Detoxification of a Mustard-Gas Simulant by Nanosized Porphyrin-Based Metal–Organic Frameworks
Source abstract
Abstract
Selectivity control of the decomposition of sulfur mustard (bis(2-chloroethyl)sulfide) under photo-oxidation conditions using molecular oxygen remains a challenge. In this work, the photo-oxidation of a mustard-gas simulant, 2-chloroethyl ethyl sulfide (CEES), was studied using porphyrin-based metal–organic framework (Por-MOFs) catalysts. It is shown that Por-MOFs are selective oxidizing agents in the transformation of CEES into 2-chloroethyl ethyl sulfoxide (CEESO) without the formation of the highly toxic sulfone product 2-chloroethyl ethyl sulfone (CEESO2). This method to detoxify mustard gas is regarded as more realistic, convenient, and effective than the other available methods.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Pesticide Exposure and Toxicity · Sulfur Compounds in Biology · Synthesis and Characterization of Heterocyclic Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry & CICECO−Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
Department of Chemistry & QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States
CQE, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
Funding
European Regional Development Fund · Funda??o para a Ci?ncia e a Tecnologia
References (51)
Show source-provided references
1. 10.1002/advs.20150043410.1002/advs.201500434 ↗
2. 10.1016/j.mattod.2017.07.00610.1016/j.mattod.2017.07.006 ↗
3. 10.1039/C7TA01142C10.1039/C7TA01142C ↗
4. 10.1039/C7CS00861A10.1039/C7CS00861A ↗
5. 10.3390/molecules2110134810.3390/molecules21101348 ↗
6. 10.1002/advs.20160037110.1002/advs.201600371 ↗
7. 10.1039/C7CY01653K10.1039/C7CY01653K ↗
8. 10.1002/anie.20140886210.1002/anie.201408862 ↗
9. 10.1142/S108842461630007X10.1142/S108842461630007X ↗
10. 10.1021/acs.chemrev.5b0072610.1021/acs.chemrev.5b00726 ↗
11. 10.1039/C7NJ04679K10.1039/C7NJ04679K ↗
12. 10.1016/j.ccr.2016.11.00810.1016/j.ccr.2016.11.008 ↗
13. 10.1067/mem.2001.11432210.1067/mem.2001.114322 ↗
14. 10.1016/j.tox.2005.06.01410.1016/j.tox.2005.06.014 ↗
15. 10.1038/nmat423810.1038/nmat4238 ↗
16. 10.1002/anie.20150374110.1002/anie.201503741 ↗
17. 10.1016/j.jhazmat.2017.09.05510.1016/j.jhazmat.2017.09.055 ↗
18. 10.1021/acsami.7b0634110.1021/acsami.7b06341 ↗
19. 10.1002/anie.20150209410.1002/anie.201502094 ↗
20. 10.1002/anie.20080293210.1002/anie.200802932 ↗
21. 10.1039/C7CS00108H10.1039/C7CS00108H ↗
22. 10.1021/cr100193y10.1021/cr100193y ↗
23. 10.1016/j.jhazmat.2016.04.02010.1016/j.jhazmat.2016.04.020 ↗
24. 10.1039/B705025A10.1039/B705025A ↗
25. 10.1021/cr00016a00310.1021/cr00016a003 ↗
26. 10.1021/ie010732f10.1021/ie010732f ↗
27. 10.1021/cm051372f10.1021/cm051372f ↗
28. 10.1021/acsnano.5b0566010.1021/acsnano.5b05660 ↗
29. 10.1021/acsami.7b0549410.1021/acsami.7b05494 ↗
30. 10.1021/am402897b10.1021/am402897b ↗
31. 10.1002/chem.20160497210.1002/chem.201604972 ↗
32. 10.1039/C6RA28131A10.1039/C6RA28131A ↗
33. 10.1021/acs.inorgchem.8b0010610.1021/acs.inorgchem.8b00106 ↗
34. 10.1039/C4CE00854E10.1039/C4CE00854E ↗
35. 10.2174/1570179411310666008910.2174/15701794113106660089 ↗
36. 10.1142/S108842461100365310.1142/S1088424611003653 ↗
37. 10.1142/S108842461630013510.1142/S1088424616300135 ↗
38. 10.1002/cctc.20170048410.1002/cctc.201700484 ↗
39. 10.1039/C6TA05903A10.1039/C6TA05903A ↗
40. 10.1016/j.taap.2011.06.01210.1016/j.taap.2011.06.012 ↗
41. 10.1021/acs.inorgchem.7b0321410.1021/acs.inorgchem.7b03214 ↗
42. 10.1039/c3sc52259h10.1039/c3sc52259h ↗
43. 10.1021/ja973782d10.1021/ja973782d ↗
44. 10.1021/jo010217r10.1021/jo010217r ↗
45. 10.1021/ja805616610.1021/ja8056166 ↗
46. 10.1002/anie.20140513410.1002/anie.201405134 ↗
47. 10.1002/anie.20150215510.1002/anie.201502155 ↗
48. 10.1021/ar010087910.1021/ar0100879 ↗
49. 10.1021/ja00007a04810.1021/ja00007a048 ↗
50. 10.1002/slct.20170099810.1002/slct.201700998 ↗
51. 10.1021/acsnano.6b0499610.1021/acsnano.6b04996 ↗