journal article·2023-11-12Open access

Glycol 400 assisted preparation of high contact surface TiO2/GO nanocomposites for photocatalytic degradation rhodamine B

Feitong Lu, Wei Wei, Qiang Shi, Ning Wang, Yi Xiao, Zibo Li

Nanotechnology· Volume 34· Issue 46

Abstract

Abstract TiO2/graphene oxide (GO) nanocomposites with high contact interface were prepared with glycol 400 (PEG400) served as dispersant. This nanocomposite exhibits improved photocatalytic efficiency in contrast with the nanocomposite prepared without PEG400. In this work, the photocatalytic performance was investigated by observing the degradation rate of Rhodamine B (RhB). And it is found that the mass ratios of GO in nanocomposites plays an important role. When the mass ratio of GO reached 45%, the photocatalytic performance of the nanocomposites reached the highest, which is ∼72%. Moreover, the photocatalytic mechanism was studied through theoretical calculations, which can be summarized as follows: (1) the presence of GO decreases the band gap of TiO2 nanoparticles. (2) GO inhibits the the recombination of photogenerated electron–hole pair. (3) GO improves the adsorption capacity of TiO2 nanoparticles for RhB. This work promoted the application of TiO2/GO nanocomposites in wastewater treatment.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. Design and fabrication of microsphere photocatalysts for environmental purification and energy conversion10.1016/j.cej.2015.10.112 ↗
2. Photocatalytic oxidation technology for indoor environment air purification: the state-of-the-art10.1016/j.apcatb.2016.10.037 ↗
3. Bioinspired self-cleaning surfaces with superhydrophobicity, superoleophobicity, and superhydrophilicity10.1039/C2RA21260A ↗
4. Recent advances in TiO2-based nanostructured surfaces with controllable wettability and adhesion10.1002/smll.201501837 ↗
5. Environmental applications of semiconductor photocatalysis10.1021/cr00033a004 ↗
6. Li-ion batteries from LiFePO4 cathode and anatase/graphene composite anode for stationary energy storage10.1016/j.elecom.2009.12.039 ↗
7. Use of highly-ordered TiO2 nanotube arrays in dye-sensitized solar cells10.1021/nl052099j ↗
8. Comparison of the abilities of ambient and manufactured nanoparticles to induce cellular toxicity according to an oxidative stress paradigm10.1021/nl061025k ↗
9. Photocatalysis on TiO2 surfaces: principles, mechanisms, and selected results10.1021/cr00035a013 ↗
10. Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications10.1021/cr0500535 ↗
11. TiO2 photocatalysis and related surface phenomena10.1016/j.surfrep.2008.10.001 ↗
12. Size effects on the photophysical properties of colloidal anatase TiO2 particles: size quantization versus direct transitions in this indirect semiconductor?10.1021/j100045a026 ↗
13. Relative photonic efficiencies and quantum yields in heterogeneous photocatalysis10.1016/S1010-6030(96)04538-8 ↗
14. Structural, optical and magnetic feature of core-shell nanostructured Fe3O4@GO in photocatalytic activity
15. Synthesis of a Fe3O4-rGO-ZnO-catalyzed photo-Fenton system with enhanced photocatalytic performance10.1016/j.ceramint.2021.01.044 ↗
16. Rapid and efficient synthesis of reduced graphene oxide nano-sheets using CO ambient atmosphere as a reducing agent10.1007/s10854-018-0069-y ↗
17. Hybrid nanostructures based on titanium dioxide for enhanced photocatalysis10.1016/j.apcata.2014.10.001 ↗
18. Nanocrystalline anatase TiO2/reduced graphene oxide composite films as photoanodes for photoelectrochemical water splitting studies: the role of reduced graphene oxide10.1039/C5CP06707C ↗
19. Photoinduced electron transfer pathways in hydrogen-evolving reduced graphene oxide-boosted hybrid nano-bio catalyst10.1021/nn502011p ↗
20. Enhanced photocatalytic urea oxidation under neutral medium by reduced graphene oxide coated TiO2 nanoparticles10.1016/j.catcom.2023.106690 ↗
21. Gold-coated flower-like TiO2 microparticles wrapped with reduced graphene oxide for SERS monitoring and photocatalytic degradation of organic pollutants10.1021/acsanm.2c03400 ↗
22. Fluorine-functionalized reduced graphene oxide-TiO2 nanocomposites: a new application approach for efficient photocatalytic disinfection and algicidal effect10.1016/j.envpol.2022.120974 ↗
23. TiO2-graphene nanocomposites for gas-phase photocatalytic degradation of volatile aromatic pollutant: is TiO2-graphene truly different from other TiO2-carbon composite materials?10.1021/nn1024219 ↗
24. P25-graphene composite as a high performance photocatalyst10.1021/nn901221k ↗
25. Engineering the unique 2D mat of graphene to achieve graphene-TiO2 nanocomposite for photocatalytic selective transformation: what advantage does graphene have over its forebear carbon nanotube?10.1021/nn202519j ↗
26. Low-temperature synthesis of stable nanoTiO2-rGO composite colloids and their application in photoelectric films10.1039/c3ra23095c ↗
27. Tuning the bandgap of graphene quantum dots by gold nanoparticle-assisted O2 plasma etching10.1039/C6RA16409A ↗
28. Wrinkled single-layer graphenes fabricated by silicon nanopillar arrays10.1088/0957-4484/27/47/475304 ↗
29. Graphene: the new two-dimensional nanomaterial10.1002/anie.200901678 ↗
30. Synthesis of visible-light responsive graphene oxide/TiO2 composites with p/n heterojunction10.1021/nn102130m ↗
31. Black Si-doped TiO2 nanotube photoanode for high-efficiency photoelectrochemical water splitting10.1039/C8RA00021B ↗
32. Structural and optical characterization of electrospun TiO2 nanofibers using titanium tetrabutoxide and titanium isopropoxide as precursors for photocatalytic applications10.1016/j.colsurfa.2022.129505 ↗
33. Fabrication of a greener TiO2@gum arabic-carbon paste electrode for the electrochemical detection of Pb2+ ions in plastic toys10.1021/acsomega.0c03781 ↗
34. Synthesis, structural and electrical properties of PVA/TiO2 nanocomposite films with different TiO2 phases prepared by sol–gel technique10.1007/s10854-020-04313-7 ↗
35. Electrical and gas sensing properties of TiO2/GO nanocomposites for CO2 sensor application10.1088/1742-6596/901/1/012095 ↗
36. Bifunctional single-crystalline rutile nanorod decorated heterostructural photoanodes for efficient dye-sensitized solar cells10.1039/c1cp21833f ↗
37. Biocompatibility effects of biologically synthesized graphene in primary mouse embryonic fibroblast cells10.1186/1556-276X-8-393 ↗
38. Influence of graphene microstructures on electrochemical performance for supercapacitors10.1016/j.pnsc.2015.10.004 ↗
39. Synthesis and characterization of TiO2/graphene oxide nanocomposites for photoreduction of heavy metal ions in reverse osmosis concentrate10.1039/C8RA06681G ↗
40. Carbon-doped anatase TiO2 powders as a visible-light sensitive photocatalyst10.1246/cl.2003.772 ↗
41. Direct observation of perovskite photodetector performance enhancement by atomically thin interface engineering10.1021/acsami.8b10971 ↗
42. Removal of the hazardous dye rhodamine B through photocatalytic and adsorption treatments10.1016/j.jenvman.2006.11.002 ↗
43. Structural, optical, magnetic properties and visible light photocatalytic activity of BiFeO3/graphene oxide nanocomposites10.1088/2053-1591/ab6807 ↗
44. Heterogeneous photocatalytic treatment of organic dyes in air and aqueous media10.1016/j.jphotochemrev.2008.09.001 ↗
45. Microstructure and photocatalytic activity of SnO2:Bi3+ nanoparticles10.1016/j.optmat.2023.113552 ↗
46. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set10.1103/PhysRevB.54.11169 ↗
47. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
48. High-throughput design and optimization of fast lithium ion conductors by the combination of bond-valence method and density functional theory10.1038/srep14227 ↗
49. Tunable electronic structures in BP/MoSSe van der Waals heterostructures by external electric field and strain10.1016/j.apsusc.2019.143809 ↗
50. In situ hydrothermal fabrication and photocatalytic behavior of ZnO/reduced graphene oxide nanocomposites with varying graphene oxide concentrations
51. SnO2/reduced graphene oxide nanocomposites for highly efficient photocatalytic degradation of methylene blue