journal article·2025-09-15Open access

Enhancing natural fiber-reinforced biopolymer composites with graphene nanoplatelets: Mechanical, morphological, and thermal properties

Muhammad Adlan Azka, Salit Mohd Sapuan, Edi Syams Zainudin

Nanotechnology Reviews· Volume 14· Issue 1

Abstract

Abstract Many researchers have focused on developing eco-sustainable materials in response to the environmental concerns associated with the use of synthetic polymers, such as natural fiber-reinforced polylactic acid (PLA) composites. In this study, short bamboo and kenaf fibers were employed to reinforce PLA composites. However, using these short natural fibers resulted in composites with inadequate characteristics. Therefore, this research examined the effects of incorporating a small quantity of graphene nanoplatelets into bamboo/kenaf fibers-reinforced PLA hybrid composites enhanced their poor characteristics. The research revealed that incorporating a small quantity of graphene nanoplatelets into composites enhanced their strength, with tensile strength of 41.86 MPa (1 GBK), flexural strength of 71.6712 MPa (0.25 GBK), impact strength of 3.63 kJ/m 2 (1 GBK), and hardness of 86.80 HD. Furthermore, the morphology demonstrates that graphene nanoplatelets are successfully dispersed in composites. Also, the dynamic mechanical investigation of the composites demonstrates that the use of graphene nanoplatelets resulted in a significant rise in the composites’ storage modulus. Additionally, incorporating a small quantity of graphene nanoplatelets to the composites improves thermal stability, as seen by the highest degradation temperature of 330°C for 0.75GBK. The study aims to discover simple, low-cost ways to overcome the composite’s inadequate properties, enabling them to be used in a wider variety of applications.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Natural Fiber Reinforced Composites · Additive Manufacturing and 3D Printing Technologies · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Advanced Engineering Materials and Composites Research Centre (AEMC), Department of Mechanical and Manufacturing Engineering, Universiti Putra Malaysia , UPM Serdang , 43400, Selangor , Malaysia

Laboratory of Biocomposite Technology, Institute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia , UPM Serdang , 43400, Selangor , Malaysia

References (57)

Show source-provided references
1. Salwa HN, Sapuan SM, Mastura MT, Zuhri MY. Green bio composites for food packaging. Int J Recent Technol Eng. 2019;8:450–9. 10.35940/ijrte.B1088.0782S419.10.35940/ijrte.B1088.0782S419 ↗
2. Shebaz Ahmed JP, Satyasree K, Rohith Kumar R, Meenakshisundaram O, Shanmugavel S. A comprehensive review on recent developments of natural fiber composites synthesis, processing, properties, and characterization. Eng Res Express. 2023;5:032001. 10.1088/2631-8695/aceb2d.10.1088/2631-8695/aceb2d ↗
3. Kadea S, Kittikorn T, Hedthong R. Sustainable laminate biocomposite of wood pulp/PLA with modified PVA-MFC compatibilizer: weathering resistance and biodegradation in soil. Ind Crop Prod. 2024;218:118913. 10.1016/j.indcrop.2024.118913.10.1016/j.indcrop.2024.118913 ↗
4. Czajka A, Plichta A, Bulski R, Pomilovskis R, Iuliano A, Cygan T, et al. PLA reinforced with modified chokeberry pomace and beetroot pulp fillers effect of oligomeric chain extender on the properties of biocomposites. Polymer (Guildf). 2023;289:126472. 10.1016/j.polymer.2023.126472.10.1016/j.polymer.2023.126472 ↗
5. Chaitanya S, Singh I, Il Song J. Recyclability analysis of PLA/sisal fiber biocomposites. Compos Part B Eng. 2019;173:106895. 10.1016/j.compositesb.2019.05.106.10.1016/j.compositesb.2019.05.106 ↗
6. Azka MA, Sapuan SM, Abral H, Zainudin ES, Aziz FA. An examination of recent research of water absorption behavior of natural fiber reinforced polylactic acid (PLA) composites: A review. Int J Biol Macromol. 2024;268:131845. 10.1016/j.ijbiomac.2024.131845.10.1016/j.ijbiomac.2024.131845 ↗
7. Ruz-Cruz MA, Herrera-Franco PJ, Flores-Johnson EA, Moreno-Chulim MV, Galera-Manzano LM, Valadez-González A. Thermal and mechanical properties of PLA-based multiscale cellulosic biocomposites. J Mater Res Technol. 2022;18:485–95. 10.1016/j.jmrt.2022.02.072.10.1016/j.jmrt.2022.02.072 ↗
8. Komal UK, Lila MK, Singh I. PLA/banana fiber based sustainable biocomposites: A manufacturing perspective. Compos Part B Eng. 2020;180:107535. 10.1016/j.compositesb.2019.107535.10.1016/j.compositesb.2019.107535 ↗
9. Chen K, Li P, Li X, Liao C, Li X, Zuo Y. Effect of silane coupling agent on compatibility interface and properties of wheat straw/polylactic acid composites. Int J Biol Macromol. 2021;182:2108–16. 10.1016/j.ijbiomac.2021.05.207.10.1016/j.ijbiomac.2021.05.207 ↗
10. Reddy BM, Mohana Reddy YV, Mohan Reddy BC, Reddy RM. Mechanical, morphological, and thermogravimetric analysis of alkali-treated cordia-dichotoma natural fiber composites. J Nat Fibers. 2020;17:759–68. 10.1080/15440478.2018.1534183.10.1080/15440478.2018.1534183 ↗
11. Kumar R, Ul Haq MI, Raina A, Anand A. Industrial applications of natural fibre-reinforced polymer composites – challenges and opportunities. Int J Sustain Eng. 2019;12:212–20. 10.1080/19397038.2018.1538267.10.1080/19397038.2018.1538267 ↗
12. Kareem A, Venkat Reddy P, Snehith Kumar V, Buddi T. Influence of the stacking on mechanical and physical properties of jute/banana natural fiber reinforced polymer matrix composite. Mater Today Proc. 2023. 10.1016/j.matpr.2023.11.017.10.1016/j.matpr.2023.11.017 ↗
13. Nurnadia A, Roshafima RA, Shazwani ALN, Hafizah A, Yunus WMZW, Fatehah R. Effect of silane treatment on rise straw/high density polyethylene biocomposites. J Nat Fibre Polym Compos. 2023;2:3.
14. Asim M, Paridah MT, Chandrasekar M, Shahroze RM, Jawaid M, Nasir M, et al. Thermal stability of natural fibers and their polymer composites. Iran Polym J. 2020;29:625–48. 10.1007/s13726-020-00824-6.10.1007/s13726-020-00824-6 ↗
15. Gholampour A, Ozbakkaloglu T. A review of natural fiber composites: properties, modification and processing techniques, characterization, applications. J Mater Sci. 2020;55:829–92. 10.1007/s10853-019-03990-y.10.1007/s10853-019-03990-y ↗
16. Elfaleh I, Abbassi F, Habibi M, Ahmad F, Guedri M, Nasri M, et al. A comprehensive review of natural fibers and their composites: An eco-friendly alternative to conventional materials. Results Eng. 2023;19:101271. 10.1016/j.rineng.2023.101271.10.1016/j.rineng.2023.101271 ↗
17. Nurazzi NM, Asyraf MRM, Rayung M, Norrrahim MNF, Shazleen SS, Rani MSA, et al. Thermogravimetric analysis properties of cellulosic natural fiber polymer composites: a review on influence of chemical treatments. Polymers (Basel). 2021;13:2710. 10.3390/polym13162710.10.3390/polym13162710 ↗
18. Olonisakin K, Fan M, Xin-Xiang Z, Ran L, Lin W, Zhang W, et al. Key improvements in interfacial adhesion and dispersion of fibers/fillers in polymer matrix composites; Focus on PLA matrix composites. Compos Interfaces. 2022;29:1071–120. 10.1080/09276440.2021.1878441.10.1080/09276440.2021.1878441 ↗
19. Akhyar, Gani A, Ibrahim M, Ulmi F, Farhan A. The influence of different fiber sizes on the flexural strength of natural fiber-reinforced polymer composites. Results Mater. 2024;21:100534. 10.1016/j.rinma.2024.100534.10.1016/j.rinma.2024.100534 ↗
20. Yusof FM, Wahab NA, Abdul Rahman NL, Kalam A, Jumahat A, Mat Taib CF. Properties of treated bamboo fiber reinforced tapioca starch biodegradable composite. Mater Today Proc. 2019;16:2367–73. 10.1016/j.matpr.2019.06.140.10.1016/j.matpr.2019.06.140 ↗
21. Asyraf MRM, Rafidah M, Azrina A, Razman MR. Dynamic mechanical behaviour of kenaf cellulosic fibre biocomposites: A comprehensive review on chemical treatments. Cellulose. 2021;28:2675–95. 10.1007/s10570-021-03710-3.10.1007/s10570-021-03710-3 ↗
22. Hiremath VS, Reddy DM, Reddy Mutra R, Sanjeev A, Dhilipkumar T, Naveen J. Thermal degradation and fire retardant behaviour of natural fibre reinforced polymeric composites- A comprehensive review. J Mater Res Technol. 2024;30:4053–63. 10.1016/j.jmrt.2024.04.085.10.1016/j.jmrt.2024.04.085 ↗
23. Xu D, He S, Leng W, Chen Y, Wu Z. Replacing plastic with bamboo: a review of the properties and green applications of bamboo-fiber-reinforced polymer composites. Polym (Basel). 2023;15:4276. 10.3390/polym15214276.10.3390/polym15214276 ↗
24. Khan A, Sapuan SM, Zainudin ES, Zuhri MYM. Physical, mechanical and thermal properties of novel bamboo/kenaf fiber-reinforced polylactic acid (PLA) hybrid composites. Compos Commun. 2024;51:102103. 10.1016/j.coco.2024.102103.10.1016/j.coco.2024.102103 ↗
25. Siddiqui VU, Sapuan SM, Hassan MR. Innovative dispersion techniques of graphene nanoplatelets (GNPs) through mechanical stirring and ultrasonication: impact on morphological, mechanical, and thermal properties of epoxy nanocomposites. Def Technol. 2025;43:13–25. 10.1016/j.dt.2024.04.018.10.1016/j.dt.2024.04.018 ↗
26. Yusuf J, Sapuan SM, Rashid U, Ilyas RA, Hassan MR. Thermal, mechanical, thermo‐mechanical and morphological properties of graphene nanoplatelets reinforced green epoxy nanocomposites. Polym Compos. 2024;45:1998–2011. 10.1002/pc.27900.10.1002/pc.27900 ↗
27. Cataldi P, Athanassiou A, Bayer IS. Graphene nanoplatelets-based advanced materials and recent progress in sustainable applications. Appl Sci. 2018;8:1438. 10.3390/app8091438.10.3390/app8091438 ↗
28. Saberi M, Ansari R, Hassanzadeh-Aghdam MK. Predicting the electrical conductivity of short carbon fiber/graphene nanoplatelet/polymer composites. Mater Chem Phys. 2023;309:128324. 10.1016/j.matchemphys.2023.128324.10.1016/j.matchemphys.2023.128324 ↗
29. Gao Y, Picot OT, Bilotti E, Peijs T. Influence of filler size on the properties of poly(lactic acid) (PLA)/graphene nanoplatelet (GNP) nanocomposites. Eur Polym J. 2017;86:117–31. 10.1016/j.eurpolymj.2016.10.045.10.1016/j.eurpolymj.2016.10.045 ↗
30. Hussain M, Khan SM, Shafiq M, Al-Dossari M, Alqsair UF, Khan SU, et al. Comparative study of PLA composites reinforced with graphene nanoplatelets, graphene oxides, and carbon nanotubes: Mechanical and degradation evaluation. Energy. 2024;308:132917. 10.1016/j.energy.2024.132917.10.1016/j.energy.2024.132917 ↗
31. Azka MA, Sapuan SM, Zainudin ES. Water absorption properties of graphene nanoplatelets filled bamboo/kenaf reinforced polylactic acid hybrid composites. Int J Biol Macromol. 2025;285:138411. 10.1016/j.ijbiomac.2024.138411.10.1016/j.ijbiomac.2024.138411 ↗
32. American Society for Testing and Materials. ASTM D638-14, standard test method for tensile properties of plastics. West Conshohocken, PA, USA: ASTM International; 2022. p. 1–17. 10.1520/D0638-14.
33. American Society for Testing and Materials. ASTM D790-17, standard test methods for flexural properties of unreinforced and reinforced plastics and electrical insulating materials. West Conshohocken, PA, USA: ASTM International; 2017. p. 1–12. 10.1520/D0790-17.
34. American Society for Testing And Materials. ASTM D256, standard test methods for determining the izod pendulum impact resistance of plastics. West Conshohocken, PA, USA: ASTM International; 2023. p. 1–20. 10.1520/D0256-23E01.
35. American Society for Testing and Materials. ASTM D2240-15, standard test method for rubber property durometer hardness. West Conshohocken, PA, USA: ASTM International; 2015. p. 1–13. 10.1520/D2240-15.
36. Nazrin A, Sapuan SM, Zuhri MYM. Mechanical, physical and thermal properties of sugar palm nanocellulose reinforced thermoplastic starch (TPS)/poly (lactic acid) (PLA) blend bionanocomposites. Polymers (Basel). 2020;12:2216. 10.3390/polym12102216.10.3390/polym12102216 ↗
37. Fang X, Li Y, Zhao J, Xu J, Li C, Liu J, et al. Improved interfacial performance of bamboo fibers/polylactic acid composites enabled by a self-supplied bio-coupling agent strategy. J Clean Prod. 2022;380:134719. 10.1016/j.jclepro.2022.134719.10.1016/j.jclepro.2022.134719 ↗
38. Chung T-J, Park J-W, Lee H-J, Kwon H-J, Kim H-J, Lee Y-K, et al. The improvement of mechanical properties, thermal stability, and water absorption resistance of an eco-friendly PLA/kenaf biocomposite using acetylation. Appl Sci. 2018;8:376. 10.3390/app8030376.10.3390/app8030376 ↗
39. Kashi S, Gupta RK, Kao N, Hadigheh SA, Bhattacharya SN. Influence of graphene nanoplatelet incorporation and dispersion state on thermal, mechanical and electrical properties of biodegradable matrices. J Mater Sci Technol. 2018;34:1026–34. 10.1016/j.jmst.2017.10.013.10.1016/j.jmst.2017.10.013 ↗
40. Scaffaro R, Maio A, Gulino EF, Pitarresi G. Lignocellulosic fillers and graphene nanoplatelets as hybrid reinforcement for polylactic acid: effect on mechanical properties and degradability. Compos Sci Technol. 2020;190:108008. 10.1016/j.compscitech.2020.108008.10.1016/j.compscitech.2020.108008 ↗
41. Prabhudass JM, Palanikumar K, Natarajan E, Markandan K. Enhanced thermal stability, mechanical properties and structural integrity of MWCNT filled bamboo/kenaf hybrid polymer nanocomposites. Materials (Basel). 2022;15:506. 10.3390/ma15020506.10.3390/ma15020506 ↗
42. Sheshmani S, Ashori A, Arab Fashapoyeh M. Wood plastic composite using graphene nanoplatelets. Int J Biol Macromol. 2013;58:1–6. 10.1016/j.ijbiomac.2013.03.047.10.1016/j.ijbiomac.2013.03.047 ↗
43. Giner-Grau S, Lazaro-Hdez C, Pascual J, Fenollar O, Boronat T. Enhancing polylactic acid properties with graphene nanoplatelets and carbon black nanoparticles: A study of the electrical and mechanical characterization of 3D-printed and injection-molded samples. Polymers (Basel). 2024;16:2449. 10.3390/polym16172449.10.3390/polym16172449 ↗
44. Ab Ghani NF, Mat Desa MSZ, Bijarimi M. The evaluation of mechanical properties graphene nanoplatelets reinforced polylactic acid nanocomposites. Mater Today Proc. 2021;42:283–7. 10.1016/j.matpr.2021.01.501.10.1016/j.matpr.2021.01.501 ↗
45. Dlouhy I, Tatarko P, Bertolla L, Chlup Z. Nano-fillers (nanotubes, nanosheets): do they toughen brittle matrices? Procedia Struct Integr. 2019;23:431–8. 10.1016/j.prostr.2020.01.125.10.1016/j.prostr.2020.01.125 ↗
46. Al-Maqdasi Z, Gong G, Nyström B, Emami N, Joffe R. Characterization of wood and graphene nanoplatelets (GNPs) reinforced polymer composites. Materials (Basel). 2020;13:2089. 10.3390/ma13092089.10.3390/ma13092089 ↗
47. Batakliev T, Georgiev V, Angelov V, Ivanov E, Kalupgian C, Muñoz PAR, et al. Synergistic effect of graphene nanoplatelets and multiwall carbon nanotubes incorporated in PLA matrix: nanoindentation of composites with improved mechanical properties. J Mater Eng Perform. 2021;30:3822–30. 10.1007/s11665-021-05679-3.10.1007/s11665-021-05679-3 ↗
48. Kashi S, Gupta RK, Baum T, Kao N, Bhattacharya SN. Morphology, electromagnetic properties and electromagnetic interference shielding performance of poly lactide/graphene nanoplatelet nanocomposites. Mater Des. 2016;95:119–26. 10.1016/j.matdes.2016.01.086.10.1016/j.matdes.2016.01.086 ↗
49. Adesina OT, Sadiku ER, Jamiru T, Ogunbiyi OF, Adesina OS. Thermal properties of spark plasma -sintered polylactide/graphene composites. Mater Chem Phys. 2020;242:122545. 10.1016/j.matchemphys.2019.122545.10.1016/j.matchemphys.2019.122545 ↗
50. Cai C, Liu L, Fu Y. Processable conductive and mechanically reinforced polylactide/graphene bionanocomposites through interfacial compatibilizer. Polym Compos. 2019;40:389–400. 10.1002/pc.24663.10.1002/pc.24663 ↗
51. Liu W, Zhang S, Yang K, Yu W, Shi J, Zheng Q. Preparation of graphene-modified PLA/PBAT composite monofilaments and its degradation behavior. J Mater Res Technol. 2022;20:3784–95. 10.1016/j.jmrt.2022.08.125.10.1016/j.jmrt.2022.08.125 ↗
52. Valapa RB, Pugazhenthi G, Katiyar V. Effect of graphene content on the properties of poly(lactic acid) nanocomposites. RSC Adv. 2015;5:28410–23. 10.1039/C4RA15669B.10.1039/C4RA15669B ↗
53. Ahmed RM, Atta MM, Taha EO. Optical spectroscopy, thermal analysis, and dynamic mechanical properties of graphene nano-platelets reinforced polyvinylchloride. J Mater Sci Mater Electron. 2021;32:22699–717. 10.1007/s10854-021-06756-y.10.1007/s10854-021-06756-y ↗
54. Jesuarockiam N, Jawaid M, Zainudin ES, Thariq Hameed Sultan M, Yahaya R. Enhanced thermal and dynamic mechanical properties of synthetic/natural hybrid composites with graphene nanoplateletes. Polymers (Basel). 2019;11:1085. 10.3390/polym11071085.10.3390/polym11071085 ↗
55. Wang F, Zhou S, Yang M, Chen Z, Ran S. Thermo-mechanical performance of polylactide composites reinforced with alkali-treated bamboo fibers. Polymers (Basel). 2018;10:401. 10.3390/polym10040401.10.3390/polym10040401 ↗
56. Gonçalves C, Pinto A, Machado AV, Moreira J, Gonçalves IC, Magalhães F. Biocompatible reinforcement of poly(lactic acid) with graphene nanoplatelets. Polym Compos. 2018;39:E308–20. 10.1002/pc.24050.10.1002/pc.24050 ↗
57. Rogovina S, Lomakin S, Usachev S, Gasymov M, Kuznetsova O, Shilkina N, et al. The study of properties and structure of polylactide–graphite nanoplates compositions. Polym Cryst. 2022;2022:4367582. 10.1155/2022/4367582.10.1155/2022/4367582 ↗