journal article·2003

Equilibrium and dynamics of acetylene sorption in multiwalled carbon nanotubes

Gy. Onyestyák, J. Valyon, K. Hernádi, I. Kiricsi,, L.V.C. Rees

Carbon· Volume 41· Issue 6
Publisher page

Abstract

Abstract Multiwalled carbon nanotubes (MWCNT) were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and by adsorption of N 2 and acetylene. The dynamics of acetylene sorption was studied by frequency response spectroscopy. The average tube dimension and the shell number were determined from a statistical evaluation of the TEM images. This value agreed with that obtained from XRD via the Scherrer equation only if a shape factor of 0.49 was used. The diffusion of acetylene in the nanotubes of the MWCNT sample was found to be the rate-controlling step of the sorption process. Relationships between the tube dimensions and the equilibrium and dynamic sorption properties were demonstrated.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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