journal article·2025-03-05Open access

Fluorescent sulfur quantum dots for environmental monitoring

Kawan F. Kayani, Omer B. A. Shatery, Sewara J. Mohammed, Shujahadeen B. Aziz, Nian N. Mohammad, Gaylany H. Abdullah, Muhammad S. Mustafa, Dana A. Kader, Wrya O. Karim, Jamal Hassan

Nanotechnology Reviews· Volume 14· Issue 1

Abstract

Abstract The importance of environmental monitoring is on the rise, driven by the increased pressure on the natural environment during the age of urbanization and industrialization. To address this demand, it is necessary to have fast and dependable probes for real-time monitoring with precision and sensitivity. Analytical probes utilizing sulfur nanoparticles offer a modern alternative, exhibiting the ability to identify a range of environmental analytes. The discovery of zero-dimensional quantum dots, such as sulfur quantum dots (SQDs), with unique properties, including optical characteristics, high hydrophilicity, low toxicity, and cost-effectiveness, has positioned SQDs as advancing luminescent nanomaterials. SQDs hold great potential for fluorescence sensing, making them promising candidates for environmental monitoring. This article reviews recent studies on the synthesis of SQDs using various methods and highlights their applications as sensing materials for detecting heavy metal ions and other hazardous molecules. The article provides valuable insights into the production of high-quality SQDs tailored for environmental applications, offering guidance to researchers aiming to enhance sensing technologies for environmental monitoring and contamination detection.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · Advanced biosensing and bioanalysis techniques · Polydiacetylene-based materials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, College of Science, University of Sulaimani, Qliasan St , Sulaimani , Kurdistan Region, 46002 , Iraq

Department of Anesthesia, College of Health Sciences, Cihan University Sulaimaniya , Sulaymaniyah , Kurdistan , Iraq

Research and Development Center, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government , Sulaymaniyah , 46001 , Iraq

Pharmacy Department, College of Medicine, Komar University of Science and Technology , Sulaymaniyah , Kurdistan Region, 46002 , Iraq

Medical Research Centre, Hawler Medical University , Kurdistan , Iraq

Department of Chemistry, College of Education, University of Sulaimani, Old Campus , 46001 , Kurdistan Region , Iraq

Department of Physics, Khalifa University , 127788 , Abu Dhabi , United Arab Emirates

References (100+)

Show source-provided references
1. Kayani KF. Bimetallic metal–organic frameworks (BMOFs) for dye removal: a review. RSC Adv. 2024;14(43):31777–96. 10.1039/D4RA06626J.10.1039/D4RA06626J ↗
2. Skalny AV, Aschner M, Bobrovnitsky IP, Chen P, Tsatsakis A, Paoliello MMB, et al. Environmental and health hazards of military metal pollution. Env Res. 2021;201(June):111568. 10.1016/j.envres.2021.111568.10.1016/j.envres.2021.111568 ↗
3. Khan S, Naushad M, Govarthanan M, Iqbal J, Alfadul SM. Emerging contaminants of high concern for the environment: Current trends and future research. Env Res. 2022 May;207:112609.10.1016/j.envres.2021.112609 ↗
4. Mishra RK, Mentha SS, Misra Y, Dwivedi N. Emerging pollutants of severe environmental concern in water and wastewater: A comprehensive review on current developments and future research. Water-Energy Nexus. 2023;6:74–95. 10.1016/j.wen.2023.08.002.10.1016/j.wen.2023.08.002 ↗
5. Briggs D. Environmental pollution and the global burden of disease. Br Med Bull. 2003;68:1–24.10.1093/bmb/ldg019 ↗
6. Kayani KF, Shatery OBA, Mohammed SJ, Ahmed HR, Hamarawf RF, Mustafa MS. Synthesis and applications of luminescent metal organic frameworks (MOFs) for sensing dipicolinic acid in biological and water samples: a review. Nanoscale Adv. 2024;7:13–41. 10.1039/D4NA00652F.10.1039/D4NA00652F ↗
7. Kayani KF. Nanozyme based on bimetallic metal–organic frameworks and their applications: A review. Microchem J. 2025;208:112363, https://www.sciencedirect.com/science/article/pii/S0026265X24024767.10.1016/j.microc.2024.112363 ↗
8. Ansari MA, Shoaib S, Chauhan W, Gahtani RM, Hani U, Alomary MN, et al. Nanozymes and carbon-dots based nanoplatforms for cancer imaging, diagnosis and therapeutics: Current trends and challenges. Env Res. 2024;241:117522. 10.1016/j.envres.2023.117522.10.1016/j.envres.2023.117522 ↗
9. Kayani KF, Mohammad NN, Kader DA, Mohammed SJ, Shukur DA, Alshatteri AH, et al. Ratiometric lanthanide metal-organic frameworks (MOFs) for smartphone-assisted visual detection of food contaminants and water: a review. ChemistrySelect. 2023 Dec 18;8(47):e202303472. 10.1002/slct.202303472.10.1002/slct.202303472 ↗
10. Kordbacheh F, Heidari G. Materials chemistry horizons water pollutants and approaches for their removal. Mater Chem Horiz. 2023;2(2):139–53.
11. Mustafa MS, Mohammad NN, Radha FH, Kayani KF, Ghareeb HO, Mohammed SJ. Eco-friendly spectrophotometric methods for concurrent analysis of phenol, 2-aminophenol, and 4-aminophenol in ternary mixtures and water samples: assessment of environmental sustainability. RSC Adv. 2024;14(23):16045–55.10.1039/D4RA01094A ↗
12. Kayani KF, Mohammed SJ, Mohammad NN, Abdullah GH, Kader DA, Hamad Mustafa NS. Ratiometric fluorescence detection of tetracycline in milk and tap water with smartphone assistance for visual pH sensing using innovative dual-emissive phosphorus-doped carbon dots. Food Control. 2024 Oct;164:110611.10.1016/j.foodcont.2024.110611 ↗
13. Kayani KF, Rahim MK, Mohammed SJ, Ahmed HR, Mustafa MS, Aziz SB. Recent progress in folic acid detection based on fluorescent carbon dots as sensors: a review. J Fluoresc. 2024. 10.1007/s10895-024-03728-3.10.1007/s10895-024-03728-3 ↗
14. Rashid Ahmed H, Kayani KF. A comparative review of Fenton-like processes and advanced oxidation processes for Methylene Blue degradation. Inorg Chem Commun. 2024;113467, https://www.sciencedirect.com/science/article/pii/S1387700324014576.10.1016/j.inoche.2024.113467 ↗
15. Ahmed HR, Kayani KF, Ealias AM, George G. Eco-friendly biocatalysis: Innovative approaches for the sustainable removal of diverse dyes from aqueous solutions. Inorg Chem Commun. 2024;113447, https://www.sciencedirect.com/science/article/pii/S1387700324014370.10.1016/j.inoche.2024.113447 ↗
16. Zou L, Gu Z, Sun M. Review of the application of quantum dots in the heavy-metal detection. Toxicol Env Chem. 2015;97(3–4):477–90.10.1080/02772248.2015.1050201 ↗
17. Jaishankar M, Tseten T, Anbalagan N, Mathew BB, Beeregowda KN. Toxicity, mechanism and health effects of some heavy metals. Interdiscip Toxicol. 2014;7(2):60–72.10.2478/intox-2014-0009 ↗
18. Rabiee N, Dokmeci MR, Zarrabi A, Makvandi P, Saeb MR, Karimi-Maleh H, et al. Green Biomaterials: fundamental principles. Green Biomater. 2023;1(1):1–4. 10.1080/29934168.2023.2268943.10.1080/29934168.2023.2268943 ↗
19. Kayani KF, Abdullah AM. Eco-friendly fluorescent detection method for Cu2+ ions combined with smartphone-integrated paper strip sensors based on highly fluorescent 2-aminoterephthalic acid in milk samples. J Food Compos Anal. 2024;135:106577.10.1016/j.jfca.2024.106577 ↗
20. Ahmed HR, Salih MA, Agha NNM, Tofiq DI, Karim MAH, Kayani KF, et al. Enhanced methyl orange removal in aqueous solutions using bio-catalytic metal oxides derived from pomegranate peel waste: a green chemistry evaluation. React Kinet Mech Catal. 2024;137:3417–40. 10.1007/s11144-024-02685-z.10.1007/s11144-024-02685-z ↗
21. Fu L, Wang A, Xie K, Zhu J, Chen F, Wang H, et al. Sensors and Actuators B: Chemical Electrochemical detection of silver ions by using sulfur quantum dots modi fi ed gold electrode. Sens Actuators B Chem. 2019;314:127390.10.1016/j.snb.2019.127390 ↗
22. Liu L, Zhang Y, Yuan R, Wang H. Ultrasensitive electrochemiluminescence biosensor using sulfur quantum dots as an emitter and an efficient DNA walking machine with triple-stranded DNA as a signal amplifier. Anal Chem. 2020;92(22):15112–9.10.1021/acs.analchem.0c03311 ↗
23. Liu S, Wang H, Feng A, Chang J, Zhang C, Shi YE, et al. Photoluminescence investigations of sulfur quantum dots synthesized by a bubbling-assisted strategy. Nanoscale Adv. 2021;3(14):4271–5.10.1039/D1NA00282A ↗
24. Gao P, Wang G, Zhou L. Luminescent sulfur quantum dots: synthesis, properties and potential applications. ChemPhotoChem. 2020;4(11):5235–44.10.1002/cptc.202000158 ↗
25. Shivalkar S, Arshad F, Sahoo AK. Visible light-mediated photoactivated sulfur quantum dots as heightened antibacterial agents. ACS Omega. 2022;7:33358–64.10.1021/acsomega.2c03968 ↗
26. Ning K, Sun Y, Liu J, Fu Y, Ye K, Liang J, et al. Research update of emergent sulfur quantum dots in synthesis and sensing/bioimaging applications. Molecules. 2022;27(9):2822.10.3390/molecules27092822 ↗
27. Nanomaterials S, Li C, Wang Y, Jiang H, Wang X. Biosensors based on advanced sulfur-containing nanomaterials. Sensors. 2020;20(12):3488.10.3390/s20123488 ↗
28. Bai Z, Shen L, Wei J, Li Y, Abbas A, Li Y, et al. Layered sulfur nanosheets prepared by assembly of sulfur quantum dots: implications for wide optical absorption and multiwavelength photoluminescence. ACS Appl Nano Mater. 2020;3(11):10749–56.10.1021/acsanm.0c02024 ↗
29. Li S, Chen D, Zheng F, Zhou H, Jiang S, Wu Y. Water-soluble and lowly toxic sulphur quantum dots. Adv Funct Mater. 2014;24(45):7133–8.10.1002/adfm.201402087 ↗
30. Arshad F, Sk MP. Luminescent sulfur quantum dots for colorimetric discrimination of multiple metal ions. ACS Appl Nano Mater. 2020;3(3):3044–9.10.1021/acsanm.0c00394 ↗
31. Pal A, Arshad F, Sk MP. Emergence of sulfur quantum dots: Unfolding their synthesis, properties, and applications. Adv Colloid Interface Sci. 2020;285:102274. 10.1016/j.cis.2020.102274.10.1016/j.cis.2020.102274 ↗
32. Siomra A. Two-photon excited luminescence of sulfur quantum dots for heavy metal ion detection. RSC Adv. 2024;14:2439–46.10.1039/D3RA07521D ↗
33. Xu N, Wen Q. Single element material sulfur quantum dots nonlinear optics and ultrafast photonic applications. Opt Laser Technol. 2021;138:106858.10.1016/j.optlastec.2020.106858 ↗
34. Cotta MA. Quantum dots and their applications: what lies ahead? ACS Appl. 2020;3(6):4920–4.10.1021/acsanm.0c01386 ↗
35. Shao L, Gao Y, Yan F. Semiconductor quantum dots for biomedicial applications. Sensors. 2011;11(12):11736–51.10.3390/s111211736 ↗
36. Arshad F, Sk MP, Maurya SK, Siddique HR. Mechanochemical synthesis of sulfur quantum dots for cellular imaging. ACS Appl Nano Mater. 2021;4(4):3339–44.10.1021/acsanm.1c00509 ↗
37. Deng H, Yang Y, Chen W, Xia X. Size-focusing results in highly photoluminescent sulfur quantum dots with steadfast emission wavelength. Nanoscale. 2021;13:2519–26.10.1039/D0NR07251F ↗
38. Xia M, Mei H, Qian Q, Dahlgren RA, Gao M, Wang X. Sulfur quantum dot-based “ON–OFF–ON” fluorescence platform for detection and bioimaging of Cr(VI) and ascorbic acid in complex environmental matrices and biological tissues. RSC Adv. 2021;11(18):10572–81.10.1039/D1RA00401H ↗
39. Sheng Y, Huang Z, Zhong Q, Deng H, Lai M, Yang Y, et al. Size-focusing results in highly photoluminescent sulfur quantum dots with a stable emission wavelength. Nanoscale. 2021;13(4):2519–26.10.1039/D0NR07251F ↗
40. Tang H, Zhong J, Chen W, Shi K, Mei G, Zhang Y, et al. Lead sulfide quantum dot photodetector with enhanced responsivity through a two-step ligand-exchange method. ACS Appl Nano Mater. 2019;2(10):6135–43.10.1021/acsanm.9b00889 ↗
41. Mohammed NJ, Dagher HF. Synthesis and characterization of mercuric sulfide nanoparticles thin films by pulsed laser ablation (PLA) in distilled water (DW). Thin Films Laboratory, Coll Sci, Mustansiriyah University, Baghdad, Iraq. 2020;17(3):11–6.
42. Devi RA, Latha M, Velumani S, Oza G, Rohini M, Lee J, et al. Synthesis and characterization of cadmium sulfide nanoparticles by chemical precipitation method. J Nanosci Nanotechnol. 2015;15:8434–9.10.1166/jnn.2015.11472 ↗
43. Le N, Zhang M, Kim K. Quantum dots and their interaction with biological systems. Int J Mol Sci. 2022;23(18):1–27.10.3390/ijms231810763 ↗
44. Zhu C, Chen Z, Gao S, Leng B, Bin I, Wen K, et al. Progress in natural science: materials international recent advances in non-toxic quantum dots and their biomedical applications. Prog Nat Sci Mater Int. 2020;29(6):628–40.10.1016/j.pnsc.2019.11.007 ↗
45. Kayani KF, Mohammed SJ, Ghafoor D, Rahim MK, Ahmed HR. Carbon dot as fluorescence sensor for glutathione in human serum samples: a review. Mater Adv. 2024;5(11):4618–33. 10.1039/D4MA00185K.10.1039/D4MA00185K ↗
46. Kayani KF, Shatery OBA, Mustafa MS, Alshatteri AH, Mohammed SJ, Aziz SB. Environmentally sustainable synthesis of whey-based carbon dots for ferric ion detection in human serum and water samples: evaluating the greenness of the method. RSC Adv. 2024;14(8):5012–21.10.1039/D3RA08680A ↗
47. Kayani KF, Abdullah CN. A dual-mode detection sensor based on nitrogen-doped carbon dots for visual detection of Fe(III) and ascorbic acid via a smartphone. J Fluoresc. 2024.10.1007/s10895-024-03604-0 ↗
48. Mansuriya BD. Carbon dots: classification, properties, synthesis, characterization, and applications in health care – an updated review (2018–2021). Nanomater. 2021;11:2525.10.3390/nano11102525 ↗
49. Mohammed SJ, Hawaiz FE, Aziz SB, Al-Jaf SH. Organic soluble nitrogen-doped carbon dots (ONCDs) to reduce the optical band gap of PVC polymer: Breakthrough in polymer composites with improved optical properties. Opt Mater (Amst). 2024;149:1–16.10.1016/j.optmat.2024.115014 ↗
50. Shatery OBA, Kayani KF, Mustafa MS, Mohammed SJ. Rational design for enhancing sensitivity and robustness of a probe via encapsulation of carbon dots into a zeolitic imidazolate framework-8 for quantification of tetracycline in milk with greenness evaluation. Res Chem Intermed. 2024;50:2291–306. 10.1007/s11164-024-05271-z.10.1007/s11164-024-05271-z ↗
51. Kayani KF, Ghafoor D, Mohammed SJ, Shatery OBA. Carbon dots: synthesis, sensing mechanisms, and potential applications as promising materials for glucose sensors. Nanoscale Adv. 2024;7:42–59. 10.1039/D4NA00763H.10.1039/D4NA00763H ↗
52. Mohammed SJ, Sidiq MK, Najmuldeen HH, Kayani KF, Kader DA, Aziz SB. A Comprehensive review on nitrogen-doped carbon dots for antibacterial applications. J Env Chem Eng. 2024;12(6):114444, https://www.sciencedirect.com/science/article/pii/S2213343724025752.10.1016/j.jece.2024.114444 ↗
53. Zhao C, Song X, Liu Y, Fu Y, Ye L, Wang N, et al. Synthesis of graphene quantum dots and their applications in drug delivery. J Nanobiotechnol. 2020;18:1–32.10.1186/s12951-020-00698-z ↗
54. Zhang Y, Cai N, Chan V. Recent advances in silicon quantum dot-based fluorescent biosensors. Biosensors. 2023;13:1–16.10.3390/bios13030311 ↗
55. Ren Q, Ma Y, Zhang S, Ga L, Ai J. One-step synthesis of water-soluble silver sulfide quantum dots and their application to bioimaging. ACS Omega. 2021;6(9):6361–7.10.1021/acsomega.0c06276 ↗
56. Vishnoi P, Mazumder M, Barua M, Pati SK, Rao CNR. Phosphorene quantum dots. Chem Phys Lett. 2018;699:223–8.10.1016/j.cplett.2018.03.069 ↗
57. Kayani KF, Mohammed SJ, Mohammad NN, Abdullah AM, Tofiq DI, Mustafa MS, et al. Sulfur quantum dots for fluorescence sensing in biological and pharmaceutical samples: a review. Mater Adv. 2024;5:6351–67. 10.1039/D4MA00502C.10.1039/D4MA00502C ↗
58. Wang R, Xu Y, Zhang T, Jiang Y. Rapid and sensitive detection of Salmonella typhimurium using aptamer-conjugated carbon dots as fluorescence probe. Anal Methods. 2015;7(5):1701–6.10.1039/C4AY02880E ↗
59. Ma ZB, Zhang Y, Ren XH, He XW, Li WY, Zhang YK. Dual-reverse-signal ratiometric fluorescence method for malachite green detection based on multi-mechanism synergistic effect. Spectrochim Acta - Part A Mol Biomol Spectrosc. 2022;276:121196.10.1016/j.saa.2022.121196 ↗
60. Ruan H, Zhou L. Synthesis of fluorescent sulfur quantum dots for bioimaging and biosensing. Front Bioeng Biotechnol. 2022;10:1–7.10.3389/fbioe.2022.909727 ↗
61. Huang Z, Gao Y, Huang Z, Chen D, Sun J, Zhou L. Sulfur quantum dots: A novel fluorescent probe for sensitive and selective detection of Fe3+ and phytic acid. Microchem J. 2021;170(May):106656. 10.1016/j.microc.2021.106656.10.1016/j.microc.2021.106656 ↗
62. Winzell A, Winzell A. Surface modification of CdSe (ZnS) quantum dots for biomedical applications surface modification of CdSe (ZnS) quantum dots for biomedical applications. Thin Solid Films. 2010;519:1202–12.10.1016/j.tsf.2010.08.070 ↗
63. Zhao J, Fan Z. Using zinc ion-enhanced fluorescence of sulfur quantum dots to improve the detection of the zinc (II) -binding antifungal drug clioquinol. Microchim Acta. 2020;187(3):1–8.10.1007/s00604-019-4020-6 ↗
64. Kayani KF, Omer KM. A red luminescent europium metal organic framework (Eu-MOF) integrated with a paper strip using smartphone visual detection for determination of folic acid in pharmaceutical formulations. N J Chem. 2022;46(17):8152–61. 10.1039/D2NJ00601D.10.1039/D2NJ00601D ↗
65. Li H, Zhu H, Sun M, Yan Y, Zhang K, Huang D. Manipulating surface chemistry of quantum dots for sensitive ratiometric fluorescence detection of sulfur dioxide. Langmuir. 2015;31(31):8667–71.10.1021/acs.langmuir.5b02340 ↗
66. Wang F, Zhang H, Xu B. Physical chemistry of nanoclusters nitrogen and sulfur quantum dot co-modified graphene nanosheet with enhanced photocatalytic activity for methyl orange degradation. Russian J Phys Chem A. 2020;94(11):2299–305.10.1134/S0036024420110333 ↗
67. Shen L, Wang H, Liu S, Shen L, Wang H, Liu S, et al. Assembling of sulphur quantum dots in fission of sublimed sulphur assembling of sulphur quantum dots in fission of sublimed sulphur. J Am Chem Soc. 2018;140(25):7878–84.10.1021/jacs.8b02792 ↗
68. Mendonça LTB, Azevedo WMDe. A fast bottom-up route for preparing CdS quantum dots using laser ablation in a liquid environment. J Lumin. 2015;171:79–84.10.1016/j.jlumin.2015.10.031 ↗
69. Wang H, Wang Z, Xiong Y, Kershaw SV, Li T, Wang Y, et al. Hydrogen peroxide assisted synthesis of highly luminescent sulfur quantum dots. Angew Chem – Int Ed. 2019;58(21):7040–4.10.1002/anie.201902344 ↗
70. Navarro M. Toward greener electrochemical synthesis of composition-tunable luminescent CdX-based (X = Te, Se, S) quantum dots for bioimaging cancer cells. Sens Actuators B Chem. 2017;250:233–43.10.1016/j.snb.2017.04.185 ↗
71. Saleh HM. Synthesis and characterization of nanomaterials for application in cost-effective electrochemical devices. Sustainability. 2023;15:10891.10.3390/su151410891 ↗
72. Xiao L, Du Q, Huang Y, Wang L, Cheng S, Wang Z, et al. Rapid synthesis of sulfur nanodots by one-step hydrothermal reaction for luminescence-based applications. ACS Appl Nano Mater. 2019;2(10):6622–8.10.1021/acsanm.9b01507 ↗
73. Saravanan K, Selladurai S, Ananthakumar S, Suriakarthick R. Materials science in semiconductor processing solvothermal synthesis of copper cadmium sulphide ( CuCdS 2) nanoparticles and its structural, optical and morphological properties. Mater Sci Semicond Process. 2019;93:345–56.10.1016/j.mssp.2019.01.024 ↗
74. Bhargava SK. Easy, one- step synthesis of CdTe quantum dots via microwave irradiation for fingerprinting application. Mater Res Bull. 2017;90:260–5.10.1016/j.materresbull.2017.03.003 ↗
75. Safeera TA, Johns N, Anila EI, Martinez AI, Sreenivasan PV, Reshmi R, et al. Low temperature fabrication and characterization of wurtzite structured ZnS quantum dots by chemical spray pyrolysis. J Anal Appl Pyrolysis. 2015;115:96–102.10.1016/j.jaap.2015.07.005 ↗
76. Nair VR, Shanthil M, Sandeep K, Savitha KU, Archana A, Deepamol V, et al. Quantum dot-based fluorometric sensor for Hg(II) in water customizable for onsite visual detection. ACS Omega. 2023;8(32):29468–74.10.1021/acsomega.3c03125 ↗
77. Wang Z, Xing X, Yan Y, Zhao R, Zou T, Wang Z. One-step hydrothermal synthesis of thioglycolic acid capped CdS quantum dots as fluorescence determination of cobalt ion. Sci Rep. 2018;8(8953):1–12.10.1038/s41598-018-27244-0 ↗
78. Liu Y, Shao X, Gao Z, Zhu X, Pan Z, Ying Y, et al. Sulfur quantum dot as a fluorescent nanoprobe for Fe3+ ions: Uncovering of detection mechanism, high sensitivity, and large detection range. J Lumin. 2023;257:119693. 10.1016/j.jlumin.2023.119693.10.1016/j.jlumin.2023.119693 ↗
79. Kadian S, Chaulagain N. Probe sonication-assisted rapid synthesis of highly fl uorescent sulfur quantum dots. Nanotechnology. 2023;34(30):1–9.10.1088/1361-6528/acd00a ↗
80. Du W, Liao L, Yang L, Qin A, Liang A. Aqueous synthesis of functionalized copper sulfide quantum dots as near-infrared luminescent probes for detection of Hg2+, Ag+ and Au3+. Sci Rep. 2017;7(11451):1–12.10.1038/s41598-017-10904-y ↗
81. Zhou J, Liu Y, Tang J, Tang W. Surface ligands engineering of semiconductor quantum dots for chemosensory and biological applications. Biochem Pharmacol. 2017;20(7):360–76.10.1016/j.mattod.2017.02.006 ↗
82. Baig N, Kammakakam I, Falath W, Kammakakam I. Nanomaterials: A review of synthesis methods, properties, recent progress, and challenges. Mater Adv. 2021;2(6):1821–71.10.1039/D0MA00807A ↗
83. Khayal A, Dawane V, Amin MA, Tirth V, Yadav VK, Algahtani A, et al. Advances in the methods for the synthesis of carbon dots and their emerging applications. Polym (Basel). 2021;13(18):1–31.10.3390/polym13183190 ↗
84. Gao P, Huang Z, Tan J, Lv G, Zhou L. Efficient conversion of elemental sulfur to robust ultrabright fluorescent sulfur quantum dots using sulfur-ethylenediamine precursor. ACS Sustain Chem Eng. 2022;10(14):4634–41.10.1021/acssuschemeng.2c00036 ↗
85. Liu J, Ba D, Chen Y, Wen S, Cheng G. Synthesis of 3-(2-quinolyl) chromones from ynones and quinoline N-oxides via tandem reactions under transition metal-and additive-free conditions. Chem Commun. 2020;56(29):4078–81.10.1039/C9CC09460A ↗
86. Wang Y, Hu A. Carbon quantum dots: Synthesis, properties and applications. J Mater Chem C. 2014;2(34):6921–39.10.1039/C4TC00988F ↗
87. Shen L, Chen X, Chen Y, Peng J, Abbas A, Wei J, et al. One-step hydrothermal synthesis of sulfur quantum dots for photoelectrochemical catalysis for dye degradation. J Electron Mater. 2022;51(6):3092–100. 10.1007/s11664-022-09528-4.10.1007/s11664-022-09528-4 ↗
88. Ayyıldız MF, Karaman DN, Kartoğlu B, Şaylan M, Chormey DS, Bakırdere S. A simple microwave-assisted synthesis of cobalt ferrite nanoparticles and its application for the determination of lead ions in rooibos (Aspalathus linearis) tea. Food Chem. 2023;429:136862.10.1016/j.foodchem.2023.136862 ↗
89. Ma F, Zhou Q, Yang M, Zhang J, Chen X. Microwave-assisted synthesis of sulfur quantum dots for detection of alkaline phosphatase activity. Nanomaterials. 2022;12(16):1–10.10.3390/nano12162787 ↗
90. Zhang H, Li Y, Lu H, Gan F. A ratiometric fluorescence and colorimetric dual-mode sensing platform based on sulfur quantum dots and carbon quantum dots for selective detection of Cu2+. Anal Bioanal Chem. 2022;414(7):2471–80. 10.1007/s00216-022-03888-w.10.1007/s00216-022-03888-w ↗
91. Shen L, Wang H, Liu S, Bai Z, Zhang S, Zhang X, et al. Assembling of sulfur quantum dots in fission of sublimed sulfur. J Am Chem Soc. 2018;140(25):7878–84.10.1021/jacs.8b02792 ↗
92. Chen H, Zhu X, Huang H, Wang H, Wang T, Zhao R, et al. Sulfur dots-graphene nanohybrid: A metal-free electrocatalyst for efficient N2-to-NH3 fixation under ambient conditions. Chem Commun. 2019;55(21):3152–5.10.1039/C9CC00461K ↗
93. Gao P, Zhong W, Li T, Liu W, Zhou L. Room temperature, ultrafast and one-step synthesis of highly fluorescent sulfur quantum dots probe and their logic gate operation. J Colloid Interface Sci. 2024;666:221–31.10.1016/j.jcis.2024.04.033 ↗
94. Lu H, Zhang H, Li Y, Gan F. Sensitive and selective determination of tetracycline in milk based on sulfur quantum dot probes. RSC Adv. 2021;11(37):22960–8.10.1039/D1RA03745E ↗
95. Qiao G, Liu L, Hao X, Zheng J, Liu W, Gao J, et al. Signal transduction from small particles: Sulfur nanodots featuring mercury sensing, cell entry mechanism and in vitro tracking performance. Chem Eng J. 2020;382:1–32. 10.1016/j.cej.2019.122907.10.1016/j.cej.2019.122907 ↗
96. Tan J, Deng P, Wang L, Bi X, Zhou Y, Wang Y, et al. Signal-on and selective detection of anti-tumor adjunctive drug zoledronic acid using fluorescent sulfur quantum dots. Dye Pigment. 2022;205:110520. 10.1016/j.dyepig.2022.110520.10.1016/j.dyepig.2022.110520 ↗
97. Jiang X-X, Li P, Zhao M-Y, Chen R-C, Wang Z-G, Xie J-X, et al. In situ encapsulation of SQDs by zinc ion-induced ZIF-8 growth strategy for fluorescent and colorimetric dual-signal detection of alkaline phosphatase. Anal Chim Acta. 2022;1221:340103.10.1016/j.aca.2022.340103 ↗
98. Karimi H, Rajabi HR, Kavoshi L. Application of decorated magnetic nanophotocatalysts for efficient photodegradation of organic dye: A comparison study on photocatalytic activity of magnetic zinc sulfide and graphene quantum dots. J Photochem Photobiol A Chem. 2020;397:112534. 10.1016/j.jphotochem.2020.112534.10.1016/j.jphotochem.2020.112534 ↗
99. Sheik Mydeen S, Raj Kumar R, Sivakumar R, Sambathkumar S, Kottaisamy M, Vasantha VS. Graphene quantum dots/ZnO nanocomposite: Synthesis, characterization, mechanistic investigations of photocatalytic and antibacterial activities. Chem Phys Lett. 2020;761:138009. 10.1016/j.cplett.2020.138009.10.1016/j.cplett.2020.138009 ↗
100. Borah DJ, Mostako ATT, Malakar A. Tailoring the crystalline phase and size of the MoO3 quantum dots via sonication induced modified top-down method. J Alloy Compd. 2022;891:161870. 10.1016/j.jallcom.2021.161870.10.1016/j.jallcom.2021.161870 ↗