journal article·2025-04-09Open access

Principles, applications and future prospects in photodegradation systems

Walied A. A. Mohamed, Aiyeshah Alhodaib, Hanan A. Mousa, Hala T. Handal, Hoda R. Galal, Hala H. Abd El-Gawad, Badr A. Elsayed, Ammar A. Labib, Mohamed S. A. Abdel-Mottaleb

Nanotechnology Reviews· Volume 14· Issue 1

Abstract

Abstract Photocatalytic materials have emerged as pivotal in addressing global challenges such as environmental pollution, energy scarcity, and industrial sustainability. This review delves into the principles, mechanisms, and applications of photocatalytic systems, emphasizing their roles in photodegradation and renewable energy production. United Nations (UN) specified a guideline for sustainable development strategies. UN determined 17 goals of sustainable development and the services of photocatalytic materials underwent 4 of these goals to reflect the distinguishable interest and importance of different photocatalytic materials in many fields for various purposes. Advances in material design, nanotechnology, and system integration have significantly advanced this field, aligning it with sustainable development goals. Key materials like TiO 2 , ZnO, g-C 3 N 4 , and quantum dots are highlighted for their unique properties and enhanced photocatalytic activity through modifications such as doping, heterostructure formation, and biopolymer-supported photocatalysts. Practical applications in wastewater treatment, hydrogen production, air purification, and carbon dioxide reduction are comprehensively analyzed, with case studies demonstrating the successful photodegradation of industrial pollutants. The review also explores the integration of photocatalysis with renewable energy sources, addressing challenges like charge carrier recombination and photocatalyst stability. Interdisciplinary approaches, including computational modeling and machine learning, are discussed for designing next-generation photocatalysts, aligning innovations with global sustainability initiatives.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Photochemistry and Nanomaterials Lab, Inorganic Chemistry Department, Advanced Materials Technology and Mineral Resources Institute, National Research Centre , P.O. Box 12622 , Cairo , Egypt

Department of Physics, College of Science, Qassim University , Buraydah , 51452 , Saudi Arabia

Department of Chemistry, Faculty of Science, King Khalid University , Abha , 61413 , Saudi Arabia

Inorganic & Analytical Chemistry, Chemistry Department, Faculty of Science, Al-Azhar University , 11884 , Cairo , Egypt

Nano-Photochemistry, Solar Chemistry, Computational Chemistry Labs, Department of Chemistry, Faculty of Science, Ain Shams University, Abbassia , 11566 , Cairo , Egypt

References (100+)

Show source-provided references
1. Navidpour AH, Abbasi S, Li D, Mojiri A, Zhou JL. Investigation of advanced oxidation process in the presence of TiO2 semiconductor as photocatalyst: Property, principle, kinetic analysis, and photocatalytic activity. Catalysts. 2023;13:1–29. 10.3390/catal13020232.10.3390/catal13020232 ↗
2. Serpone N. Heterogeneous photocatalysis and prospects of TiO2-based photocatalytic DeNOxing the atmospheric environment. Catalysts. 2018;8:553.10.3390/catal8110553 ↗
3. Hassaan MA, El-Nemr MA, Elkatory MR, Ragab S, Niculescu V-C, El Nemr A. Principles of photocatalysts and their different applications: a review. Top Curr Chem. 2023;381:31. 10.1007/s41061-023-00444-7.10.1007/s41061-023-00444-7 ↗
4. Jabbar ZH, Graimed BH, Ammar SH, Sabit DA, Najim AA, Radeef AY, et al. The latest progress in the design and application of semiconductor photocatalysis systems for degradation of environmental pollutants in wastewater: Mechanism insight and theoretical calculations. Mater Sci Semicond Process. 2024;173:108153. 10.1016/j.mssp.2024.108153.10.1016/j.mssp.2024.108153 ↗
5. Mohapatra L, Yoo SH. Superwetting materials as catalysts in photocatalysis: State-of-the-Art review. Chem Eng J. 2024;481:148537. 10.1016/j.cej.2024.148537.10.1016/j.cej.2024.148537 ↗
6. Maeda K. Photocatalytic water splitting using semiconductor particles: History and recent developments. J Photochem Photobiol C: Photochem Rev. 2011;12:237–68. 10.1016/j.jphotochemrev.2011.07.001.10.1016/j.jphotochemrev.2011.07.001 ↗
7. Yang H, Yang B, Chen W, Yang J. Preparation and photocatalytic activities of TiO2-based composite catalysts. Catalysts. 2022;12:1263. 10.3390/catal12101263.10.3390/catal12101263 ↗
8. Chen S, Qi Y, Li C, Domen K, Zhang F. Surface strategies for particulate photocatalysts toward artificial photosynthesis. Joule. 2018;2:2260–88. 10.1016/j.joule.2018.07.030.10.1016/j.joule.2018.07.030 ↗
9. Li Z, Wen C, Li D, Fang Z, Lin Z, Liu D, et al. Insights into nitrogen-doped BiOBr with oxygen vacancy and carbon quantum dots photocatalysts for the degradation of sulfonamide antibiotics: Actions to promote exciton dissociation and carrier migration. Chem Eng J. 2024;492:152449. 10.1016/j.cej.2024.152449.10.1016/j.cej.2024.152449 ↗
10. Han Q, Wu Z, Zhou Y, Lei Y, Nie B, Yang L, et al. Accelerating carrier separation to boost the photocatalytic CO2 reduction performance of ternary heterojunction Ag–Ti3C2Tx/ZnO catalysts††Electronic supplementary information (ESI) available. RSC Adv. 2024;14:13719–33. 10.1039/d4ra01985g.10.1039/D4RA01985G ↗
11. Zhou R, Zhao J, Chen L, Zhang J, Fan Z, Peng C, et al. Carbonaceous structures as electronic bridges to enhance charge migration and radical reactions in composite photocatalysts: An effective way to achieve efficient mineralization of pollutants. Colloids Surf A: Physicochem Eng Asp. 2024;702:135015. 10.1016/j.colsurfa.2024.135015.10.1016/j.colsurfa.2024.135015 ↗
12. Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode. Nature. 1972;238:37.10.1038/238037a0 ↗
13. Kamat PV, Sivula K. Celebrating 50 years of photocatalytic hydrogen generation. ACS Energy Lett. 2022;7:3149–50. 10.1021/acsenergylett.2c01889.10.1021/acsenergylett.2c01889 ↗
14. Li X, Chen Y, Tao Y, Shen L, Xu Z, Bian Z, et al. Challenges of photocatalysis and their coping strategies. Chem Catal. 2022;2:1315–45. 10.1016/j.checat.2022.04.007.10.1016/j.checat.2022.04.007 ↗
15. Kang X, Liu S, Dai Z, He Y, Song X, Tan Z. Titanium dioxide: From engineering to applications. Catalysts. 2019;9:191. 10.3390/catal9020191.10.3390/catal9020191 ↗
16. Goodarzi N, Ashrafi-Peyman Z, Khani E, Moshfegh AZ. Recent progress on semiconductor heterogeneous photocatalysts in clean energy production and environmental Remediation. Catalysts. 2023;13:1102. 10.3390/catal13071102.10.3390/catal13071102 ↗
17. Ahmadpour N, Nowrouzi M, Madadi Avargani V, Sayadi MH, Zendehboudi S. Design and optimization of TiO2-based photocatalysts for efficient removal of pharmaceutical pollutants in water: Recent developments and challenges. J Water Process Eng. 2024;57:104597. 10.1016/j.jwpe.2023.104597.10.1016/j.jwpe.2023.104597 ↗
18. Wang Q, Yang X, Jing Z, Liu H, Tang P, Zhu H, et al. Recent advances in one-dimensional alkali-metal hexatitanate photocatalysts for environmental remediation and solar fuel production. J Mater Sci Technol. 2024;202:201–39. 10.1016/j.jmst.2024.02.071.10.1016/j.jmst.2024.02.071 ↗
19. Lee D-E, Mameda N, Devthade V, Jo W-K, Tonda S. A hierarchical 3D hybrid CoAl-layered double hydroxide/TiO2/Ti3C2 MXene S-scheme photocatalyst with 2D/0D/2D contact interfaces for sustainable pollutant degradation. Appl Surf Sci. 2024;649:159178. 10.1016/j.apsusc.2023.159178.10.1016/j.apsusc.2023.159178 ↗
20. Jabbar ZH, Esmail Ebrahim S. Recent advances in nano-semiconductors photocatalysis for degrading organic contaminants and microbial disinfection in wastewater: A comprehensive review. Environ Nanotechnol Monit Manag. 2022;17:100666. 10.1016/j.enmm.2022.100666.10.1016/j.enmm.2022.100666 ↗
21. Balu S, Ganapathy D, Arya S, Atchudan R, Sundramoorthy AK. Advanced photocatalytic materials based degradation of micropollutants and their use in hydrogen production – a review. RSC Adv. 2024;14:14392–424. 10.1039/D4RA01307G.10.1039/D4RA01307G ↗
22. Torlaema TAM, Jaafar NF, Mutalib AAA, Lahuri AH, Wahyuni ET. Potential of polymer as dopant in photocatalyst to boost degradation of pollutants: A mini review. Chem Eng Res Des. 2024;208:863–80. 10.1016/j.cherd.2024.07.046.10.1016/j.cherd.2024.07.046 ↗
23. Beil SB, Bonnet S, Casadevall C, Detz RJ, Eisenreich F, Glover SD, et al. Challenges and future perspectives in photocatalysis: conclusions from an interdisciplinary workshop. JACS Au. 2024;4:2746–66. 10.1021/jacsau.4c00527.10.1021/jacsau.4c00527 ↗
24. Ali H, Masar M, Yasir M, Machovsky M, Monteiro OC, Kuritka I. Current trends in environmental and energy photocatalysis and ISO standardization. J Environ Chem Eng. 2023;11:111541. 10.1016/j.jece.2023.111541.10.1016/j.jece.2023.111541 ↗
25. Byrne C, Subramanian G, Pillai SC. Recent advances in photocatalysis for environmental applications. J Environ Chem Eng. 2018;6:3531–55. 10.1016/j.jece.2017.07.080.10.1016/j.jece.2017.07.080 ↗
26. Chakravorty A, Roy S. A review of photocatalysis, basic principles, processes, and materials. Sustain Chem Environ. 2024;8:100155. 10.1016/j.scenv.2024.100155.10.1016/j.scenv.2024.100155 ↗
27. Mohamadpour F, Amani AM. Photocatalytic systems: reactions, mechanism, and applications. RSC Adv. 2024;14:20609–45. 10.1039/D4RA03259D.10.1039/D4RA03259D ↗
28. Iervolino G. Visible light active photocatalysts for the removal of inorganic emerging contaminants. Visible light active structured photocatalysts for the removal of emerging contaminants. Amsterdam: Elsevier; 2020. p. 141–62.10.1016/B978-0-12-818334-2.00006-7 ↗
29. Chen F, Yang Y, Chen X. A first-principles and machine learning study on design of graphitic carbon nitride-based single-atom photocatalysts. ACS Appl Nano Mater. 2024;7:11862–70. 10.1021/acsanm.4c01412.10.1021/acsanm.4c01412 ↗
30. Wang S, Wang S, Yang X, Lv Z, Chai H, Meng L, et al. Improved performance of quantum dot solar cells by type-II InAs/GaAsSb structure with moderate Sb composition. Heliyon. 2023;9:e20005. 10.1016/j.heliyon.2023.e20005.10.1016/j.heliyon.2023.e20005 ↗
31. Kokal RK, Deepa M, Kalluri A, Singh S, Macwan I, Patra PK, et al. Solar cells with PbS quantum dot sensitized TiO2-multiwalled carbon nanotube composites, sulfide-titania gel and tin sulfide coated C-fabric. Phys Chem Chem Phys. 2017;19:26330–45. 10.1039/c7cp05582j.10.1039/C7CP05582J ↗
32. Zhang Z, Yi G, Li P, Zhang X, Fan H, Zhang Y, et al. A minireview on doped carbon dots for photocatalytic and electrocatalytic applications. Nanoscale. 2020;12:13899–906. 10.1039/d0nr03163a.10.1039/D0NR03163A ↗
33. Nobel Prize in Chemistry 2023 Rewards the Discovery and Development of Quantum Dots. News Digital Object Group. Hoboken, New Jersey: Wiley; 2023. 10.1002/msid.0050049.
34. Manna L, Odom TW. Profile of Alexei I. Ekimov, Louis E. Brus, and Moungi G. Bawendi: 2023 Nobel laureates in chemistry. Proc Natl Acad Sci U S A. 2024;121:e2410357121. 10.1073/pnas.2410357121.10.1073/pnas.2410357121 ↗
35. Kuspanov Z, Bakbolat B, Baimenov A, Issadykov A, Yeleuov M, Daulbayev C. Photocatalysts for a sustainable future: Innovations in large-scale environmental and energy applications. Sci Total Environ. 2023;885:163914. 10.1016/j.scitotenv.2023.163914.10.1016/j.scitotenv.2023.163914 ↗
36. Su T, Zhu X. Advanced photocatalytic materials for environmental and energy applications. Materials (Basel). 2023;16:1–4. 10.3390/ma16227197.10.3390/ma16227197 ↗
37. Wang Q, Wang X, Zhang F. Photocatalysis in energy application: What’s next? Energy. 2023;1:100016. 10.1016/j.nxener.2023.100016.10.1016/j.nxener.2023.100016 ↗
38. Ahuja T, Brighu U, Saxena K. Recent advances in photocatalytic materials and their applications for treatment of wastewater: A review. J Water Process Eng. 2023;53:103759. 10.1016/j.jwpe.2023.103759.10.1016/j.jwpe.2023.103759 ↗
39. Antonietti M, Pelicano CM. Translating laboratory success into the large-scale implementation of photocatalytic overall water splitting. Front Sci. 2024;2:1–4. 10.3389/fsci.2024.1507745.10.3389/fsci.2024.1507745 ↗
40. Abhishek B, Jayarama A, Rao AS, Nagarkar SS, Dutta A, Duttagupta SP, et al. Challenges in photocatalytic hydrogen evolution: Importance of photocatalysts and photocatalytic reactors. Int J Hydrogen Energy. 2024;81:1442–66. 10.1016/j.ijhydene.2024.07.262.10.1016/j.ijhydene.2024.07.262 ↗
41. Rajbongshi BM. 7 - Photocatalyst: mechanism, challenges, and strategy for organic contaminant degradation. In: Mustansar Hussain C, Mishra AK, editors. Handbook of smart photocatalytic materials. Amsterdam: Elsevier; 2020. p. 127–49.10.1016/B978-0-12-819049-4.00011-8 ↗
42. Variar AG, Ramyashree MS, Ail VU, Sudhakar K, Tahir M. Influence of various operational parameters in enhancing photocatalytic reduction efficiency of carbon dioxide in a photoreactor: A review. J Ind Eng Chem. 2021;99:19–47. 10.1016/j.jiec.2021.04.017.10.1016/j.jiec.2021.04.017 ↗
43. Uekert T, Kasap H, Reisner E. Photoreforming of nonrecyclable plastic waste over a carbon nitride/nickel phosphide catalyst. J Am Chem Soc. 2019;141:15201–10. 10.1021/jacs.9b06872.10.1021/jacs.9b06872 ↗
44. Ighalo JO, Smith ML, Mayyahi AA, Amama PB. MXenes in photocatalytic NOx abatement: Current innovations, opportunities, and challenges. Appl Catal B: Environ Energy. 2024;358:124352. 10.1016/j.apcatb.2024.124352.10.1016/j.apcatb.2024.124352 ↗
45. Abdelfattah I, El-Shamy AM. Review on the escalating imperative of zero liquid discharge (ZLD) technology for sustainable water management and environmental resilience. J Environ Manage. 2024;351:119614. 10.1016/j.jenvman.2023.119614.10.1016/j.jenvman.2023.119614 ↗
46. Bigham A, Zarepour A, Safarkhani M, Huh Y, Khosravi A, Rabiee N, et al. Inspired by nature: Bioinspired and biomimetic photocatalysts for biomedical applications. Nano Mater Sci. 2024. 10.1016/j.nanoms.2024.02.006.10.1016/j.nanoms.2024.02.006 ↗
47. Phongamwong T, Chareonpanich M, Limtrakul J. Role of chlorophyll in Spirulina on photocatalytic activity of CO2 reduction under visible light over modified N-doped TiO2 photocatalysts. Appl Catal B: Environ. 2015;168–169:114–24. 10.1016/j.apcatb.2014.12.022.10.1016/j.apcatb.2014.12.022 ↗
48. Zhou H, Yan R, Zhang D, Fan T. Challenges and perspectives in designing artificial photosynthetic systems. Chemistry. 2016;22:9870–85. 10.1002/chem.201600289.10.1002/chem.201600289 ↗
49. Soni R, Thakur A, Ghotekar S, Lokhande PE, Aepuru R, Sathish M, et al. Sparkling jewels of innovation: Revolutionizing environmental solutions with spinel-infused advanced nanomaterials, unveiling today’s insights, and illuminating tomorrow’s frontiers. J Alloy Compd. 2024;993:174542. 10.1016/j.jallcom.2024.174542.10.1016/j.jallcom.2024.174542 ↗
50. Wu N. Plasmonic metal-semiconductor photocatalysts and photoelectrochemical cells: a review. Nanoscale. 2018;10:2679–96. 10.1039/c7nr08487k.10.1039/C7NR08487K ↗
51. Dai Y, Yao J, Song Y, Wang S, Yuan Y. Enhanced adsorption and degradation of phenolic pollutants in water by carbon nanotube modified laccase-carrying electrospun fibrous membranes. Environ Sci: Nano. 2016;3:857–68. 10.1039/c6en00148c.10.1039/C6EN00148C ↗
52. Friedmann D. A general overview of heterogeneous photocatalysis as a remediation technology for wastewaters containing pharmaceutical compounds. Water. 2022;14:1–31. 10.3390/w14213588.10.3390/w14213588 ↗
53. Rasouli J, Zandifar A, Rasouli K, Sabbaghi S, Esmaeilzadeh F, Shah M, et al. High-efficiency ternary CeO2/WO3/AC photocatalyst supported by biomass waste-derived activated carbon for efficient doxycycline photodegradation: Optimization of synthesis conditions and operational parameters. Mater Res Bull. 2024;178:112874. 10.1016/j.materresbull.2024.112874.10.1016/j.materresbull.2024.112874 ↗
54. Mahmood M, Chaudhary K, Shahid M, Shakir I, Agboola PO, Aadil M. Fabrication of MoO3 Nanowires/MXene@CC hybrid as highly conductive and flexible electrode for next-generation supercapacitors applications. Ceram Int. 2022;48:19314–23. 10.1016/j.ceramint.2022.03.226.10.1016/j.ceramint.2022.03.226 ↗
55. Bukhari MA, Bukhari SMZS, Khalid MY, Arif ZU. Advancing photocatalytic activity through a green route: Bismuth ferrite@molybdenum trioxide heterostructure for sustainable water treatment. J Mol Struct. 2024;1315:138811. 10.1016/j.molstruc.2024.138811.10.1016/j.molstruc.2024.138811 ↗
56. Serpone N, Emeline AV, Ryabchuk VK, Kuznetsov VN, Artem’ev YM, Horikoshi S. Why do hydrogen and oxygen yields from semiconductor-based photocatalyzed water splitting remain disappointingly low? Intrinsic and extrinsic factors impacting surface redox reactions. ACS Energy Lett. 2016;1:931–48. 10.1021/acsenergylett.6b00391.10.1021/acsenergylett.6b00391 ↗
57. Nautiyal R, Tavar D, Suryavanshi U, Singh G, Singh A, Vinu A, et al. Advanced nanomaterials for highly efficient CO2 photoreduction and photocatalytic hydrogen evolution. Sci Technol Adv Mater. 2022;23:866–94. 10.1080/14686996.2022.2149036.10.1080/14686996.2022.2149036 ↗
58. Wang Z, Lin Z, Shen S, Zhong W, Cao S. Advances in designing heterojunction photocatalytic materials. Chin J Catal. 2021;42:710–30. 10.1016/s1872-2067(20)63698-1.10.1016/S1872-2067(20)63698-1 ↗
59. Sohail M, Rauf S, Irfan M, Hayat A, Alghamdi MM, El-Zahhar AA, et al. Recent developments, advances and strategies in heterogeneous photocatalysts for water splitting. Nanoscale Adv. 2024;6:1286–330. 10.1039/D3NA00442B.10.1039/D3NA00442B ↗
60. Yang J, Zeng X, Tebyetekerwa M, Wang Z, Bie C, Sun X, et al. Engineering 2D photocatalysts for solar hydrogen peroxide production. Adv Energy Mater. 2024;14:2400740. 10.1002/aenm.202400740.10.1002/aenm.202400740 ↗
61. Karunarathne S, Malaarachchi CK, Abdelkader AM, Kamali AR. Advances in bifunctional electrocatalysts towards high-performing Li-air batteries. J Power Sources. 2024;607:234553. 10.1016/j.jpowsour.2024.234553.10.1016/j.jpowsour.2024.234553 ↗
62. Sofia DR, Hanam ES, Sunardi S, Sumiarsa D, Joni IM. Hydroxyl radical-based advanced oxidation processes of red reactive dyes by ultrafine bubbles method. Water. 2024;16:1–30. 10.3390/w16121678.10.3390/w16121678 ↗
63. Roslan NN, Lau HL, Suhaimi NAA, Shahri NNM, Verinda SB, Nur M, et al. Recent advances in advanced oxidation processes for degrading pharmaceuticals in wastewater – A review. Catalysts. 2024;14:1–25. 10.3390/catal14030189.10.3390/catal14030189 ↗
64. Xiao J, Guo S, Wang D, An Q. Fenton-like reaction: recent advances and new trends. Chem – Eur J. 2024;30:e202304337. 10.1002/chem.202304337.10.1002/chem.202304337 ↗
65. Rueda-Márquez JJ, Levchuk I, Manzano M, Sillanpää M. Toxicity reduction of industrial and municipal wastewater by advanced oxidation processes (photo-fenton, UVC/H2O2, electro-fenton and galvanic fenton): a review. Catalysts. 2020;10:1–28. 10.3390/catal10060612.10.3390/catal10060612 ↗
66. Velasquez M, Santander IP, Contreras DR, Yanez J, Zaror C, Salazar RA, et al. Oxidative degradation of sulfathiazole by Fenton and photo-Fenton reactions. J Environ Sci Health A Tox Hazard Subst Environ Eng. 2014;49:661–70. 10.1080/10934529.2014.865447.10.1080/10934529.2014.865447 ↗
67. Coleman RE, Boulton RB, Stuchebrukhov AA. Chain reaction of fenton autoxidation of tartaric acid: critical behavior at low pH. J Phys Chem B. 2023;127:4300–8. 10.1021/acs.jpcb.3c02172.10.1021/acs.jpcb.3c02172 ↗
68. Timoshnikov VA, Kobzeva TV, Polyakov NE, Kontoghiorghes GJ. Inhibition of Fe2+ - and Fe3+ - induced hydroxyl radical production by the iron-chelating drug deferiprone. Free Radic Biol Med. 2015;78:118–22. 10.1016/j.freeradbiomed.2014.10.513.10.1016/j.freeradbiomed.2014.10.513 ↗
69. Jiang Q, Ji Y, Zheng T, Li X, Xia C. The nexus of innovation: electrochemically synthesizing H2O2 and its integration with downstream reactions. ACS Mater Au. 2024;4:133–47. 10.1021/acsmaterialsau.3c00070.10.1021/acsmaterialsau.3c00070 ↗
70. Lv X, Ma Y, Li Y, Yang Q. Heterogeneous fenton-like catalytic degradation of 2,4-dichlorophenoxyacetic acid by nano-scale zero-valent iron assembled on magnetite nanoparticles. Water. 2020;12:481–9. 10.3390/w12102909.10.3390/w12102909 ↗
71. Khan ZUH, Gul NS, Sabahat S, Sun J, Tahir K, Shah NS, et al. Removal of organic pollutants through hydroxyl radical-based advanced oxidation processes. Ecotoxicol Environ Saf. 2023;267:115564. 10.1016/j.ecoenv.2023.115564.10.1016/j.ecoenv.2023.115564 ↗
72. Wu M, Tao Y, Liu Y, Hou S, Xiao T, Fu Q, et al. Fe-N-coordinated graphene-like honeycomb porous carbon as an extremely effective catalyst for catalytic oxidation. Sep Purif Technol. 2024;354(6):129225. 10.1016/j.seppur.2024.129225.10.1016/j.seppur.2024.129225 ↗
73. Serpone N, Emeline AV. Semiconductor photocatalysis - past, present, and future outlook. J Phys Chem Lett. 2012;3:673–7. 10.1021/jz300071j.10.1021/jz300071j ↗
74. Kumar R, Chaudhary MP, Al-Ahmed A, Bhattacharyya S, von Gratowski S, Iqbal J. Inamuddin, photo-to-chemical energy transformation: Pioneering photocatalysts, surface and interface engineering. Mater Res Bull. 2024;180:113046. 10.1016/j.materresbull.2024.113046.10.1016/j.materresbull.2024.113046 ↗
75. Liu Y, Zeng X, Easton CD, Li Q, Xia Y, Yin Y, et al. An in situ assembled WO3-TiO2 vertical heterojunction for enhanced Z-scheme photocatalytic activity. Nanoscale. 2020;12:8775–84. 10.1039/d0nr01611j.10.1039/D0NR01611J ↗
76. Pirhashemi M, Habibi-Yangjeh A. Z-scheme-based heterostructure photocatalysts for organic pollutant degradation. Heterostructured photocatalysts for solar energy conversion. Amsterdam: Elsevier; 2021. p. 177–217.10.1016/B978-0-12-820072-8.00005-6 ↗
77. Xu Y-F, Wu W-Q, Rao H-S, Chen H-Y, Kuang D-B, Su C-Y. CdS/CdSe co-sensitized TiO2 nanowire-coated hollow Spheres exceeding 6% photovoltaic performance. Nano Energy. 2015;11:621–30. 10.1016/j.nanoen.2014.11.045.10.1016/j.nanoen.2014.11.045 ↗
78. Zhu Y, Egap E. Light-mediated polymerization induced by semiconducting nanomaterials: state-of-the-art and future perspectives. ACS Polym Au. 2021;1:76–99. 10.1021/acspolymersau.1c00014.10.1021/acspolymersau.1c00014 ↗
79. Liao P, Keith JA, Carter EA. Water oxidation on pure and doped hematite (0001) surfaces: prediction of Co and Ni as effective dopants for electrocatalysis. J Am Chem Soc. 2012;134:13296–309. 10.1021/ja301567f.10.1021/ja301567f ↗
80. Atif S, Shehzad A, Abdelkader L, Li X, Dong Q, Wang C. 1 - Photochemistry: from basic principles to photocatalysis. In: Wang C, Duan Y, Wang L, Zhu Q, editors. Full-spectrum responsive photocatalytic materials. Cambridge, UK: Woodhead Publishing; 2024. p. 1–24.10.1016/B978-0-443-13631-3.00001-X ↗
81. Nadikatla SK, Chintada VB, Gurugubelli TR, Koutavarapu R. Review of recent developments in the fabrication of ZnO/CdS heterostructure photocatalysts for degradation of organic pollutants and hydrogen production. Molecules. 2023;28:4277. 10.3390/molecules28114277.10.3390/molecules28114277 ↗
82. Rogolino A, Savateev O. Photochargeable semiconductors: in “Dark Photocatalysis” and beyond. Adv Funct Mater. 2023;33:2305028. 10.1002/adfm.202305028.10.1002/adfm.202305028 ↗
83. Ben-Shahar Y, Stone D, Banin U. Rich landscape of colloidal semiconductor-metal hybrid nanostructures: synthesis, synergetic characteristics, and emerging applications. Chem Rev. 2023;123:3790–851. 10.1021/acs.chemrev.2c00770.10.1021/acs.chemrev.2c00770 ↗
84. Zhu S, Wang D. Photocatalysis: Basic principles, diverse forms of implementations and emerging scientific opportunities. Adv Energy Mater. 2017;7:1700841. 10.1002/aenm.201700841.10.1002/aenm.201700841 ↗
85. Kou J, Lu C, Wang J, Chen Y, Xu Z, Varma RS. Selectivity enhancement in heterogeneous photocatalytic transformations. Chem Rev. 2017;117:1445–514. 10.1021/acs.chemrev.6b00396.10.1021/acs.chemrev.6b00396 ↗
86. Yang X, Wang Y, Li CM, Wang D. Mechanisms of water oxidation on heterogeneous catalyst surfaces. Nano Res. 2021;14:3446–57. 10.1007/s12274-021-3607-5.10.1007/s12274-021-3607-5 ↗
87. Mei B, Han K, Mul G. Driving surface redox reactions in heterogeneous photocatalysis: The active state of illuminated semiconductor-supported nanoparticles during overall water-splitting. ACS Catal. 2018;8:9154–64. 10.1021/acscatal.8b02215.10.1021/acscatal.8b02215 ↗
88. Zhang Q, Wang Y, Jia Y, Yan W, Li Q, Zhou J, et al. Engineering the electronic structure towards visible lights photocatalysis of CaTiO3 perovskites by cation (La/Ce)-anion (N/S) co-doping: A first-principles study. Molecules. 2023;28:1–21. 10.3390/molecules28207134.10.3390/molecules28207134 ↗
89. Santos Correa S, Schultz J, Lauersen KJ, Soares Rosado A. Natural carbon fixation and advances in synthetic engineering for redesigning and creating new fixation pathways. J Adv Res. 2023;47:75–92. 10.1016/j.jare.2022.07.011.10.1016/j.jare.2022.07.011 ↗
90. Pavel M, Anastasescu C, State R-N, Vasile A, Papa F, Balint I. Photocatalytic degradation of organic and inorganic pollutants to harmless end products: assessment of practical application potential for water and air cleaning. Catalysts. 2023;13:1–45. 10.3390/catal13020380.10.3390/catal13020380 ↗
91. Hu W, Yang J. Two-dimensional van der Waals heterojunctions for functional materials and devices. J Mater Chem C. 2017;5:12289–97. 10.1039/c7tc04697a.10.1039/C7TC04697A ↗
92. Zheng Z, Zu X, Zhang Y, Zhou W. Rational design of type-II nano-heterojunctions for nanoscale optoelectronics. Mater Today Phys. 2020;15:100262. 10.1016/j.mtphys.2020.100262.10.1016/j.mtphys.2020.100262 ↗
93. Zhong X, Li Y, Wu H, Xie R. Recent progress in BiVO4-based heterojunction nanomaterials for photocatalytic applications. Mater Sci Eng: B. 2023;289:116278. 10.1016/j.mseb.2023.116278.10.1016/j.mseb.2023.116278 ↗
94. Kumar A, Khosla A, Kumar Sharma S, Dhiman P, Sharma G, Gnanasekaran L, et al. A review on S-scheme and dual S-scheme heterojunctions for photocatalytic hydrogen evolution, water detoxification and CO2 reduction. Fuel. 2023;333:126267. 10.1016/j.fuel.2022.126267.10.1016/j.fuel.2022.126267 ↗
95. Negi A, Ringwal S, Pandey M, Taha Yassin M. Plant-mediated Z-scheme ZnO/TiO2-NCs for antibacterial potential and dye degradation: experimental and DFT study. Sci Rep. 2024;14:7955. 10.1038/s41598-024-57392-5.10.1038/s41598-024-57392-5 ↗
96. Gui X, Lu Y, Wang Q, Cai M, Sun S. Application of quantum dots for photocatalytic hydrogen evolution reaction. Appl Sci. 2024;14:5333. 10.3390/app14125333.10.3390/app14125333 ↗
97. Rana F, Manolatou C, Ram RJ. Microring resonator based widely tunable semiconductor lasers. Integrated Photonics Research, OSA. Canada: OPG; 2002.10.1364/IPR.2002.IFH3 ↗
98. Bonef B, Shah RD, Mukherjee K. Fast diffusion and segregation along threading dislocations in semiconductor heterostructures. Nano Lett. 2019;19:1428–36. 10.1021/acs.nanolett.8b03734.10.1021/acs.nanolett.8b03734 ↗
99. Zhu Y, Hudait MK. Low-power tunnel field effect transistors using mixed As and Sb based heterostructures, nano Online. Berlin, Germany: De Gruyter; 2016.10.1515/nano.0034.00063 ↗
100. Nakamura K, Nagamura N, Ueno K, Taniguchi T, Watanabe K, Nagashio K. All 2D heterostructure tunnel field-effect transistors: impact of band alignment and heterointerface quality. ACS Appl Mater Interfaces. 2020;12:51598–606. 10.1021/acsami.0c13233.10.1021/acsami.0c13233 ↗