Excited-state geometry relaxation of pyrene-modified cellulose nanocrystals under UV-light excitation for detecting Fe 3+
Source abstract
Abstract
Abstract Capturing and detecting Fe 3+ ions in aqueous solution is of great significance in biological systems as well as the water treatment industry. Herein, pyrene-modified cellulose nanocrystal (CNC-1-Pyr) acting as a fluorescent probe was prepared by a one-step esterification reaction, which shows geometry relaxation under UV-light excitation. Experiments and density functional theory-based simulations revealed that the structural geometry relaxation is controlled by the electron excitation and fluorescence emission. The S1 state of CNC-1-Pyr provides a conformation match for coordination with Fe 3+ under the excitation of UV light, facilitating the detecting and capturing of Fe 3+ efficiently.
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Research context
OpenAlex topics: Advanced Cellulose Research Studies · Carbon and Quantum Dots Applications · Molecular Sensors and Ion Detection
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University , Chengdu , Sichuan 610031 , China
College of Materials Science and Engineering, Sichuan University , Chengdu , Sichuan 610065 , China
Yibin Institute of Southwest Jiaotong University , Yibin , Sichuan 644000 , China
Institute of Frontier Science and Technology, Southwest Jiaotong University , Chengdu , Sichuan 610031 , China
References (36)
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