journal article·2021-01-08

In-situ electrical conductance measurement of suspended ultra-narrow graphene nanoribbons observed via transmission electron microscopy

Chunmeng Liu, Jiaqi Zhang, Xiaobin Zhang, Manoharan Muruganathan, Hiroshi Mizuta, Yoshifumi Oshima

Nanotechnology· Volume 32· Issue 2
Publisher page

Abstract

Abstract Graphene nanoribbon is an attractive material for nano-electronic devices, as their electrical transport performance can be controlled by their edge structures. However, in most cases, the electrical transport has been investigated only for graphene nanoribbons fabricated on a substrate, which hinders the appearance of intrinsic electrical transport due to screening effects. In this study, we developed special devices based on silicon chips for transmission electron microscopy to observe a monolayer graphene nanoribbon suspended between two gold electrodes. Moreover, with the development of an in-situ transmission electron microscopy holder, the current–voltage characteristics were achieved simultaneously with observing and modifying the structure. We found that the current–voltage characteristics differed between 1.5 nm-wide graphene nanoribbons with armchair and zigzag edge structures. The energy gap of the zigzag edge was more than two-fold larger than that of the armchair edge and exhibited an abrupt jump above a critical bias voltage in the differential conductance curve. Thus, our in-situ transmission electron microscopy method is promising for elucidating the structural dependence of electrical conduction in two-dimensional materials.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Graphene research and applications · Quantum and electron transport phenomena · Surface and Thin Film Phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Ultrahigh electron mobility in suspended graphene10.1016/j.ssc.2008.02.024 ↗
2. Electronic transport in helium-ion-beam etched encapsulated graphene nanoribbons10.1016/j.carbon.2017.04.062 ↗
3. High-strength chemical-vapor- deposited graphene and grain boundaries10.1126/science.1235126 ↗
4. Measurement of the elastic properties and intrinsic strength of monolayer graphene10.1126/science.1157996 ↗
5. Superior thermal conductivity of single-layer graphene10.1021/nl0731872 ↗
6. Thermal properties of graphene and nanostructured carbon materials10.1038/nmat3064 ↗
7. Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation10.1021/nn900020u ↗
8. The rise of graphene10.1038/nmat1849 ↗
9. Carbon sheets an atom thick give rise to graphene dreams10.1126/science.324_875 ↗
10. Measurement of scattering rate and minimum conductivity in graphene10.1103/PhysRevLett.99.246803 ↗
11. Transfer of large-area graphene films for high-performance transparent conductive electrodes10.1021/nl902623y ↗
12. Conductance enlargement in picoscale electroburnt graphene nanojunctions10.1073/pnas.1418632112 ↗
13. The influence of edge structure on the electronic properties of graphene quantum dots and nanoribbons10.1038/nmat2378 ↗
14. Graphene edges and beyond: temperature-driven structures and electromagnetic properties10.1021/acsnano.5b02617 ↗
15. Structure-dependent electrical properties of graphene nanoribbon devices with graphene electrodes10.1016/j.carbon.2019.01.071 ↗
16. Correlating atomic structure and transport in suspended graphene nanoribbons10.1021/nl501872x ↗
17. First principles study on the electronic structures and transport properties of armchair/zigzag edge hybridized graphene nanoribbons10.1063/1.5020603 ↗
18. Quasiparticle energies and band gaps in graphene nanoribbons10.1103/PhysRevLett.99.186801 ↗
19. Room-temperature magnetic order on zigzag edges of narrow graphene nanoribbons10.1038/nature13831 ↗
20. Dielectric-screening reduction‐induced large transport gap in suspended sub‐10 nm graphene nanoribbon functional devices10.1002/smll.201903025 ↗
21. In situ electronic characterization of graphene nanoconstrictions fabricated in a transmission electron microscope10.1021/nl2023756 ↗
22. Fabrication and in situ transmission electron microscope characterization of free-standing graphene nanoribbon devices10.1021/acsnano.5b06975 ↗
23. Electrical wind force-driven and dislocation-templated amorphization in phase-change nanowires10.1126/science.1220119 ↗
24. High-resolution transmission electron microscopy study of electrically-driven reversible phase change in Ge2 Sb2 Te5 nanowires10.1021/nl104537c ↗
25. Transfer of CVD-grown monolayer graphene onto arbitrary substrates10.1021/nn201207c ↗
26. Graphene annealing: how clean can it be?10.1021/nl203733r ↗
27. Ultraclean suspended monolayer graphene achieved by in situ current annealing10.1088/1361-6528/28/4/045706 ↗
28. Clean graphene surface through high temperature annealing10.1016/j.carbon.2015.07.046 ↗
29. Accurate measurement of electron beam induced displacement cross sections for single-layer graphene10.1103/PhysRevLett.108.196102 ↗
30. Atomic-scale electron-beam sculpting of near-defect-free graphene nanostructures10.1021/nl200369r ↗
31. Engineering of nanostructured carbon materials with electron or ion beams10.1038/nmat1996 ↗
32. Real-time observation of tubule formation from amorphous carbon nanowires under high-bias joule heating10.1021/nl0609910 ↗
33. Energy band-gap engineering of graphene nanoribbons10.1103/PhysRevLett.98.206805 ↗
34. Electron transport in disordered graphene nanoribbons10.1103/PhysRevLett.104.056801 ↗
35. Disorder-induced gap behavior in graphene nanoribbons10.1103/PhysRevB.81.115409 ↗
36. Approaching the intrinsic band gap in suspended high-mobility graphene nanoribbons10.1103/PhysRevB.84.125411 ↗
37. Origin of nonlinear current-voltage curves for suspended zigzag edge graphene nanoribbon10.1016/j.carbon.2020.05.010 ↗
38. I − V curve signatures of nonequilibrium-driven band gap collapse in magnetically ordered zigzag graphene nanoribbon two-terminal devices10.1103/PhysRevB.79.205430 ↗