journal article·2023-07-14Open access

Scalable High Tensile Modulus Composite Laminates Using Continuous Carbon Nanotube Yarns for Aerospace Applications

Cecil E. Evers, Britannia Vondrasek, Claire N. Jolowsky, Jin Gyu Park, Michael W. Czabaj, Bailee E. Ku, Kaylee R. Thagard, Gregory M. Odegard, Zhiyong Liang

ACS Applied Nano Materials· Volume 6· Issue 13

Abstract

High Resolution Image Download MS PowerPoint Slide An approach is established for fabricating high-strength and high-stiffness composite laminates with continuous carbon nanotube (CNT) yarns for scaled-up mechanical tests and potential aerospace structure applications. Continuous CNT yarns with up to 80% degree of nanotube alignment and a unique self-assembled graphitic CNT packing result in their specific tensile strengths of 1.77 ± 0.07 N/tex and an apparent specific modulus of 92.6 ± 3.2 N/tex. Unidirectional CNT yarn reinforced composite laminates with a CNT concentration of greater than 80 wt % and minimal microscale voids are fabricated using filament winding and aerospace-grade resin matrices. A specific tensile strength of up to 1.71 GPa/(g cm –3 ) and specific modulus of 256 GPa/(g cm –3 ) are realized; the specific modulus exceeds current state-of-the-art unidirectional carbon fiber composite laminates. The specific modulus of the laminates is 2.76 times greater than the specific modulus of the constituent CNT yarns, a phenomenon not observed in carbon fiber reinforced composites. The results demonstrate an effective approach for fabricating high-strength CNT yarns into composites for applications that require specific tensile modulus properties that are significantly beyond state-of-the-art carbon fiber composites and potentially open an unexplored performance region in the Ashby chart for composite material applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Carbon Nanotubes in Composites · Material Properties and Applications · Additive Manufacturing and 3D Printing Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

FAMU-FSU College of Engineering, High-Performance Materials Institute, Florida State University, 2005 Levy Avenue, Tallahassee, Florida 32311, United States

Department of Mechanical Engineering, University of Utah, Salt Lake City, Utah 84112, United States

Mechanical Engineering─Engineering Mechanics, Michigan Technological University, Houghton, Michigan 49931, United States

Funding

Solvay · National Aeronautics and Space Administration

References (65)

Show source-provided references
1. 10.1088/1361-6528/aa7c5a10.1088/1361-6528/aa7c5a ↗
2. Elliott J. · WSEAS Trans. Appl. Theor. Mech. · 2017 · 12 · 33
3. 10.1002/adma.20190202810.1002/adma.201902028 ↗
4. 10.1039/C8RA01212A10.1039/C8RA01212A ↗
5. 10.1126/science.122806110.1126/science.1228061 ↗
6. 10.1016/j.compscitech.2022.10950110.1016/j.compscitech.2022.109501 ↗
7. 10.1038/s41565-018-0141-z10.1038/s41565-018-0141-z ↗
8. 10.1557/mrs2007.23110.1557/mrs2007.231 ↗
9. 10.1016/j.compscitech.2018.04.01310.1016/j.compscitech.2018.04.013 ↗
10. 10.1021/acsnano.8b0651110.1021/acsnano.8b06511 ↗
11. 10.1088/0022-3727/36/5/32310.1088/0022-3727/36/5/323 ↗
12. 10.1115/1.403825710.1115/1.4038257 ↗
13. 10.3390/nano1006121310.3390/nano10061213 ↗
14. 10.1021/la062743p10.1021/la062743p ↗
15. 10.1063/1.325374710.1063/1.3253747 ↗
16. 10.1063/1.146688010.1063/1.1466880 ↗
17. 10.1016/j.compscitech.2015.04.00810.1016/j.compscitech.2015.04.008 ↗
18. 10.1016/j.carbon.2016.07.02810.1016/j.carbon.2016.07.028 ↗
19. 10.1016/j.carbon.2015.07.07610.1016/j.carbon.2015.07.076 ↗
20. 10.1016/j.compscitech.2018.04.00310.1016/j.compscitech.2018.04.003 ↗
21. 10.1016/j.compositesa.2014.05.01310.1016/j.compositesa.2014.05.013 ↗
22. 10.1016/j.carbon.2015.06.01210.1016/j.carbon.2015.06.012 ↗
23. 10.1016/j.compscitech.2016.07.00610.1016/j.compscitech.2016.07.006 ↗
24. 10.1016/j.compscitech.2020.10801410.1016/j.compscitech.2020.108014 ↗
25. 10.1016/j.compositesa.2019.10547710.1016/j.compositesa.2019.105477 ↗
26. 10.3390/nano1109244510.3390/nano11092445 ↗
27. 10.1002/adem.20160049910.1002/adem.201600499 ↗
28. 10.1016/j.compstruct.2019.03.06510.1016/j.compstruct.2019.03.065 ↗
29. 10.1002/adfm.20090066310.1002/adfm.200900663 ↗
30. 10.1016/j.carbon.2016.04.06610.1016/j.carbon.2016.04.066 ↗
31. 10.1016/j.polymer.2006.01.00310.1016/j.polymer.2006.01.003 ↗
32. 10.1016/j.compscitech.2018.02.01010.1016/j.compscitech.2018.02.010 ↗
33. 10.1016/j.carbon.2019.04.11310.1016/j.carbon.2019.04.113 ↗
34. 10.1021/nn102925a10.1021/nn102925a ↗
35. 10.1016/j.msea.2020.13982410.1016/j.msea.2020.139824 ↗
36. 10.1016/j.carbon.2015.05.06510.1016/j.carbon.2015.05.065 ↗
37. 10.1016/j.carbon.2019.09.07010.1016/j.carbon.2019.09.070 ↗
38. Kim J.-W. · 2018
39. Kim J.-W. · 2015
40. 10.1016/S1748-0132(08)70062-810.1016/S1748-0132(08)70062-8 ↗
41. 10.1016/S1369-7021(12)70135-910.1016/S1369-7021(12)70135-9 ↗
42. Marlett, K.; Ng, Y.; Tomblin, J. Hexcel 8552 IM7 Unidirectional Prepreg 190 Gsm & 35%RC Qualification Material Property Data Report ; National Institute for Aviation Research, 2011.
43. 10.1021/acsnano.0c0858810.1021/acsnano.0c08588 ↗
44. 10.1021/am101104710.1021/am1011047 ↗
45. Siochi E. J. · 2016
46. 10.1016/j.carbon.2020.11.05510.1016/j.carbon.2020.11.055 ↗
47. 10.1126/sciadv.abn093910.1126/sciadv.abn0939 ↗
48. 10.1021/acsanm.1c0096910.1021/acsanm.1c00969 ↗
49. 10.1021/nn301039v10.1021/nn301039v ↗
50. 10.1021/acsanm.1c0258210.1021/acsanm.1c02582 ↗
51. 10.1063/1.153673310.1063/1.1536733 ↗
52. Park, J. G.; Sweat, R.; Liang, R. Quantitative Microstructure Study of PAN and Pitch-Based Carbon Fibers Through TEM and X-Ray Scattering Analysis. Proceedings of the American Society for Composites─Thirty-Fourth Technical Conference ; ASC, 2019.10.12783/asc34/31384 ↗
53. Anderson D. P. · 1991
54. Jolowsky, C.; Arias, M.; Holleran, M. Scale-up Study and Demonstration of Highly Aligned and High Concentration CNT Reinforced Composites for Aerospace Applications. Proceedings of the American Society for Composites─Thirty-Second Technical Conference ; ASC, 2017.10.12783/asc2017/15338 ↗
55. 10.1021/acsanm.0c0301310.1021/acsanm.0c03013 ↗
56. 10.3390/polym1313216210.3390/polym13132162 ↗
57. 10.1021/acs.langmuir.1c0180010.1021/acs.langmuir.1c01800 ↗
58. D20 Committee · 2001
59. D20 Committee · 2014
60. 10.1016/j.compscitech.2022.10937510.1016/j.compscitech.2022.109375 ↗
61. Dessureault Y.-S. · 2021
62. Ku B. · 2022
63. Toray Composite Materials America, Inc. · 2018
64. Toray Composite Materials America, Inc. · 2018
65. Hexcel · 2020