspective on the sustainability of cathode materials used in lithium-ion batteries. Adv. Energy Mater. 11, 2102028 (2021).10.1002/aenm.202102028 ↗
19. Lima, P. Nickel reduction in EV batteries with NCM 217 cathode. PushEVs https://pushevs.com/2020/04/30/nickel-reduction-in-ev-batteries-with-ncm-217-cathode/ (2022).
20. Aiken, C. P. et al. Li[Ni0.5Mn0.3Co0.2]O2 as a superior alternative to LiFePO4 for long-lived low voltage Li-ion cells. J. Electrochem. Soc. 169, 050512 (2022).10.1149/1945-7111/ac67b5 ↗
21. Buechel, C., Bednarski, L. & Wietlisbach, S. As lithium-ion battery materials evolve, suppliers face new challenges. S&P Global https://ihsmarkit.com/research-analysis/lithiumion-battery-materials-evolve-suppliers-face-new-challenges.html (2021).
22. Bhandari, N. et al. Batteries: The Greenflation Challenge (Goldman Sachs, 2022).
23. Noh, H.-J., Youn, S., Yoon, C. S. & Sun, Y.-K. Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries. J. Power Sources 233, 121–130 (2013).10.1016/j.jpowsour.2013.01.063 ↗
24. Urban, A., Abdellahi, A., Dacek, S., Artrith, N. & Ceder, G. Electronic-structure origin of cation disorder in transition-metal oxides. Phys. Rev. Lett. 119, 176402 (2017).10.1103/PhysRevLett.119.176402 ↗
25. Arachi, Y. et al. Structural change of Li1−xNi0.5Mn0.5O2 cathode materials for lithium-ion batteries by synchrotron radiation. Chem. Lett. 32, 60–61 (2002).10.1246/cl.2003.60 ↗
26. Zhao, H. et al. Cobalt-free cathode materials: families and their prospects. Adv. Energy Mater. 12, 2103894 (2022).10.1002/aenm.202103894 ↗
27. Hu, G. et al. Sb doping and Sb2O3 coating collaboration to improve the electrochemical performance of LiNi0.5Mn0.5O2 cathode material for lithium ion batteries. Electrochim. Acta 364, 137127 (2020).10.1016/j.electacta.2020.137127 ↗
28. Li, L. et al. Atomic-scale mechanisms of enhanced electrochemical properties of Mo-doped Co-free layered oxide cathodes for lithium-ion batteries. ACS Energy Lett. 4, 2540–2546 (2019).10.1021/acsenergylett.9b01830 ↗
29. Cui, S.-L. et al. Understanding the structure–performance relationship of lithium-rich cathode materials from an oxygen-vacancy perspective. ACS Appl. Mater. Interfaces 12, 47655–47666 (2020).10.1021/acsami.0c14979 ↗
30. Hy, S., Felix, F., Rick, J., Su, W.-N. & Hwang, B. J. Direct in situ observation of Li2O evolution on Li-rich high-capacity cathode material, Li[NixLi(1–2x)/3Mn(2–x)/3]O2 (0 ≤ x ≤ 0.5). JACS 136, 999–1007 (2014).10.1021/ja410137s ↗
31. Xue, Y. et al. Improving electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4 cathode by cobalt surface modification. ACS Appl. Energy Mater. 2, 2982–2989 (2019).10.1021/acsaem.9b00564 ↗
32. Lin, R. et al. Anomalous metal segregation in lithium-rich material provides design rules for stable cathode in lithium-ion battery. Nat. Commun. 10, 1650 (2019).10.1038/s41467-019-09248-0 ↗
33. Zhang, R. et al. Compositionally complex doping for zero-strain zero-cobalt layered cathodes. Nature 610, 67–73 (2022).10.1038/s41586-022-05115-z ↗
34. Li, H. et al. Stabilizing nickel-rich layered oxide cathodes by magnesium doping for rechargeable lithium-ion batteries. Chem. Sci. 10, 1374–1379 (2019).10.1039/C8SC03385D ↗
35. Voronina, N., Sun, Y.-K. & Myung, S.-T. Co-free layered cathode materials for high energy density lithium-ion batteries. ACS Energy Lett. 5, 1814–1824 (2020).10.1021/acsenergylett.0c00742 ↗
36. Thackeray, M. M. et al. Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries. J. Mater. Chem. 17, 3112–3125 (2007).10.1039/b702425h ↗
37. Liu, X. et al. Understanding the stability of LiNi0.5Mn0.5O2 as a Co-free positive electrode. J. Phys. Chem. Lett. 13, 6181–6186 (2022).10.1021/acs.jpclett.2c01126 ↗
38. Luchkin, S. Y. et al. Cycling-driven electrochemical activation of Li-rich NMC positive electrodes for Li-ion batteries. ACS Appl. Energy Mater. 5, 7758–7769 (2022).10.1021/acsaem.2c01239 ↗
39. Xu, J. et al. Understanding the degradation mechanism of lithium nickel oxide cathodes for Li-ion batteries. ACS Appl. Mater. Interfaces 8, 31677–31683 (2016).10.1021/acsami.6b11111 ↗
40. Lin, R., Zhang, R., Wang, C., Yang, X.-Q. & Xin, H. L. TEMImageNet training library and AtomSegNet deep-learning models for high-precision atom segmentation, localization, denoising, and deblurring of atomic-resolution images. Sci. Rep. 11, 5386 (2021).10.1038/s41598-021-84499-w ↗
41. Chen, Y. et al. A review of lithium-ion battery safety concerns: the issues, strategies, and testing standards. J. Energy Chem. 59, 83–99 (2021).10.1016/j.jechem.2020.10.017 ↗
42. Duan, J. et al. Building safe lithium-ion batteries for electric vehicles: a review. Electrochem. Energy Rev. 3, 1–42 (2020).10.1007/s41918-019-00060-4 ↗
43. Dunn, B., Kamath, H. & Tarascon, J.-M. Electrical energy storage for the grid: a battery of choices. Science 334, 928–935 (2011).10.1126/science.1212741 ↗