journal article·2022-09-10Open access

Phonon assisted electron emission from quasi-freestanding bilayer epitaxial graphene microstructures

Daniel Lewis, Brendan Jordan, Michael Pedowitz, Daniel J Pennachio, Jenifer R Hajzus, Rachael Myers-Ward, Kevin M Daniels

Nanotechnology· Volume 33· Issue 37

Abstract

Abstract Electron emission from quasi-freestanding bilayer epitaxial graphene (QFEG) on a silicon carbide substrate is reported, demonstrating emission currents as high as 8.5 μ A, at ∼200 °C, under 0.3 Torr vacuum. Given the significantly low turn-on temperature of these QFEG devices, ∼150°C, the electron emission is explained by phonon-assisted electron emission, where the acoustic and optical phonons of QFEG causes carrier acceleration and emission. Devices of differing dimensions and shapes are fabricated via a simple and scalable fabrication procedure and tested. Variations in device morphology increase the density of dangling bonds, which can act as electron emission sites. Devices exhibit emission enhancement at increased temperatures, attributed to greater phonon densities. Devices exhibit emission under various test conditions, and a superior design and operating methodology are identified.
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Research context

OpenAlex topics: Graphene research and applications · Diamond and Carbon-based Materials Research · Carbon Nanotubes in Composites

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References (40)

Show source-provided references
1. Tuning the work function in transition metal oxides and their heterostructures10.1103/PhysRevB.93.235116 ↗
2. Tunable graphene micro-emitters with fast temporal response and controllable electron emission10.1038/ncomms11513 ↗
3. High-performance on-chip thermionic electron micro- emitter arrays based on super-aligned carbon nanotube films10.1002/adfm.201907814 ↗
4. Electron-emission materials: advances, applications, and models10.1557/mrs.2017.142 ↗
5. Breakdown of Richardson’s law in electron emission from individual self-joule-heated carbon nanotubes10.1038/srep05102 ↗
6. Phonon-Assisted electron emission from individual carbon nanotubes10.1021/nl103861p ↗
7. High-field electrical transport in single-wall carbon nanotubes10.1103/PhysRevLett.84.2941 ↗
8. High-field quasiballistic transport in short carbon nanotubes10.1103/PhysRevLett.92.106804 ↗
9. Electron-phonon scattering in metallic single-walled carbon nanotubes10.1021/nl035258c ↗
10. Phonon anharmonicities in graphite and graphene10.1103/PhysRevLett.99.176802 ↗
11. Electron transport and hot phonons in carbon nanotubes10.1103/PhysRevLett.95.236802 ↗
12. Raman spectroscopic evidence for hot-phonon generation in electrically biased carbon nanotubes10.1103/PhysRevLett.100.127401 ↗
13. Phonon populations and electrical power dissipation in carbon nanotube transistors10.1038/nnano.2009.22 ↗
14. Phonon linewidths and electron phonon coupling in nanotubes10.1103/PhysRevB.73.155426 ↗
15. Highly monochromatic electron emission from graphene/ hexagonal boron nitride/Si heterostructure10.1021/acsami.9b17468 ↗
16. A graphene-based large area surface-conduction electron emission display10.1016/j.carbon.2013.01.004 ↗
17. Richardson constant and electrostatics in transfer-free CVD grown few-layer MoS2/graphene barristor with Schottky barrier modulation >0.6 eV10.1063/1.5005796 ↗
18. Graphene field emitters: a review of fabrication, characterization and properties10.1016/j.mseb.2017.03.007 ↗
19. X-ray generation using carbon nanotubes10.1186/s40580-014-0034-2 ↗
20. Field emission from single and few-layer graphene flakes10.1063/1.3579533 ↗
21. Electronic and field emission properties of wrinkled graphene10.1021/jp3103063 ↗
22. Field electron emission characteristics and physical mechanism of individual single-layer graphene10.1021/nn101719r ↗
23. Edge field emission of large-area single layer graphene10.1016/j.apsusc.2015.09.160 ↗
24. Field emission properties of carbon nanowalls prepared by RF magnetron sputtering10.1007/s00339-019-2645-2 ↗
25. Electron emission from individual graphene nanoribbons driven by internal electric field10.1021/nn204172w ↗
26. Field emission energy distribution and three-terminal current-voltage characteristics from planar graphene edges10.1063/1.5064366 ↗
27. Thermal growth of graphene: a review10.3390/coatings8010040 ↗
28. Improved electron field emission from morphologically disordered monolayer graphene10.1063/1.3679135 ↗
29. Dimensional effects on field emission properties of the body for single-walled carbon nanotube10.1063/1.1388871 ↗
30. Narrow plasmon resonances enabled by quasi-freestanding bilayer epitaxial graphene10.1088/2053-1583/aa5c75 ↗
31. Contribution of the buffer layer to the Raman spectrum of epitaxial graphene on SiC(0001)10.1088/1367-2630/15/4/043031 ↗
32. Electron thermionic emission from graphene and thermionic energy converter10.1103/PhysRevApplied.3.014002 ↗
33. Thermionic electron emission from single carbon nanostructures and its applications in vacuum nanoelectronics10.1557/mrs.2017.145 ↗
34. Heating graphene to incandescence and the measurement of its work function by the thermionic emission method10.1007/s12274-014-0423-1 ↗
35. Electron field emission from screen-printed graphene films10.1088/0957-4484/20/42/425702 ↗
36. Field emission of single-layer graphene films prepared by electrophoretic deposition10.1002/adma.200802560 ↗
37. Field emission from few-layer graphene nanosheets produced by liquid phase exfoliation of graphite10.1166/jnn.2010.2432 ↗
38. Temperature dependence of the field emission from the few-layer graphene film10.1063/1.3651323 ↗
39. Simplified theory of carrier back-scattering in semiconducting carbon nanotubes: A Kane’s model approach10.1063/1.3374687 ↗
40. Low-bremsstrahlung x-ray source using a low-voltage high-current-density nanostructured field emission cathode and a transmission anode for markerless soft tissue imaging10.1109/JMEMS.2014.2332176 ↗