Preparation and adsorption properties of nano-graphene oxide/tourmaline composites
Source abstract
Abstract
Abstract This research addresses the asphalt smoke emission in the process of asphalt pavement construction. The nano-graphene oxide (GO)/tourmaline composites were prepared to alleviate the asphalt smoke emission and improve the construction environment. The macrocharacteristics and micromorphology of the composites were analyzed, and their optimal preparation process was determined. Using material microanalysis methods, such as X-ray diffractometer, Raman spectroscopy, and Fourier transform infrared spectrometer, the structural characteristics and material composition of the composites were studied. The adsorption properties of the composites on asphalt smoke were clarified. It will provide technical support for the improvement of infrastructure construction environment. The results show that 3-aminopropyl triethoxysilane is superior than hexadecyl trimethyl ammonium bromide in surface modification of tourmaline. During the composite process, surface modifiers and GO had no significant effect on the structure of tourmaline. GO could enhance the adsorption properties of tourmaline on asphalt smoke. When the GO content was 1.5 wt%, the improvement was the largest, which is 17.42%. At that time, the emission-reduction rate of asphalt smoke reached 41.11%.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Graphene research and applications · Adsorption and biosorption for pollutant removal · Graphene and Nanomaterials Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Road Engineering, School of Highway, Chang’an University , Xi’an 710064 , China
References (48)
Show source-provided references
1. Wang C, Wang S, Gao Z, Song Z. Effect evaluation of road piezoelectric micro-energy collection-storage system based on laboratory and on-site tests. Appl Energ. 2021;287:116581.10.1016/j.apenergy.2021.116581 ↗
2. Khare P, Machesky J, Soto R, He M, Presto A, Gentner D. Asphalt-related emissions are a major missing source of secondary organic aerosol precursors. Sci Adv. 2020;6(36):eabb9785.10.1126/sciadv.abb9785 ↗
3. Poulikakos L, Papadaskalopoulou C, Hofko B, Gschösser F, Falchetto A, Bueno M. Harvesting the unexplored potential of European waste materials for road construction. Resour Conserv Recy. 2017;116:32–44.10.1016/j.resconrec.2016.09.008 ↗
4. Obrist M, Kannan R, Schmidt T, Kober T. Decarbonization pathways of the Swiss cement industry towards net zero emissions. J Clean Prod. 2021;288:125413.10.1016/j.jclepro.2020.125413 ↗
5. Zhang Z, Wang C, Zhang L, Wang S, Zen W. Construction and assessment technology of green road in China. J Chang’an Univ (Nat Sci Ed). 2018;38(5):76–86.
6. Sun X, Yuan J, Zhang Y, Yin Y, Lv J, Jiang S. Thermal aging behavior characteristics of asphalt binder modified by nano-stabilizer based on DSR and AFM. Nanotechnol Rev. 2021;10(1):1157–82.10.1515/ntrev-2021-0075 ↗
7. Chen Q, Lu Y, Wang C, Han B, Fu H. Effect of raw material composition on the working performance of waterborne epoxy resin for road. Int J Pavement Eng. 2020;1–2. 10.1080/10298436.2020.1856842.10.1080/10298436.2020.1856842 ↗
8. Zhang L. Preparation and properties of graphene/tourmaline composite modified asphalt materials. Master Dissertation. Xi’an City, Shaanxi Province, China: Chang’an University; 2019.
9. Fu H, Wang C, Yu G, Chen Q, Liu L. Design optimization and performance evaluation of the open graded friction course with small particle size aggregate. Adv Civ Eng. 2021;2021:6668378.10.1155/2021/6668378 ↗
10. Wang C, Chen Q, Li QJ, Sun X, Li Z. A quantitative rating system for pollutant emission reduction of asphalt mixture. Math Probl Eng. 2017;2017:3761850.10.1155/2017/3761850 ↗
11. Ma C, Christianson L, Huang X, Christianson R, Li S. Efficacy of heated tourmaline in reducing biomass clogging within woodchip bioreactors. Sci Total Env. 2020;755:142401.10.1016/j.scitotenv.2020.142401 ↗
12. Liang Y, Tang X, Zhu Q, Han J, Wang C. A review: application of tourmaline in environmental fields. Chemosphere. 2021;281(11):130780.10.1016/j.chemosphere.2021.130780 ↗
13. Wang F, Meng J, Liang J, Fang B, Zhang H. Insight into the thermal behavior of tourmaline mineral. JOM. 2019;71:2468–74.10.1007/s11837-019-03391-1 ↗
14. Editorial Department of China Journal of Highway and Transport. Review on China’s pavement engineering research·2020. China J Highway Transport. 2020;33(10):1–66.
15. Ding H, Rahman A, Li Q, Qiu Y. Advanced mechanical characterization of asphalt mastics containing tourmaline modifier. Constr Build Mater. 2017;150:520–8.10.1016/j.conbuildmat.2017.05.203 ↗
16. Ye Q, Dong W, Wang S, Li H. Research on the rheological characteristics and aging resistance of asphalt modified with tourmaline. Mater. 2020;13(1):69.10.3390/ma13010069 ↗
17. Zhao Y, Wang P, Wang C, Li Y. Investigation of road performance and colloidal structure of tourmaline modified asphalt. Adv Mater Res. 2012;535–537:1731–4.10.4028/www.scientific.net/AMR.535-537.1731 ↗
18. Zhou X, Moghaddam T, Chen M, Wu S, Adhikari S. Biochar removes volatile organic compounds generated from asphalt. Sci Total Env. 2020;745:141096.10.1016/j.scitotenv.2020.141096 ↗
19. Wang C, Wang P, Li Y, Zhao Y. Laboratory investigation of dynamic rheological properties of tourmaline modified bitumen. Constr Build Mater. 2015;80:195–9.10.1016/j.conbuildmat.2014.12.105 ↗
20. Wang C, Fu H, Chen Q, Sun X, Guo T, Guo J. Preparation and performance of road micro-surfacing materials with exhaust purification function. KSCE J Civ Eng. 2019;23(7):2877–88.10.1007/s12205-019-0856-x ↗
21. Chen Q, Wang C, Wen P, Wang M, Zhao J. Comprehensive performance evaluation of low-carbon modified asphalt based on efficacy coefficient method. J Clean Prod. 2018;203:633–44.10.1016/j.jclepro.2018.08.316 ↗
22. Chen Q, Wang C, Wen P, Sun X, Guo T. Performance evaluation of tourmaline modified asphalt mixture based on grey target decision method. Constr Build Mater. 2019;205:137–47.10.1016/j.conbuildmat.2019.01.168 ↗
23. Zhang X, Zhou X, Xu X, Zhang F, Chen L. Enhancing the functional and environmental properties of asphalt binders and asphalt mixtures using tourmaline anion powder modification. Coatings. 2021;11(5):550.10.3390/coatings11050550 ↗
24. Li G, Chen D, Zhao W, Zhang X. Efficient adsorption behavior of phosphate on la-modified tourmaline. J Environ Chem Eng. 2015;3(1):515–22.10.1016/j.jece.2015.01.010 ↗
25. Li Y, Sun Y, Li J, Gao C. Socioeconomic drivers of urban heat island effect: empirical evidence from major Chinese cities. Sustain Cities Soc. 2020;63:102425.10.1016/j.scs.2020.102425 ↗
26. Chen Y, Wang S, Li Y, Liu Y, Zeng Z. Adsorption of Pb(Ⅱ) by tourmaline-montmorillonite composite in aqueous phase. J Colloid Interf Sci. 2020;575:367–76.10.1016/j.jcis.2020.04.110 ↗
27. Li Y, Xing X, Pei J, Li R, Wen Y, Cui S, et al. Automobile exhaust gas purification material based on physical adsorption of tourmaline powder and visible light catalytic decomposition of g-C3N4/BiVO4. Ceram Int. 2020;46(8):12637–47.10.1016/j.ceramint.2020.02.029 ↗
28. Wang C, Chen Q, Guo T, Li Q. Environmental effects and enhancement mechanism of graphene/tourmaline composites. J Clean Prod. 2020;262:121313.10.1016/j.jclepro.2020.121313 ↗
29. Sun L, Guo Y, Hu Y, Pan S, Jiao Z. Conductometric n-butanol gas sensor based on Tourmaline@ZnO hierarchical micro-nanostructures. Sens Actuat B-Chem. 2021;337:129793.10.1016/j.snb.2021.129793 ↗
30. Zhang X, Jing Q, Ao S, Schneider GF, Kireev D, Zhang Z, et al. Ultrasensitive field‐effect biosensors enabled by the unique electronic properties of graphene. Small. 2020;16(15):1902820.10.1002/smll.201902820 ↗
31. Sherlala A, Raman A, Bello MM, Asghar A. A review of the applications of organo-functionalized magnetic graphene oxide nanocomposites for heavy metal adsorption. Chemosphere. 2018;193:1004–17.10.1016/j.chemosphere.2017.11.093 ↗
32. Zhang X, Wang Y, Luo G, Xing M. Two-dimensional graphene family material: assembly, biocompatibility and sensors applications. Sensors-Basel. 2019;19(13):2966.10.3390/s19132966 ↗
33. Phasuksom K, Prissanaroon-Ouajai W, Sirivat A. A highly responsive methanol sensor based on graphene oxide/polyindole composites. RSC Adv. 2020;10(26):15206–20.10.1039/D0RA00158A ↗
34. Korkmaz S, Kariper A. Graphene and graphene oxide based aerogels: Synthesis, characteristics and supercapacitor applications. J Energy Storage. 2020;27:101038.10.1016/j.est.2019.101038 ↗
35. Deng P, Liu Y, Luo P, Wang J, Liu Y, Wang D, et al. Two-steps synthesis of sandwich-like graphene oxide/LLM-105 nanoenergetic composites using functionalized graphene. Mater Lett. 2017;194:156–9.10.1016/j.matlet.2017.02.038 ↗
36. Wang J, Lei W, Xue Z, Qian H, Liu W. Research progress on synthesis and application of graphene reinforced metal matrix composites. J Mater Eng. 2018;46(12):18–27.
37. Guo T, Wang C, Chen H, Li Z, Chen Q, Han A, et al. Rheological properties of graphene-tourmaline composite modified asphalt. Pet Sci Technol. 2019;37(21):2190–8.10.1080/10916466.2019.1624375 ↗
38. Zhang D, Shen H, Cao X, Ye Y, Zhang X, Ye L, et al. Research progress in graphene reinforced aeronautical metal matrix composites. J Mater Eng. 2019;47(1):1–10.
39. Chen Q, Wang C, Qiao Z, Guo T. Graphene/tourmaline composites as a filler of hot mix asphalt mixture: preparation and properties. Constr Build Mater. 2020;239:117859.10.1016/j.conbuildmat.2019.117859 ↗
40. Luo Y, Chen Q, Wang C, Guo T. Preparation and improved negative ion release of graphene/tourmaline composite. Mater Res Express. 2019;6:055507.10.1088/2053-1591/ab0322 ↗
41. Ministry of Ecology and Environment of the People’s Republic of China. Emission standard of pollutants for petroleum refining industry. GB 31570–2015. Beijing: China Environmental Science Press; 2015.
42. Lin S, Sun S, Shen K, Dong F. Environmental functionalities of tourmaline and applications of its functional composites. Mater Rev. 2017;31(7):131–7.
43. Zhang S, Sun J, Hu D, Xiao C, Zhuo Q, Wang J, et al. Large-sized graphene oxide/modified tourmaline nanoparticle aerogel with stable honeycomb-like structure for high-efficiency PM2.5 capture. J Mater Chem A. 2018;6:16139–48.10.1039/C8TA05506H ↗
44. Huang Z, Wang T, Zhang X, Zheng L, Xue G, Liang J. Preparation of tourmaline/graphene oxide and its application in thermal interface materials. J Compos Mater. 2016;50(28):3953–60.10.1177/0021998316630393 ↗
45. Zhang K, Wang J, Fei G, Xia H. Properties of natural rubber filled with graphene oxide and mesoporous silica. Polym Mater Sci Eng. 2018;34(8):117–23.
46. Guo T, Fu H, Wang C, Chen H, Chen Q, Wang Q, et al. Road performance and emission reduction effect of graphene/tourmaline-composite-modified asphalt. Sustainability. 2021;13(16):8932.10.3390/su13168932 ↗
47. Yin D, Yu M, Shi J, Xu Z, Song D, Liu G. Adsorption characteristics of enrofloxacin by schorl. Chin J Environ Eng. 2017;11(4):2183–9.
48. Bronzova Y, Babushkina M, Frank-Kamenetskaya O, Vereshchagin O, Rozhdestvenskaya I, Zolotarev A. Short-range order in Li–Al tourmalines: IR spectroscopy, X-ray single crystal diffraction analysis and a bond valence theory approach. Phys Chem Min. 2019;46(9):815–25.10.1007/s00269-019-01042-0 ↗