Controlling point defect populations in AlGaN deep UV LEDs
Source abstract
Abstract
Abstract Point defects are known to degrade LED performance by lowering efficiencies, maximum output power and device lifetimes. Here we show that growth temperature is a key variable, affecting both point defect concentrations and distributions. Cathodoluminescence and electron beam induced current measurements elucidate the role these defects play in carrier recombination within the wells. Combining such measurements with atomic force microscopy allows us to identify the growth mechanisms at play and help explain the point defect distributions observed. We find that in all cases, the presence of threading dislocations with a screw component LED to the formation of spiral hillocks. Desorption of gallium along ridges and wide atomic terraces lead to blue-shifted quantum well emission energies but also impacted point defect populations. As growth temperatures were increased, dislocation mediated gettering counteracts a rising population of point defects. This restricts their impact below 1060 ∘ C, above which, performance regresses and point defects dominate.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: GaN-based semiconductor devices and materials · Semiconductor Quantum Structures and Devices · Chemical and Physical Properties of Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Gatan, Inc.
SUPA, University of Strathclyde
Technische Universität Berlin
University of Cambridge
Ferdinand-Braun-Institut
Funding
UK Engineering and Physical Sciences Research Council · German Federal Ministry of Education and Research
References (57)
Show source-provided references
1. Skin tolerant inactivation of multiresistant pathogens using far-UVC LEDs10.1038/s41598-021-94070-2 ↗
2. Ultraviolet communications: potential and state-of-the-art10.1109/MCOM.2008.4511651 ↗
3. The emergence and prospects of deep-ultraviolet light-emitting diode technologies10.1038/s41566-019-0359-9 ↗
4. The 2020 UV emitter roadmap10.1088/1361-6463/aba64c ↗
5. Optical light polarization and light extraction efficiency of AlGaN-based LEDs emitting between 264 and 220 nm10.7567/1347-4065/ab0d09 ↗
6. High internal quantum efficiency in AlGaN multiple quantum wells grown on bulk AlN substrates10.1063/1.4917540 ↗
7. Roles of carbon impurities and intrinsic nonradiative recombination centers on the carrier recombination processes of GaN crystals10.7567/1882-0786/ab5adc ↗
8. Degradation of AlGaN-based UV-C SQW LEDs analyzed by means of capacitance deep-level transient spectroscopy and numerical simulations10.1063/5.0144783 ↗
9. Investigation of degradation dynamics of 265 nm LEDs assisted by EL measurements and numerical simulations10.1088/1361-6641/ad54e9 ↗
10. Modeling the electrical degradation of AlGaN-based UV-C LEDs by combined deep-level optical spectroscopy and TCAD simulations10.1063/5.0144721 ↗
11. Imaging nonradiative point defects buried in quantum wells using cathodoluminescence10.1021/acs.nanolett.1c01295 ↗
12. Fermi level control of compensating point defects during metalorganic chemical vapor deposition growth of Si-doped AlGaN10.1063/1.4903058 ↗
13. Impacts of Si-doping and resultant cation vacancy formation on the luminescence dynamics for the near-band-edge emission of Al0.6Ga0.4N films grown on AlN templates by metalorganic vapor phase epitaxy10.1063/1.4807906 ↗
14. GaN buffer growth temperature and efficiency of InGaN/GaN quantum wells: the critical role of nitrogen vacancies at the GaN surface10.1063/5.0040326 ↗
15. Controlling the morphology transition between step-flow growth and step-bunching growth10.1016/j.jcrysgro.2017.09.007 ↗
16. Novel approach to simulation of group-III nitrides growth by MOVPE10.1557/S1092578300000600 ↗
17. Analysis of point defects in AlN epilayers by cathodoluminescence spectroscopy10.1063/1.3154518 ↗
18. A study of parasitic reactions between NH3 and TMGa or TMAI10.1007/BF02666736 ↗
19. Point defect reduction in MOCVD (Al)GaN by chemical potential control and a comprehensive model of C incorporation in GaN10.1063/1.5002682 ↗
20. Oxygen and silicon point defects in Al 0.65 Ga 0.35 N10.1103/PhysRevMaterials.3.054604 ↗
21. Effect of the AlGaN multi-quantum well growth temperature on the efficiency of metal-organic vapor-phase epitaxy-grown far-ultraviolet-C light-emitting diodes emitting near 235 nm10.1002/pssa.202400392 ↗
22. High-temperature annealing and patterned AlN/sapphire interfaces10.1002/pssb.202100187 ↗
23. Reliability of UVC LEDs fabricated on AlN/sapphire templates with different threading dislocation densities10.1063/5.0027769 ↗
24. Analysis of doping concentration and composition in wide bandgap AlGaN: Si by wavelength dispersive x-ray spectroscopy10.1088/1361-6641/aa58cf ↗
25. Advanced in-situ control for III-nitride RF power device epitaxy10.1088/1361-6641/aab410 ↗
26. The influence of threading dislocations propagating through an AlGaN UVC LED10.1063/5.0086034 ↗
27. The growth of crystals and the equilibrium structure of their surfaces10.1098/rsta.1951.0006 ↗
28. Anisotropic step-flow growth and island growth of GaN (0001) by molecular beam epitaxy10.1103/PhysRevLett.82.2749 ↗
29. Perfect dislocations in the wurtzite lattice10.1002/pssb.19680300103 ↗
30. The role of surface kinetics on composition and quality of AlGaN10.1016/j.jcrysgro.2016.06.055 ↗
31. Carrier diffusion in GaN: a cathodoluminescence study. III. Nature of nonradiative recombination at threading dislocations10.1103/PhysRevApplied.17.024019 ↗
32. Electron-beam-induced-current study of defects in GaN; experiments and simulation10.1088/0953-8984/14/48/352/meta ↗
33. Spatial correlation of defect-selective etching and dark luminescence spots in AlxGa1-xN10.1088/1361-6641/ad5040 ↗
34. Spatial clustering of defect luminescence centers in Si-doped low resistivity Al0.82Ga0.18N10.1063/1.4928667 ↗
35. Nanostars in highly Si-doped GaN10.1021/acs.cgd.3c00317 ↗
36. Surface reconstructions of (0001) AlN during metal-organic vapor phase epitaxy10.1002/pssb.201600711 ↗
37. Surface morphology of homoepitaxial c-plane GaN: hillocks and ridges10.1016/j.jcrysgro.2013.07.035 ↗
38. Screw dislocation-induced growth spirals as emissive exciton localization centers in Al-rich AlGaN/AlN quantum wells10.1063/1.4935567 ↗
39. Influence of the growth substrate on the internal quantum efficiency of AlGaN/AlN multiple quantum wells governed by carrier localization10.1002/pssb.202000464 ↗
40. Step pinning and hillock formation in (Al, Ga)N films on native AlN substrates10.1063/5.0125480 ↗
41. Influence of growth temperature on AlGaN multiquantum well point defect incorporation and photoluminescence efficiency10.1063/1.3583448 ↗
42. High-temperature annealing of AlGaN10.1002/pssa.202000473 ↗
43. Surface kinetics in AlN growth: a universal model for the control of surface morphology in III-nitrides10.1016/j.jcrysgro.2015.12.022 ↗
44. Point defect reduction in wide bandgap semiconductors by defect quasi Fermi level control10.1063/1.4967397 ↗
45. Cathodoluminescence efficiency dependence on excitation density in n-type gallium nitride10.1017/S1431927603030204 ↗
46. Tracking of point defects in the full compositional range of AlGaN via photoluminescence spectroscopy10.1002/pssa.202200390 ↗
47. Luminescence properties of defects in GaN10.1063/1.1868059 ↗
48. Current status of carbon-related defect luminescence in GaN10.1002/pssa.202100235 ↗
49. Evaluation of the concentration of point defects in GaN10.1038/s41598-017-08570-1 ↗
50. The kinetics of migration of point defects to dislocations10.1088/0034-4885/33/1/303 ↗
51. Oxygen segregation to dislocations in GaN10.1063/1.2136224 ↗
52. Role of oxygen at screw dislocations in GaN10.1103/PhysRevLett.91.165501 ↗
53. Origin of the parasitic luminescence of 235 nm UVC LEDs grown on different AlN templates10.1063/5.0183772 ↗
54. Time-resolved luminescence studies on AlN and high AlN mole fraction AlGaN alloys10.1002/pssc.201200676 ↗
55. Dislocation mediated surface morphology of GaN10.1063/1.370150 ↗
56. V-pit to truncated pyramid transition in AlGaN-based heterostructures10.1088/0268-1242/30/11/114010 ↗
57. Douglas C Paul E Robert M Gunnar K Viesturs S Rachel O 2026 Data for: “Controlling point defect populations in AlGaN deep UV LEDs” University of Strathclyde 10.15129/2844718f-7c0c-48e0-9ad9-bc66a2e3b7e310.15129/2844718f-7c0c-48e0-9ad9-bc66a2e3b7e3 ↗