Enhancing chloride resistance of freeze–thaw affected concrete through innovative nanomaterial–polymer hybrid cementitious coating
Source abstract
Abstract
Abstract The deterioration of concrete structures in cold marine environments presents a significant durability challenge, particularly due to the synergistic effects of chloride attack and freeze–thaw cycles. However, this problem has not been solved satisfactorily. This study explores an innovative strategy for improving concrete durability via the development of a nano- and polymer-modified cementitious coating system. The research team formulated a composite coating by incorporating precisely controlled concentrations (0.5–1.5 wt%) of nano-SiO 2 or nano-CaCO 3 with waterborne polyacrylate emulsion. Comprehensive experimental investigations were conducted on coated concrete specimens, including mass loss analysis, relative dynamic modulus of elasticity evaluation and Coulomb electric flux test during freeze–thaw cycles, and long-term salt solution immersion. The results demonstrate that the coating system exhibits a dual protective mechanism, effectively mitigating freeze–thaw induced damage while significantly enhancing the chloride resistance of concrete before and after freeze–thaw cycles. Microstructural analysis reveals that the synergistic combination of nanomaterials and polymer optimizes the pore structure of the coating, reducing total porosity and decreasing harmful and more harmful pore volume. Among the tested coating formulations, the 1.0 wt% nano-SiO 2 composite demonstrates superior performance, showing 68% improvement in chloride resistance and 2.27 times in ultimate freeze–thaw cycles compared to uncoated concrete.
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Research context
OpenAlex topics: Concrete and Cement Materials Research · Innovative concrete reinforcement materials · Magnesium Oxide Properties and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Mechanics and Civil Engineering, China University of Mining and Technology , Xuzhou , Jiangsu, 221116 , China
Xuzhou Emergency Management Rescue Center , Xuzhou , Jiangsu, 221000 , China
School of Mines, China University of Mining and Technology , Xuzhou , Jiangsu, 221116 , China
References (49)
Show source-provided references
1. Ariyadasa LM, Bassuoni MT, Mady M, Ghazy A. Performance of plain and nano-modified coatings applied to a concrete bridge deck in cold regions. Case Stud Constr Mater. 2024;21:e03664.10.1016/j.cscm.2024.e03664 ↗
2. Liu Y, Lin P, Ma J, He Z, Luo M. Research on spatial corrosion behavior and durability protection technology of concrete box girder bridge in cold regions. Constr Build Mater. 2024;441:137585.10.1016/j.conbuildmat.2024.137585 ↗
3. Wang D, Zhou X, Fu B, Zhang L. Chloride ion penetration resistance of concrete containing fly ash and silica fume against combined freezing-thawing and chloride attack. Constr Build Mater. 2018;169:740–7.10.1016/j.conbuildmat.2018.03.038 ↗
4. Cao Q, Gao Q, Gao R, Jia J. Chloride penetration resistance and frost resistance of fiber reinforced expansive self-consolidating concrete. Constr Build Mater. 2018;158:719–27.10.1016/j.conbuildmat.2017.10.029 ↗
5. Mostofinejad D, Bahmani H, Khorshidifar A, Afsharpour R. Enhancing concrete durability with polymer impregnation: A comparative study of corrosion and freeze-thaw resistance. Dev Built Environ. 2024;18:100414.10.1016/j.dibe.2024.100414 ↗
6. Jin M, Li W, Wang X, Tang J, Teng L, Ma Y, et al. Investigating the dual influence of freezing-thawing cycles and chloride ion penetration on GGBS-AEA concrete deterioration. J Build Eng. 2023;78:107759.10.1016/j.jobe.2023.107759 ↗
7. Liu J, Hang M, Jiang M, Song H, Zhou X. Performance and mechanism of triethanolamine-triisopropanolamine corrosion inhibitor to deterioration of reinforced concrete under the coupling effect of freeze-thaw cycles and chloride attack. J Build Eng. 2024;98:111066.10.1016/j.jobe.2024.111066 ↗
8. Bao J, Zhang H, Ding Y, Chen X, Zhang P, Xue S, et al. Salt-frost scaling resistance characteristics of nano silica-modified recycled aggregate concrete. J Build Eng. 2024;91:109674.10.1016/j.jobe.2024.109674 ↗
9. Huo J, Liu D. Freezing and thawing durability of lightweight aggregate concrete improved by steel fiber. Concrete. 2009;2:76–9.
10. Zhou Z, Zhang J, Shi X, et al. Research on frost and salt-frost resistance of polypropylene fiber concrete. J Water Resour Water Eng. 2014;25(1):152–60.
11. Li G, Chen X, Zhang Y, Zhuang Z, Lv Y. Studies of nano-SiO2 and subsequent water curing on enhancing the frost resistance of autoclaved PHC pipe pile concrete. J Build Eng. 2023;69:106209.10.1016/j.jobe.2023.106209 ↗
12. Sun S, Han X, Chen A, Zhang Q, Wang Z, Li K. Experimental analysis and evaluation of the compressive strength of rubberized concrete during freeze–thaw cycles. Int J Concr Struct Mater. 2023;17:28.10.1186/s40069-023-00592-6 ↗
13. Han X, Ding N, Chen A, Wang Z, Xu Y, Feng L, et al. Experimental study on freeze-thaw failure of concrete incorporating waste tire crumb rubber and analytical evaluation of frost resistance. Constr Build Mater. 2024;439:137356.10.1016/j.conbuildmat.2024.137356 ↗
14. Han X, Zhang Z, Wang D, Chen A, Ji Y, Wang Z, et al. Experimental study on freeze-thaw failure mechanism of rubberized concrete and analytical evaluation of the damage evolution. Constr Build Mater. 2025;480:141511.10.1016/j.conbuildmat.2025.141511 ↗
15. Zhang SH, Guo D, Li G, Wang JW, Lv YJ. Studies of hydrophobic treatment on improving the salt-frost resistance of hydraulic concrete. Yellow River. 2021;43(1):120–4.
16. Li G, Fan C, Lv Y, Fan F. Effect of hydrophobic treatments on improving the salt frost resistance of concrete. Materials. 2020;13:5361.10.3390/ma13235361 ↗
17. Guo S, Quan J, Liu J, Deng P, Shi C, Zhu D. Influence of high performance cementitious materials coating on the mechanical performance and freeze-thaw resistance of the rubberized concrete. Constr Build Mater. 2024;452:138901.10.1016/j.conbuildmat.2024.138901 ↗
18. Zhang F, He P, Wei F, Dai L. Study on effect of fluorosilicone coating on concrete performance under freeze-thaw cycles. Coat Prot. 2022;43(7):34–40.
19. Meng Q. Study on frost resistance of hydraulic concrete coated with polyurethane. Heilongjiang Hydraul Sci Technol. 2022;50(12):5–7.
20. Liu T. Experimental study on freeze-thaw resistance of new protective coating for hydraulic concrete. Heilongjiang Hydraul Sci Technol. 2022;50(4):1–3.
21. Cao WK, Zhang KJ, Li G, Wang JW, Lv YJ, Li WH. Application of nanomaterials in concrete durability protective coatings. J North China Univ Water Resour Electr Power (Nat Sci Ed). 2023;44(4):60–8.
22. Thissen P, Bogner A, Dehn F. Surface treatments on concrete: An overview on organic, inorganic and nano-based coatings and an outlook about surface modification by rare-earth oxides. RSC Sustainability. 2024;2:2092–124.10.1039/D3SU00482A ↗
23. Basheer PAM, Basheer L, Cleland DJ, Long AE. Surface treatments for concrete: assessment methods and reported performance. Constr Build Mater. 1997;11(7–8):413–29.10.1016/S0950-0618(97)00019-6 ↗
24. Almusallam AA, Khan FM, Dulaijan SU, Al-Amoudi OSB. Effectiveness of surface coatings in improving concrete durability. Cem Concr Compos. 2003;25:473–81.10.1016/S0958-9465(02)00087-2 ↗
25. Yu HF, Sun W, Yan LH, Wang Q. Research on freezing-thawing durability of air-entrained concrete exposed to salt lakes. J Wuhan Univ Technol. 2004;26(3):15–8.
26. Ai HM, Guo JH, Yang CG, Dai BL. Durability of high fly ash content concrete under the coupling effect of freeze-thaw and chlorine salt erosion. Res Appl Build Mater. 2015;2:15–8.
27. Kravanja G, Godec RF, Rozman M, Rudolf R, Ivanič A. Biomimetic superhydrophobic concrete with enhanced anticorrosive, freeze thaw, and deicing resistance. Adv Eng Mater. 2022;24(7):2101445.10.1002/adem.202101445 ↗
28. Guan X, Li F, Hao X, Ji H, Hou P. Study on chloride ion penetration performance of recycled composite micro powder concrete under freeze-thaw environment. J Build Eng. 2024;98:111289.10.1016/j.jobe.2024.111289 ↗
29. Soudki KA, Safiuddin M, Jeffs P, Macdonald G, Kroker M. Chloride penetration resistance of concrete sealer and coating systems. J Civ Eng Manag. 2015;21(4):492–502.10.3846/13923730.2014.890659 ↗
30. Li G, Yang B, Guo C, Du J, Wu X. Time dependence and service life prediction of chloride resistance of concrete coatings. Constr Build Mater. 2015;83:19–25.10.1016/j.conbuildmat.2015.03.003 ↗
31. Yu ML, Deng AZ, Sun H, Chen HH, Fan Z, Qu L. Applicability of organic protective coating for concrete in saline soil environment. N Build Mater. 2021;10:90–4.
32. Zhang C, Li WH, Fan JP, Xun WJ, Chen YH. Relative method for evaluating freeze-thaw damage of coated concrete. J Build Mater. 2023;23(3):546–51.
33. Pushpalal D, Danzandorj S, Narantogtokh B, Nishiwaki T, Sashka U, Erdenebat S, et al. Freezing-thawing durability and chemical characteristics of air-entrained sustainable concrete incorporated high-calcium fly ash in high-volume. J Build Eng. 2024;89:109307.10.1016/j.jobe.2024.109307 ↗
34. Li G, Wei R, Li X, et al. Carbonation resistance of concrete with infiltration coatings. J South China Univ Technol (Nat Sci Ed). 2014;42(6):102–6.
35. Pan X, Shi Z, Shi C, Ling TC, Li N. A review on concrete surface treatment Part I: Types and mechanisms. Constr Build Mater. 2017;132:578–90.10.1016/j.conbuildmat.2016.12.025 ↗
36. Li G, Cui H, Zhou J, Hu W. Improvements of nano-TiO2 on the long-term chloride resistance of concrete with polymer coatings. Coatings. 2019;9:323.10.3390/coatings9050323 ↗
37. Leung CKY, Zhu HG, Kim JK, Woo RSC. Use of polymer/organoclay nanocomposite surface treatment as water/ion barrier for concrete. J Mater Civ Eng. 2008;20(7):484–92.10.1061/(ASCE)0899-1561(2008)20:7(484) ↗
38. Diamanti MV, Brenna A, Bolzoni F, Berra M, Pastore T, Ormellese M. Effect of polymer modified cementitious coatings on water and chloride permeability in concrete. Constr Build Mater. 2013;49:720–8.10.1016/j.conbuildmat.2013.08.050 ↗
39. Zheng W, Chen WG, Feng T, Li WQ, Liu XT, Dong LL, et al. Enhancing chloride ion penetration resistance into concrete by using graphene oxide reinforced waterborne epoxy coating. Prog Org Coat. 2020;138:105389.10.1016/j.porgcoat.2019.105389 ↗
40. Li G, Ding Y, Gao T, Qin Y, Lv Y, Wang K. Chloride resistance of concrete containing nanoparticle-modified polymer cementitious coatings. Constr Build Mater. 2021;299:123736.10.1016/j.conbuildmat.2021.123736 ↗
41. Soleimani M, Bagheri E, Mosaddegh P, Rabiee T, Fakhar A, Sadeghi M. Stable waterborne epoxy emulsions and the effect of silica nanoparticles on their coatings properties. Prog Org Coat. 2021;156:106250.10.1016/j.porgcoat.2021.106250 ↗
42. Qu H, Feng M, Li M, Tian D, Zhang Y, Chen X, et al. Enhancing the carbonation and chloride resistance of concrete by nano-modified eco-friendly water-based organic coatings. Mater Today Commun. 2023;37:107284.10.1016/j.mtcomm.2023.107284 ↗
43. GB/T 50082-2024. Standard for test methods of long-term performance and durability of ordinary concrete. Beijing: China Building Industry Press; 2024.
44. Du J, Liu Z, Sun J, Li G, Wu X, Li G, et al. Enhancing concrete sulfate resistance by adding NaCl. Constr Build Mater. 2022;322:126370.10.1016/j.conbuildmat.2022.126370 ↗
45. Zhao Z, Qi T, Zhou W, Hui D, Xiao C, Qi J, et al. A review on the properties, reinforcing effects, and commercialization of nanomaterials for cement-based materials. Nanotechnol Rev. 2020;9(1):303–22.10.1515/ntrev-2020-0023 ↗
46. ASTM C1202. Standard test method for electrical indication of concrete’s ability to resist chloride ion penetration. ASTM International; 2022.
47. Wu Z, Lian H. High performance concrete. Beijing: China Railway Publishing House; 1999.
48. Zhang J, Bian F, Zhang Y, Fang Z, Fu C, Guo J. Effect of pore structures on gas permeability and chloride diffusivity of concrete. Constr Build Mater. 2018;163:402–13.10.1016/j.conbuildmat.2017.12.111 ↗
49. Li G, Dong L, Bai Z, Lei M, Du J. Predicting carbonation depth for concrete with organic film coatings combined with ageing effects. Constr Build Mater. 2017;142:59–65.10.1016/j.conbuildmat.2017.03.063 ↗