Tunable Photocatalytic Properties of Au-Decorated BiFeO₃ Nanostructures for Dye Photodegradation

High Resolution Image Download MS PowerPoint Slide This study presents the synthesis and characterization of Au nanoparticle-decorated BiFeO 3 (Au-BiFeO 3 ) nanocrystals fabricated by a hydrothermal technique. The key focus is the augmented photocatalytic properties of these nanocrystals for the effective photodegradation of methylene blue (MB), a common industrial dye. The magnetic properties of the Au-BiFeO 3 merely differ from those of the BiFeO 3 . The decoration of Au nanoparticles onto the BiFeO 3 introduces heterojunction structures that lead to effective charge-carrier separation under illumination. Time-resolved photoluminescence spectroscopy confirms the enhanced charge separation and reduced recombination rate in Au-BiFeO 3 nanocrystals. Through meticulous optimization, the photocatalytic performance of these nanocomposites was evaluated under various Au loadings, revealing that 1.0 wt % Au-BiFeO 3 exhibits the most superior activity, achieving an impressive 98% degradation efficiency of MB under a 500 W xenon lamp within 120 min. The study also demonstrates the structural integrity and stability of the photocatalyst, with it retaining about 80% of its original activity after four cycles of the 120 min photodegradation process. These findings suggest that the Au-BiFeO 3 nanocrystals are promising, efficient, and sustainable photocatalysts for environmental purification and offer insights into designing advanced materials for solar energy utilization.