Nanoporous Water-Stable Zr-Based Metal–Organic Frameworks for Water Adsorption
Source abstract
Abstract
Studying the hydrolytic stability in metal–organic frameworks (MOFs) is essential for practical implementations. Herein, we designed a new nanoporous MOF, NU-950, with sqc topology and studied the water sorption of three polymorphs NU-901 (scu), NU-1000 (csq), and NU-950 (sqc). The work reveled the effect of topology on the water stability. Additionally, we described a facile and generalizable method to improve the water stability of the as-synthesized Zr-based MOFs using a small hydrophobic capping agent, trifluoroacetic acid (TFA). The work highlighted the synergistic effect of topology and pore environment control in improving the water stability of nanoporous Zr-based MOFs.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
Funding
Defense Advanced Research Projects Agency · Division of Graduate Education · Northwestern University
References (28)
Show source-provided references
1. 10.1038/natrevmats.2015.1810.1038/natrevmats.2015.18 ↗
2. 10.1038/s41578-019-0140-110.1038/s41578-019-0140-1 ↗
3. 10.1021/acscentsci.0c0059210.1021/acscentsci.0c00592 ↗
4. 10.1039/C9CS00756C10.1039/C9CS00756C ↗
5. 10.1126/science.aaz888110.1126/science.aaz8881 ↗
6. 10.1021/jacs.8b1108510.1021/jacs.8b11085 ↗
7. 10.1016/j.chempr.2016.05.00110.1016/j.chempr.2016.05.001 ↗
8. 10.1039/C6CS00362A10.1039/C6CS00362A ↗
9. 10.1016/j.tree.2017.11.00610.1016/j.tree.2017.11.006 ↗
10. 10.1039/C9SC03916C10.1039/C9SC03916C ↗
11. 10.1002/adma.20170430310.1002/adma.201704303 ↗
12. 10.1021/ja500330a10.1021/ja500330a ↗
13. 10.1021/ja00005a07310.1021/ja00005a073 ↗
14. 10.1021/ja903411w10.1021/ja903411w ↗
15. 10.1002/adma.20100402810.1002/adma.201004028 ↗
16. 10.1021/la304151r10.1021/la304151r ↗
17. 10.31635/ccschem.020.20200051510.31635/ccschem.020.202000515 ↗
18. 10.1021/ja509960n10.1021/ja509960n ↗
19. 10.1039/C9EN01321K10.1039/C9EN01321K ↗
20. 10.1039/C5SC01784J10.1039/C5SC01784J ↗
21. 10.1021/ja408959g10.1021/ja408959g ↗
22. 10.1021/jacs.9b0294710.1021/jacs.9b02947 ↗
23. 10.1016/j.ccr.2019.01.01710.1016/j.ccr.2019.01.017 ↗
24. 10.1039/D0CS00997K10.1039/D0CS00997K ↗
25. 10.1021/ja406844r10.1021/ja406844r ↗
26. 10.1021/acs.chemrev.9b0064810.1021/acs.chemrev.9b00648 ↗
27. 10.1021/jacs.8b1371010.1021/jacs.8b13710 ↗
28. 10.1016/j.chempr.2017.11.00510.1016/j.chempr.2017.11.005 ↗