Introducing high-valence elements into cobalt-free layered cathodes for practical lithium-ion batteries
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OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
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References (51)
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1. Schmuch, R., Wagner, R., Hörpel, G., Placke, T. & Winter, M. Performance and cost of materials for lithium-based rechargeable automotive batteries. Nat. Energy 3, 267–278 (2018).10.1038/s41560-018-0107-2 ↗
2. Naceur, K. B. Tracking Clean Energy Progress (International Energy Agency, 2016).
3. Andre, D. et al. Future generations of cathode materials: an automotive industry perspective. J. Mater. Chem. A 3, 6709–6732 (2015).10.1039/C5TA00361J ↗
4. 2020 Annual Merit Review, Vehicle Technologies Office (US Department of Energy, 2020); https://www.energy.gov/sites/prod/files/2020/06/f75/bat317_liu_2020_o_4.22.20_148PM_LR.pdf
5. Kittner, N., Lill, F. & Kammen, D. M. Energy storage deployment and innovation for the clean energy transition. Nat. Energy 2, 17125 (2017).10.1038/nenergy.2017.125 ↗
6. Cobalt London Metal Exchange https://www.lme.com/en/Metals/EV/LME-Cobalt# (2022).
7. Nkulu, C. B. L. et al. Sustainability of artisanal mining of cobalt in DR Congo. Nat. Sustain. 1, 495–504 (2018).10.1038/s41893-018-0139-4 ↗
8. Alves Dias, P., Blagoeva, D., Pavel, C. & Arvanitidis, N. Cobalt: Demand–Supply Balances in the Transition to Electric Mobility. EUR 29381 EN (Publications Office of the European Union, 2018); https://doi.org/10.2760/9771010.2760/97710 ↗
9. Delmas, C., Saadoune, I. & Rougier, A. The cycling properties of the LixNi1−yCoyO2 electrode. J. Power Sources 44, 595–602 (1993).10.1016/0378-7753(93)80208-7 ↗
10. MacNeil, D. D., Lu, Z. & Dahn, J. R. Structure and electrochemistry of Li[NixCo1−2xMnx]O2 (0 ≤ x ≤ 1/2). J. Electrochem. Soc. 149, A1332–A1336 (2002).10.1149/1.1505633 ↗
11. Sun, H.-H., Choi, W., Lee, J. K., Oh, I.-H. & Jung, H.-G. Control of electrochemical properties of nickel-rich layered cathode materials for lithium ion batteries by variation of the manganese to cobalt ratio. J. Power Sources 275, 877–883 (2015).10.1016/j.jpowsour.2014.11.075 ↗
12. Aishova, A., Park, G.-T., Yoon, C. S. & Sun, Y.-K. Cobalt-free high-capacity Ni-rich layered Li[Ni0.9Mn0.1]O2 cathode. Adv. Energy Mater. 10, 1903179 (2019).10.1002/aenm.201903179 ↗
13. Li, M. & Lu, J. Cobalt in lithium-ion batteries. Science 367, 979–980 (2020).10.1126/science.aba9168 ↗
14. Ryu, H.-H., Sun, H.-H., Myung, S.-T., Yoon, C. S. & Sun, Y.-K. Reducing cobalt from lithium-ion batteries for the electric vehicle era. Energy Environ. Sci. 14, 844–852 (2021).10.1039/D0EE03581E ↗
15. Li, H. et al. Is cobalt needed in Ni-rich positive electrode materials for lithium ion batteries? J. Electrochem. Soc. 166, A429–A439 (2019).10.1149/2.1381902jes ↗
16. Mu, L. et al. Dopant distribution in Co-free high-energy layered cathode materials. Chem. Mater. 31, 9769–9776 (2019).10.1021/acs.chemmater.9b03603 ↗
17. Li, W., Lee, S. & Manthiram, A. High-nickel NMA: a cobalt-free alternative to NMC and NCA cathodes for lithium-ion batteries. Adv. Mater. 32, 2002718 (2020).10.1002/adma.202002718 ↗
18. Ohzuku, T. & Makimura, Y. Layered lithium insertion material of LiNi1/2Mn1/2O2: a possible alternative to LiCoO2 for advanced lithium-ion batteries. Chem. Lett. 30, 744–745 (2001).10.1246/cl.2001.744 ↗
19. Yabuuchi, N., Kim, Y.-T., Li, H. H. & Shao-Horn, Y. Thermal instability of cycled LixNi0.5Mn0.5O2 electrodes: an in situ synchrotron X-ray powder diffraction study. Chem. Mater. 20, 4936–4951 (2008).10.1021/cm800314d ↗
20. Sun, Y.-K., Lee, D.-J., Lee, Y. J., Chen, Z. & Myung, S.-T. Cobalt-free nickel rich layered oxide cathodes for lithium-ion batteries. ACS Appl. Mater. Interfaces 5, 11434–11440 (2013).10.1021/am403684z ↗
21. Li, L. et al. Atomic-scale mechanisms of enhanced electrochemical properties of Mo-doped Co-free layered oxide cathodes for lithium-ion batteries. ACS Energy Lett. 4, 2540–2546 (2019).10.1021/acsenergylett.9b01830 ↗
22. Liu, T. et al. Understanding Co roles towards developing Co-free Ni-rich cathodes for rechargeable batteries. Nat. Energy 6, 277–286 (2021).10.1038/s41560-021-00776-y ↗
23. Van der Ven, A., Bhattacharya, J. & Belak, A. A. Understanding Li diffusion in Li-intercalation compounds. Acc. Chem. Res. 46, 1216–1225 (2013).10.1021/ar200329r ↗
24. Hong, C. et al. Revealing the correlation between structural evolution and Li+ diffusion kinetics of nickel-rich cathode materials in Li-ion batteries.J. Mater. Chem. A 8, 8540 (2020).10.1039/D0TA00555J ↗
25. Park, G.-T. et al. Ultrafine-grained Ni-rich layered cathode for advanced Li-ion batteries. Energy Environ. Sci. 14, 6616–6626 (2021).10.1039/D1EE02898G ↗
26. Zang, Y., Ding, C.-X., Wang, X.-C., Wen, Z.-Y. & Chen, C.-H. Molybdenum-doped lithium-rich layered-structured cathode material Li1.2Ni0.2Mn0.6O2 with high specific capacity and improved rate performance. Electrochim. Acta 168, 234–239 (2015).10.1016/j.electacta.2015.03.223 ↗
27. Breuer, O. et al. Understanding the role of minor molybdenum doping in LiNi0.5Co0.2Mn0.3O2 electrodes: from structural and surface analyses and theoretical modeling to practical electrochemical cells. ACS Appl. Mater. Interfaces 10, 29608–29621 (2018).10.1021/acsami.8b09795 ↗
28. Susai, F. A. et al. Improving performance of LiNi0.8Co0.1Mn0.1O2 cathode materials for lithium-ion batteries by doping with molybdenum-ions: theoretical and experimental studies. ACS Appl. Energy Mater. 2, 4521–4534 (2019).10.1021/acsaem.9b00767 ↗
29. Darbar, D. et al. New synthesis strategies to improve Co-free LiNi0.5Mn0.5O2 cathodes: early transition metal d0 dopants and manganese pyrophosphate coating. J. Power Sources 479, 228591 (2020).10.1016/j.jpowsour.2020.228591 ↗
30. Li, Y. et al. Synthesis and characterization of Mo-doped LiNi0.5Co0.2Mn0.3O2 cathode materials prepared by a hydrothermal process. Ceram. Int. 43, 3483–3488 (2017).10.1016/j.ceramint.2016.10.038 ↗
31. Yoon, C. S. et al. Cation ordering of Zr-doped LiNiO2 cathode for lithium-ion batteries. Chem. Mater. 30, 1808–1814 (2018).10.1021/acs.chemmater.8b00619 ↗
32. Kim, U.-H. et al. Cation ordered Ni-rich layered cathode for ultra-long battery life. Energy Environ. Sci. 14, 1573–1583 (2021).10.1039/D0EE03774E ↗
33. Kim, U.-H. et al. Heuristic solution for achieving long-term cycle stability for Ni-rich layered cathodes at full depth of discharge. Nat. Energy 5, 860–869 (2020).10.1038/s41560-020-00693-6 ↗
34. Li, H. H. et al. Changes in the cation ordering of layered O3 LixNi0.5Mn0.5O2 during electrochemical cycling to high voltages: an electron diffraction study. Chem. Mater. 19, 2551–2565 (2007).10.1021/cm070139+ ↗
35. Ohzuku, T., Ueda, A. & Nagayama, M. Electrochemistry and structural chemistry of LiNiO2 (R3m) for 4 volt secondary lithium cells. J. Electrochem. Soc. 140, 1862–1870 (1993).10.1149/1.2220730 ↗
36. Ryu, H.-H., Park, K.-J., Yoon, C. S. & Sun, Y.-K. Capacity fading of Ni-rich Li[NixCoyMn1–x–y]O2 (0.6 ≤ x ≤ 0.95) cathodes for high-energy-density lithium-ion batteries: bulk or surface degradation?. Chem. Mater. 30, 1155–1163 (2018).10.1021/acs.chemmater.7b05269 ↗
37. Ryu, H.-H. et al. Microstrain alleviation in high-energy Ni-rich NCMA cathode for long battery life. ACS Energy Lett. 6, 216–223 (2021).10.1021/acsenergylett.0c02281 ↗
38. Park, G.-T. et al. High-performance Ni-rich Li[Ni0.9–xCo0.1Alx]O2 cathodes via multi-stage microstructural tailoring from hydroxide precursor to the lithiated oxide. Energy Environ. Sci. 14, 5084–5095 (2021).10.1039/D1EE01773J ↗
39. Yang, S., Yan, B., Lu, L. & Zeng, K. Grain boundary effects on Li-ion diffusion in a Li1.2Co0.13Ni0.13Mn0.54O2 thin film cathode studied by scanning probe microscopy techniques. RSC Adv. 6, 94000–94009 (2016).10.1039/C6RA17681J ↗
40. Schwab, C. et al. Bulk and grain boundary Li-diffusion in dense LiMn2O4 pellets by means of isotope exchange and ToF-SIMS analysis. Phys. Chem. Chem. Phys. 21, 26066–26076 (2019).10.1039/C9CP05128G ↗
41. Xiao, Y. et al. Insight into the origin of lithium/nickel ions exchange in layered Li(NixMnyCoz)O2 cathode materials. Nano Energy 49, 77–85 (2018).10.1016/j.nanoen.2018.04.020 ↗
42. Yoon, C. S., Jun, D.-W., Myung, S.-T. & Sun, Y.-K. Structural stability of LiNiO2 cycled above 4.2 V. ACS Energy Lett. 2, 1150–1155 (2017).10.1021/acsenergylett.7b00304 ↗
43. Alvarado, J. et al. A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries. Mat. Today 21, 341–353 (2018).10.1016/j.mattod.2018.02.005 ↗
44. Hagos, T. T. et al. Developing high-voltage carbonate-ether mixed electrolyte via anode-free cell configuration. J. Power Sources 461, 228053 (2020).10.1016/j.jpowsour.2020.228053 ↗
45. Klein, S. et al. Understanding the outstanding high-voltage performance of NCM523||graphite lithium ion cells after elimination of ethylene carbonate solvent from conventional electrolyte. Adv. Energy Mater. 11, 2003738 (2021).10.1002/aenm.202003738 ↗
46. Nguyen, C. C. & Lucht, B. L. Comparative study of fluoroethylene carbonate and vinylene carbonate for silicon anodes in lithium ion batteries. J. Electrochem. Soc. 161, A1933–A1938 (2014).10.1149/2.0731412jes ↗
47. Zhu, Z. et al. Fluoroethylene carbonate enabling a robust LiF-rich solid electrolyte interphase to enhance the stability of the MoS2 anode for lithium-ion storage. Angew. Chem. 130, 3718–3722 (2018).10.1002/ange.201712907 ↗
48. Park, S.-J., Hwang, J.-Y., Yoon, C. S., Jung, H.-G. & Sun, Y.-K. Stabilization of lithium-metal batteries based on the in situ formation of a stable solid electrolyte interphase layer. ACS Appl. Mater. Interfaces 10, 17985–17993 (2018).10.1021/acsami.8b04592 ↗
49. Markevich, E. et al. High-performance LiNiO2 cathodes with practical loading cycled with Li metal anodes in fluoroethylene carbonate-based electrolyte solution. ACS Appl. Energy Mater. 1, 2600–2607 (2018).10.1021/acsaem.8b00304 ↗
50. Lee, Y. et al. Fluorine-incorporated interface enhances cycling stability of lithium metal batteries with Ni-rich NCM cathodes. Nano Energy 67, 104309 (2020).10.1016/j.nanoen.2019.104309 ↗
51. Rueden, C. T. et al. ImageJ2: imageJ for the next generation of scientific image data. BMC Bioinf. 18, 529 (2017).10.1186/s12859-017-1934-z ↗